Cobalt Nanoparticles Chemically Bonded to Porous Carbon Nanosheets: A Stable High-Capacity Anode for Fast-Charging Lithium-Ion Batteries

2018 ◽  
Vol 10 (5) ◽  
pp. 4652-4661 ◽  
Author(s):  
Vinodkumar Etacheri ◽  
Chulgi Nathan Hong ◽  
Jialiang Tang ◽  
Vilas G. Pol
2014 ◽  
Vol 2 (9-10) ◽  
pp. 778-785 ◽  
Author(s):  
Jun Ming ◽  
Won Jin Kwak ◽  
Sung Jun Youn ◽  
Hai Ming ◽  
Jusef Hassoun ◽  
...  

2015 ◽  
Vol 155 ◽  
pp. 18-22 ◽  
Author(s):  
Yuqi Zhou ◽  
Heng-guo Wang ◽  
Yan Zeng ◽  
Chao Li ◽  
Yu Shen ◽  
...  

Small ◽  
2017 ◽  
Vol 13 (46) ◽  
pp. 1702903 ◽  
Author(s):  
Chunfu Lin ◽  
Shengjue Deng ◽  
David J. Kautz ◽  
Zhihao Xu ◽  
Tao Liu ◽  
...  

2021 ◽  
Vol 14 (1) ◽  
Author(s):  
Jinghui Ren ◽  
Zhenyu Wang ◽  
Peng Xu ◽  
Cong Wang ◽  
Fei Gao ◽  
...  

AbstractHigh-energy–density lithium-ion batteries (LIBs) that can be safely fast-charged are desirable for electric vehicles. However, sub-optimal lithiation potential and low capacity of commonly used LIBs anode cause safety issues and low energy density. Here we hypothesize that a cobalt vanadate oxide, Co2VO4, can be attractive anode material for fast-charging LIBs due to its high capacity (~ 1000 mAh g−1) and safe lithiation potential (~ 0.65 V vs. Li+/Li). The Li+ diffusion coefficient of Co2VO4 is evaluated by theoretical calculation to be as high as 3.15 × 10–10 cm2 s−1, proving Co2VO4 a promising anode in fast-charging LIBs. A hexagonal porous Co2VO4 nanodisk (PCVO ND) structure is designed accordingly, featuring a high specific surface area of 74.57 m2 g−1 and numerous pores with a pore size of 14 nm. This unique structure succeeds in enhancing Li+ and electron transfer, leading to superior fast-charging performance than current commercial anodes. As a result, the PCVO ND shows a high initial reversible capacity of 911.0 mAh g−1 at 0.4 C, excellent fast-charging capacity (344.3 mAh g−1 at 10 C for 1000 cycles), outstanding long-term cycling stability (only 0.024% capacity loss per cycle at 10 C for 1000 cycles), confirming the commercial feasibility of PCVO ND in fast-charging LIBs.


2021 ◽  
pp. 163342
Author(s):  
Yuanfa Yan ◽  
Ximing Lu ◽  
Yuexian Li ◽  
Jian Song ◽  
Qinghua Tian ◽  
...  

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