Polycrystalline and Mesoporous 3-D Bi2O3 Nanostructured Negatrodes for High-Energy and Power-Asymmetric Supercapacitors: Superfast Room-Temperature Direct Wet Chemical Growth

2018 ◽  
Vol 10 (13) ◽  
pp. 11037-11047 ◽  
Author(s):  
Nanasaheb M. Shinde ◽  
Qi Xun Xia ◽  
Je Moon Yun ◽  
Rajaram S. Mane ◽  
Kwang Ho Kim
1999 ◽  
Vol 567 ◽  
Author(s):  
Q.B. Hurst ◽  
N. Herbots ◽  
J.M. Shaw ◽  
M.M. Floyd ◽  
D.J. Smith ◽  
...  

ABSTRACTIn this paper, we investigate the correlation of electrical properties and structure of 1-4 nm thick SiO2 grown on H-passivated Si(100) for ultra-thin gate applications. Ordered (1×1) Si(100) stable in ambient air is obtained at room temperature by wet chemical cleaning. Ion Beam Analysis using a combination of ion channeling and 16O(α,α)16O nuclear resonance yields Si areal densities lower than that of a bulk-terminated Si crystal as calculated by Monte-Carlo simulations. This result indicates shadowing of Si substrate atoms by Si atoms in the thermally grown oxide. Detection of order by ion channeling is supported by Reflection High Energy Electron Diffraction (RHEED). C-V and I-V measurements are generally inconclusive for ultra-thin (1-2 nm) oxides because of leakage and breakdown. Surface charge analysis enables a comparison between ordered oxides and conventional oxides. The results are promising.


Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1535
Author(s):  
Yanjie Wang ◽  
Yingjie Zhang ◽  
Hongyu Cheng ◽  
Zhicong Ni ◽  
Ying Wang ◽  
...  

Lithium metal batteries have achieved large-scale application, but still have limitations such as poor safety performance and high cost, and limited lithium resources limit the production of lithium batteries. The construction of these devices is also hampered by limited lithium supplies. Therefore, it is particularly important to find alternative metals for lithium replacement. Sodium has the properties of rich in content, low cost and ability to provide high voltage, which makes it an ideal substitute for lithium. Sulfur-based materials have attributes of high energy density, high theoretical specific capacity and are easily oxidized. They may be used as cathodes matched with sodium anodes to form a sodium-sulfur battery. Traditional sodium-sulfur batteries are used at a temperature of about 300 °C. In order to solve problems associated with flammability, explosiveness and energy loss caused by high-temperature use conditions, most research is now focused on the development of room temperature sodium-sulfur batteries. Regardless of safety performance or energy storage performance, room temperature sodium-sulfur batteries have great potential as next-generation secondary batteries. This article summarizes the working principle and existing problems for room temperature sodium-sulfur battery, and summarizes the methods necessary to solve key scientific problems to improve the comprehensive energy storage performance of sodium-sulfur battery from four aspects: cathode, anode, electrolyte and separator.


2021 ◽  
Vol 11 (14) ◽  
pp. 2003493
Author(s):  
Alex Yong Sheng Eng ◽  
Vipin Kumar ◽  
Yiwen Zhang ◽  
Jianmin Luo ◽  
Wenyu Wang ◽  
...  

Author(s):  
Jian Zhao ◽  
He Cheng ◽  
Huanyu Li ◽  
Yan-Jie Wang ◽  
Qingyan Jiang ◽  
...  

Developing advanced negative and positive electrode materials for asymmetric supercapacitors (ASCs) as the electrochemical energy storage can enable the device to reach high energy/power densities resulting from the cooperative effect...


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Kazuaki Kisu ◽  
Sangryun Kim ◽  
Takara Shinohara ◽  
Kun Zhao ◽  
Andreas Züttel ◽  
...  

AbstractHigh-energy-density and low-cost calcium (Ca) batteries have been proposed as ‘beyond-Li-ion’ electrochemical energy storage devices. However, they have seen limited progress due to challenges associated with developing electrolytes showing reductive/oxidative stabilities and high ionic conductivities. This paper describes a calcium monocarborane cluster salt in a mixed solvent as a Ca-battery electrolyte with high anodic stability (up to 4 V vs. Ca2+/Ca), high ionic conductivity (4 mS cm−1), and high Coulombic efficiency for Ca plating/stripping at room temperature. The developed electrolyte is a promising candidate for use in room-temperature rechargeable Ca batteries.


2017 ◽  
Vol 5 (2) ◽  
pp. 804-813 ◽  
Author(s):  
Neng Yu ◽  
Kai Guo ◽  
Wei Zhang ◽  
Xianfu Wang ◽  
Ming-Qiang Zhu

A flexible asymmetric supercapacitor assembled with novel MnO@C composite nanosheets and Co3O4 nanosheets as negative and positive electrodes achieves an exceptional energy density of 59.6 W h kg−1 at a power density of 1529.8 W kg−1.


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