Role of Nitrogen Moieties in N-Doped 3D-Graphene Nanosheets for Oxygen Electroreduction in Acidic and Alkaline Media

2018 ◽  
Vol 10 (14) ◽  
pp. 11623-11632 ◽  
Author(s):  
Sadia Kabir ◽  
Kateryna Artyushkova ◽  
Alexey Serov ◽  
Plamen Atanassov
RSC Advances ◽  
2016 ◽  
Vol 6 (18) ◽  
pp. 15167-15174 ◽  
Author(s):  
C. Li ◽  
Z. Han ◽  
Y. Yu ◽  
Y. Zhang ◽  
B. Dong ◽  
...  

High-performance self-supported Co–N-doped carbon electrocatalyst for ORR with comparable activity to Pt/C in both acidic and alkaline media was prepared.


2020 ◽  
Vol 12 (24) ◽  
pp. 27150-27165 ◽  
Author(s):  
Andrey A. Koverga ◽  
Ana M. Gómez-Marín ◽  
Ludovic Dorkis ◽  
Elizabeth Flórez ◽  
Edson A. Ticianelli

RSC Advances ◽  
2016 ◽  
Vol 6 (83) ◽  
pp. 79459-79469 ◽  
Author(s):  
Yue Guan ◽  
Zhiyu Dou ◽  
Yan Yang ◽  
Juanhong Xue ◽  
Zhen Zhu ◽  
...  

We have synthesized hierarchically 3D porous Fe5C2/N-doped graphene (3D Fe5C2/N-PG) with numerous micro/meso-pores by a controllable and facile strategy. The catalyst displays excellent catalytic activity for ORR in both acidic and alkaline media.


2020 ◽  
Vol 9 (1) ◽  
pp. 843-852
Author(s):  
Hunan Jiang ◽  
Jinyang Li ◽  
Mengni Liang ◽  
Hanpeng Deng ◽  
Zuowan Zhou

AbstractAlthough Fe–N/C catalysts have received increasing attention in recent years for oxygen reduction reaction (ORR), it is still challenging to precisely control the active sites during the preparation. Herein, we report FexN@RGO catalysts with the size of 2–6 nm derived from the pyrolysis of graphene oxide and 1,1′-diacetylferrocene as C and Fe precursors under the NH3/Ar atmosphere as N source. The 1,1′-diacetylferrocene transforms to Fe3O4 at 600°C and transforms to Fe3N and Fe2N at 700°C and 800°C, respectively. The as-prepared FexN@RGO catalysts exhibited superior electrocatalytic activities in acidic and alkaline media compared with the commercial 10% Pt/C, in terms of electrochemical surface area, onset potential, half-wave potential, number of electrons transferred, kinetic current density, and exchange current density. In addition, the stability of FGN-8 also outperformed commercial 10% Pt/C after 10000 cycles, which demonstrates the as-prepared FexN@RGO as durable and active ORR catalysts in acidic media.


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