High-Efficiency and Stable Organic Solar Cells Enabled by Dual Cathode Buffer Layers

2018 ◽  
Vol 10 (6) ◽  
pp. 5682-5692 ◽  
Author(s):  
Zhaoxiang Huai ◽  
Lixin Wang ◽  
Yansheng Sun ◽  
Rui Fan ◽  
Shahua Huang ◽  
...  
2021 ◽  
Vol 95 (3) ◽  
pp. 30201
Author(s):  
Xi Guan ◽  
Yufei Wang ◽  
Shang Feng ◽  
Jidong Zhang ◽  
Qingqing Yang ◽  
...  

Organic solar cells (OSCs) have been fabricated using cathode buffer layers based on bathocuproine (BCP) and 4,4'-N,N'-dicarbazole-biphenyl (CBP). It is found that despite nearly same power conversion efficiencies, the bilayer of BCP/CBP shows increased thermal stability of device than the monolayer of BCP, mostly because upper CBP thin film stabilizes under BCP thin film. The mixed layer of BCP:CBP gives slightly decreased efficiency than BCP and BCP/CBP, mostly because the electron mobility of the OSC using BCP:CBP is decreased than those using BCP and BCP/CBP. However, the BCP:CBP increases thermal stability of device than BCP and BCP/CBP, ascribed to that the BCP and CBP effectively inhibit reciprocal tendencies of crystallizations in the mixed layer. Moreover, the BCP:CBP improves the light stability of device than the BCP and BCP/CBP, because the energy transfer from BCP to CBP in in the mixed layer effectively decelerates the photodegradation of BCP. We provide a facial method to improve the stabilities of cathode buffer layers against heat and light, beneficial to the commercial development of OSCs.


2012 ◽  
Vol 100 (18) ◽  
pp. 183301 ◽  
Author(s):  
Miles C. Barr ◽  
Chiara Carbonera ◽  
Riccardo Po ◽  
Vladimir Bulović ◽  
Karen K. Gleason

2016 ◽  
Vol 4 (46) ◽  
pp. 10820-10826 ◽  
Author(s):  
Jiantai Wang ◽  
Chi Yan ◽  
Xiaoqin Zhang ◽  
Xiaofei Zhao ◽  
Yingying Fu ◽  
...  

A kind of solution-processible gallium-doped ZnO nanoparticle is used as a cathode interfacial layer to fabricate polymer solar cells.


Solar RRL ◽  
2020 ◽  
Vol 4 (10) ◽  
pp. 2000241
Author(s):  
Geedhika K. Poduval ◽  
Leiping Duan ◽  
Md. Anower Hossain ◽  
Borong Sang ◽  
Yu Zhang ◽  
...  

2021 ◽  
Vol 33 (18) ◽  
pp. 2170142
Author(s):  
Ming Zhang ◽  
Lei Zhu ◽  
Tianyu Hao ◽  
Guanqing Zhou ◽  
Chaoqun Qiu ◽  
...  

2011 ◽  
Vol 21 (39) ◽  
pp. 15587 ◽  
Author(s):  
Somnath Dey ◽  
Paola Vivo ◽  
Alexander Efimov ◽  
Helge Lemmetyinen

2021 ◽  
Vol 31 (16) ◽  
pp. 2010172
Author(s):  
Jiaming Huang ◽  
Zhiwei Ren ◽  
Yaokang Zhang ◽  
Kuan Liu ◽  
Hengkai Zhang ◽  
...  

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Juanyong Wan ◽  
Yonggao Xia ◽  
Junfeng Fang ◽  
Zhiguo Zhang ◽  
Bingang Xu ◽  
...  

AbstractNonfullerene organic solar cells (OSCs) have achieved breakthrough with pushing the efficiency exceeding 17%. While this shed light on OSC commercialization, high-performance flexible OSCs should be pursued through solution manufacturing. Herein, we report a solution-processed flexible OSC based on a transparent conducting PEDOT:PSS anode doped with trifluoromethanesulfonic acid (CF3SO3H). Through a low-concentration and low-temperature CF3SO3H doping, the conducting polymer anodes exhibited a main sheet resistance of 35 Ω sq−1 (minimum value: 32 Ω sq−1), a raised work function (≈ 5.0 eV), a superior wettability, and a high electrical stability. The high work function minimized the energy level mismatch among the anodes, hole-transporting layers and electron-donors of the active layers, thereby leading to an enhanced carrier extraction. The solution-processed flexible OSCs yielded a record-high efficiency of 16.41% (maximum value: 16.61%). Besides, the flexible OSCs afforded the 1000 cyclic bending tests at the radius of 1.5 mm and the long-time thermal treatments at 85 °C, demonstrating a high flexibility and a good thermal stability.


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