Forming Intermediate Phase on the Surface of PbI2 Precursor Films by Short-Time DMSO Treatment for High-Efficiency Planar Perovskite Solar Cells via Vapor-Assisted Solution Process

2018 ◽  
Vol 10 (2) ◽  
pp. 1781-1791 ◽  
Author(s):  
Haibin Chen ◽  
Xihong Ding ◽  
Pan Xu ◽  
Tasawar Hayat ◽  
Ahmed Alsaedi ◽  
...  
2021 ◽  
pp. 2103019
Author(s):  
Shaomin Yang ◽  
Jialun Wen ◽  
Zhike Liu ◽  
Yuhang Che ◽  
Jie Xu ◽  
...  

2015 ◽  
Vol 17 (30) ◽  
pp. 19745-19750 ◽  
Author(s):  
Da-Xing Yuan ◽  
Adam Gorka ◽  
Mei-Feng Xu ◽  
Zhao-Kui Wang ◽  
Liang-Sheng Liao

High efficiency inverted planar NH2CHNH2PbI3 perovskite solar cells fabricated by a low-temperature solution-process.


Nanomaterials ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 915 ◽  
Author(s):  
Lei Shi ◽  
Huiying Hao ◽  
Jingjing Dong ◽  
Tingting Zhong ◽  
Chen Zhang ◽  
...  

Intermediate phase is considered an important aspect to deeply understand the crystallization procedure in the growth of high-quality perovskite layers by an anti-solvent technique. However, the moisture influence on the intermediate phase formation is not clear in air conditions as yet. In this work, pure (FA0.2MA1.8)Pb3X8(DMSO·DMF) intermediate phase was obtained in as-prepared perovskite film by spin-coating the precursor of co-solvent (DMSO and DMF) in an ambient air (RH20–30%). Moreover, the appropriate quantity of ethyl acetate (C4H8O2, EA) also controls the formation of pure intermediate phase. The uniform and homogeneous perovskite film was obtained after annealing this intermediate film. Therefore, the best power conversion efficiency (PCE) of perovskite solar cells (PSCs) is 16.24% with an average PCE of 15.53%, of which almost 86% of its initial PCE was preserved after 30 days in air conditions. Besides, the steady-state output efficiency ups to 15.38% under continuous illumination. In addition, the PCE of large area device (100 mm2) reaches 11.11% with a little hysteresis effect. This work would give an orientation for PSCs production at the commercial level, which could lower the cost of fabricating the high efficiency PSCs.


2021 ◽  
pp. 2102492
Author(s):  
Yeonghun Yun ◽  
Devthade Vidyasagar ◽  
Minho Lee ◽  
Oh Yeong Gong ◽  
Jina Jung ◽  
...  

2019 ◽  
Vol 201 ◽  
pp. 110113 ◽  
Author(s):  
Tao Ye ◽  
Guifang Han ◽  
Abhijith Surendran ◽  
Jia Li ◽  
Teck Ming Koh ◽  
...  

2020 ◽  
Vol 7 (3) ◽  
pp. 934-942 ◽  
Author(s):  
Luyao Wang ◽  
Xin Wang ◽  
Lin-Long Deng ◽  
Shibing Leng ◽  
Xiaojun Guo ◽  
...  

Tuning the polarity of green antisolvents (using various ethers) allows high control over the purity of the intermediate phase of triple-cation lead halide perovskite thin films.


Science ◽  
2016 ◽  
Vol 353 (6294) ◽  
pp. 58-62 ◽  
Author(s):  
Xiong Li ◽  
Dongqin Bi ◽  
Chenyi Yi ◽  
Jean-David Décoppet ◽  
Jingshan Luo ◽  
...  

Metal halide perovskite solar cells (PSCs) currently attract enormous research interest because of their high solar-to-electric power conversion efficiency (PCE) and low fabrication costs, but their practical development is hampered by difficulties in achieving high performance with large-size devices. We devised a simple vacuum flash–assisted solution processing method to obtain shiny, smooth, crystalline perovskite films of high electronic quality over large areas. This enabled us to fabricate solar cells with an aperture area exceeding 1 square centimeter, a maximum efficiency of 20.5%, and a certified PCE of 19.6%. By contrast, the best certified PCE to date is 15.6% for PSCs of similar size. We demonstrate that the reproducibility of the method is excellent and that the cells show virtually no hysteresis. Our approach enables the realization of highly efficient large-area PSCs for practical deployment.


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