Gelled Graphene Oxide–Ionic Liquid Composite Membranes with Enriched Ionic Liquid Surfaces for Improved CO2 Separation

2018 ◽  
Vol 10 (8) ◽  
pp. 7389-7400 ◽  
Author(s):  
Winny Fam ◽  
Jaleh Mansouri ◽  
Hongyu Li ◽  
Jingwei Hou ◽  
Vicki Chen
2018 ◽  
Vol 51 (18) ◽  
pp. 7112-7120 ◽  
Author(s):  
Akika Ito ◽  
Tomohiro Yasuda ◽  
Tetsuro Yoshioka ◽  
Akihiro Yoshida ◽  
Xiang Li ◽  
...  

2021 ◽  
Vol 24 ◽  
pp. 101164
Author(s):  
Xinyi Wan ◽  
Xiao Wang ◽  
Ting Wan ◽  
Youguo Yan ◽  
Zhizhen Ye ◽  
...  

2013 ◽  
Vol 430 ◽  
pp. 211-222 ◽  
Author(s):  
Shinji Kanehashi ◽  
Masanori Kishida ◽  
Takashi Kidesaki ◽  
Ryohei Shindo ◽  
Shuichi Sato ◽  
...  

2020 ◽  
Vol 37 (12) ◽  
pp. 2287-2294
Author(s):  
Gishedaraankumar Krishnan ◽  
Safia Syazana Mohtar ◽  
Farhana Aziz ◽  
Juhana Jaafar ◽  
Norhaniza Yusof ◽  
...  

2015 ◽  
Vol 3 (12) ◽  
pp. 6629-6641 ◽  
Author(s):  
Qingping Xin ◽  
Zhao Li ◽  
Congdi Li ◽  
Shaofei Wang ◽  
Zhongyi Jiang ◽  
...  

Amino acid-functionalized graphene oxide nanosheet-incorporated composite membranes significantly enhanced the CO2/CH4(N2) diffusivity, reactivity and solubility selectivities.


2021 ◽  
Vol 60 (11) ◽  
pp. 4405-4419
Author(s):  
Murilo Leite Alcantara ◽  
Gerlon de Almeida Oliveira ◽  
Luciano Morais Lião ◽  
Cristiano Piacsek Borges ◽  
Silvana Mattedi

2017 ◽  
Vol 5 (2) ◽  
pp. 649-656 ◽  
Author(s):  
M. Karunakaran ◽  
L. F. Villalobos ◽  
M. Kumar ◽  
R. Shevate ◽  
F. H. Akhtar ◽  
...  

Thin film composite membranes were prepared using the blends of graphene oxide and an ionic liquid for efficient CO2 gas capture.


RSC Advances ◽  
2017 ◽  
Vol 7 (11) ◽  
pp. 6422-6431 ◽  
Author(s):  
Mengdie Li ◽  
Xiangping Zhang ◽  
Shaojuan Zeng ◽  
Lu bai ◽  
Hongshuai Gao ◽  
...  

A series of composite membranes with high gas transport properties enhanced by IL and ZIF-8 have been developed. The influence of ionic liquid and ZIF-8 addition on gas separation performance were systematically investigated.


2020 ◽  
Vol 10 (11) ◽  
pp. 3859 ◽  
Author(s):  
Daria Nikolaeva ◽  
Sandrine Loïs ◽  
Paul Inge Dahl ◽  
Marius Sandru ◽  
Jolanta Jaschik ◽  
...  

A poly(ionic-liquid) (PIL) matrix can be altered by incorporating additives that will disrupt the polymer chain packing, such as an ionic liquid (IL) and inorganic salts to boost their exploitation as materials for membrane production to be used in CO2 capture. Herein, potential of PIL/IL/salt blends is investigated on the example of poly(diallyldimethyl ammonium) bis(trifluoromethylsulfonyl)imide (P[DADMA][Tf2N]) with N-butyl-N-methyl pyrrolidinium bis(trifluoromethylsulfonyl)imide ([Pyrr14][Tf2N]) and zinc di-bis(trifluoromethylsulfonyl)imide (Zn[Tf2N]2). Composite material with IL and a higher amount of Zn2+ showed an increase in the equilibrium CO2 sorption capacity to 2.77 cm3 (STP)cm −3 bar−1. Prepared blends were successfully processed into thick, dense membranes and thin-film composite membranes. Their CO2 separation efficiency was determined using ideal and mixed-gas feed (vol% CO2 = 50 , dry and with 90% relative humidity). The dominant role of solubility in the transport mechanism is confirmed by combining direct gravimetric sorption measurements and indirect estimations from time-lag experiments. The maximum incorporated amount of Zn2+ salts increased equilibrium solubility selectivity by at least 50% in comparison to the parent PIL. All materials showed increased CO2 permeance values by at least 30% in dry conditions, and 60% in humidified conditions when compared to the parent PIL; the performance of pure PIL remained unchanged upon addition of water vapor to the feed stream. Mixed-gas selectivities for all materials rose by 10% in humidified conditions when compared to dry feed experiments. Our results confirm that the addition of IL improves the performance of PIL-based composites due to lower stiffness of the membrane matrix. The addition of Zn2+-based salt had a marginal effect on CO2 separation efficiency, suggesting that the cation participates in the facilitated transport of CO2.


2020 ◽  
Vol 2 (11) ◽  
pp. 5067-5076
Author(s):  
Irshad Kammakakam ◽  
Jason E. Bara ◽  
Enrique M. Jackson

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