Aggregation-Induced Emission Enhancement from Disilane-Bridged Donor–Acceptor–Donor Luminogens Based on the Triarylamine Functionality

2018 ◽  
Vol 10 (15) ◽  
pp. 12164-12172 ◽  
Author(s):  
Tsukasa Usuki ◽  
Masaki Shimada ◽  
Yoshinori Yamanoi ◽  
Tatsuhiko Ohto ◽  
Hirokazu Tada ◽  
...  
2017 ◽  
Vol 5 (30) ◽  
pp. 7436-7440 ◽  
Author(s):  
Ezhakudiyan Ravindran ◽  
Narayanasastri Somanathan

The rational design of an efficient and thermally stable non-doped red fluorophore material with tunable AIEE and ICT characteristics triggers enhanced OLED performances.


2019 ◽  
Vol 72 (5) ◽  
pp. 369 ◽  
Author(s):  
Ying Liu ◽  
Yuqi Cao ◽  
Xue Li ◽  
Yang Li ◽  
Bowei Wang

Four donor–acceptor (D-A) type phenothiazine derivatives were designed and synthesized and all of them exhibited an aggregation-induced emission enhancement (AIEE) effect and red-shifted piezofluorochromic (PFC) behaviour. Moreover, it was found that the compound containing a shorter alkyl chain displayed more remarkable PFC properties. This result was probably ascribed to highly twisted conformations which can lead to loose solid molecular packing with cavities and weak interactions. After they were pressed, the planarization of the molecular conformation increased and molecular conjugation degree enhanced, resulting in a red-shift in the photoluminescence spectrum. In addition, optimized geometric structures indicate that the compound with a longer alkyl chain has a more planer geometric structure, which leads to a smaller bathochromic shift upon grinding. In summary, we provide a new path to regulate the PFC behaviours of fluorescent materials by changing the length of their substituted alkyl chain.


2017 ◽  
Vol 196 ◽  
pp. 163-176 ◽  
Author(s):  
Cunfang Feng ◽  
Jinyu Li ◽  
Xiao Han ◽  
Xin He ◽  
Liqun Liu ◽  
...  

A donor–acceptor molecule, PICNDSB, with cyclopenta[b]indole as the donor and (1,4-phenylene)bis(3-phenylacrylonitrile) as the acceptor, is designed and synthesized. PICNDSB shows typical aggregation-induced emission characteristics. The photoluminescence quantum yield of PICNDSB in dilute THF was only 0.7% and reaches 51.4% in the solid state. Compared with its analogue CzCNDSB, PICNDSB possesses stronger intramolecular charge transfer properties, as revealed from CV measurements, theoretical calculations, and their fluorescence behaviors. Correspondingly, the relatively more efficient electron-donating terminal group of cyclopenta[b]indole endows the molecule with a much higher two-photon absorption cross section of 1286 GM compared to CzCNDSB (357 GM).


Author(s):  
Mykhaylo A. Potopnyk ◽  
Mykola Kravets ◽  
Roman Luboradzki ◽  
Dmytro Volyniuk ◽  
Volodymyr Sashuk ◽  
...  

Two novel AIE-active donor–acceptor organoboron complexes with a carbazole donor unit are developed and their morphology-dependent solid-state fluorescence properties are established.


2021 ◽  
pp. 109452
Author(s):  
Chuan-Zeng Wang ◽  
Ze-Dong Yu ◽  
Wen-Xuan Zhao ◽  
Kai Yang ◽  
Yuki Noda ◽  
...  

2014 ◽  
Vol 202 ◽  
pp. 209-216 ◽  
Author(s):  
Gaobin Zhang ◽  
Aixiang Ding ◽  
Yao Zhang ◽  
Longmei Yang ◽  
Lin Kong ◽  
...  

RSC Advances ◽  
2014 ◽  
Vol 4 (107) ◽  
pp. 62684-62688 ◽  
Author(s):  
Priyabrata Roy ◽  
Debabrata Jana ◽  
Ashis Kundu ◽  
Animesh Pramanik

Sign in / Sign up

Export Citation Format

Share Document