Transient Mass and Thermal Transport during Methane Adsorption into the Metal–Organic Framework HKUST-1

2018 ◽  
Vol 10 (3) ◽  
pp. 2400-2406 ◽  
Author(s):  
Hasan Babaei ◽  
Alan J. H. McGaughey ◽  
Christopher E. Wilmer
Keyword(s):  
Thermal Transport ◽  
Metal Organic Framework ◽  
Methane Adsorption ◽  
Metal Organic ◽  
Organic Framework

Enhanced electrical properties and restrained thermal transport in p- and n-type thermoelectric metal–organic framework hybrids

2021 ◽  
Vol 9 (1) ◽  
pp. 310-319
Author(s):  
Xia Qi ◽  
Yizhuo Wang ◽  
Kuncai Li ◽  
Jing Wang ◽  
Hao-Li Zhang ◽  
...  
Keyword(s):  
Electrical Properties ◽  
Thermal Transport ◽  
Transport Model ◽  
Metal Organic Framework ◽  
Parallel Transport ◽  
Metal Organic ◽  
Organic Framework

σ, S, and k match well with a parallel transport model in the hybrids.

Methane Adsorption on the Metal–Organic Framework Structure Al-BTC

2019 ◽  
Vol 55 (1) ◽  
pp. 9-14 ◽  
Author(s):  
M. K. Knyazeva ◽  
A. Yu. Tsivadze ◽  
O. V. Solovtsova ◽  
A. A. Fomkin ◽  
A. A. Pribylov ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Methane Adsorption ◽  
Framework Structure ◽  
Metal Organic ◽  
Organic Framework

Methane Adsorption on Cu-BTC110 Metal-Organic Framework

2019 ◽  
Vol 64 (12) ◽  
pp. 1507-1512
Author(s):  
M. K. Knyazeva ◽  
O. V. Solovtsova ◽  
A. Yu. Tsivadze ◽  
A. A. Fomkin ◽  
A. V. Shkolin ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Methane Adsorption ◽  
Metal Organic ◽  
Organic Framework

Experimental and Theoretical Studies of Supercritical Methane Adsorption in the MIL-53(Al) Metal Organic Framework

2011 ◽  
Vol 115 (42) ◽  
pp. 20628-20638 ◽  
Author(s):  
Andriy Lyubchyk ◽  
Isabel A. A. C. Esteves ◽  
Fernando J. A. L. Cruz ◽  
José P. B. Mota
Keyword(s):  
Metal Organic Framework ◽  
Methane Adsorption ◽  
Theoretical Studies ◽  
Metal Organic ◽  
Experimental And Theoretical Studies ◽  
Organic Framework

Water Cluster Confinement and Methane Adsorption in the Hydrophobic Cavities of a Fluorinated Metal–Organic Framework

2013 ◽  
Vol 135 (34) ◽  
pp. 12615-12626 ◽  
Author(s):  
Nour Nijem ◽  
Pieremanuele Canepa ◽  
Ushasree Kaipa ◽  
Kui Tan ◽  
Katy Roodenko ◽  
...  
Keyword(s):  
Water Cluster ◽  
Metal Organic Framework ◽  
Methane Adsorption ◽  
Metal Organic ◽  
Organic Framework

Multifunctional metal–organic framework heterostructures for enhanced cancer therapy

2021 ◽  
Author(s):  
Jintong Liu ◽  
Jing Huang ◽  
Lei Zhang ◽  
Jianping Lei
Keyword(s):  
Cancer Therapy ◽  
General Principle ◽  
Biomedical Applications ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Functional Modulation ◽  
Organic Framework

We review the general principle of the design and functional modulation of nanoscaled MOF heterostructures, and biomedical applications in enhanced therapy.

Magnetic Ordering via Itinerant Ferromagnetism in a Metal-Organic Framework

2020 ◽  
Author(s):  
Jesse Park ◽  
Brianna Collins ◽  
Lucy Darago ◽  
Tomce Runcevski ◽  
Michael Aubrey ◽  
...  
Keyword(s):  
Charge Transport ◽  
Magnetic Order ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Magnetic Ordering ◽  
Double Exchange ◽  
Itinerant Ferromagnetism ◽  
Organic Solids ◽  
Metal Organic ◽  
Organic Framework

<b>Materials that combine magnetic order with other desirable physical attributes offer to revolutionize our energy landscape. Indeed, such materials could find transformative applications in spintronics, quantum sensing, low-density magnets, and gas separations. As a result, efforts to design multifunctional magnetic materials have recently moved beyond traditional solid-state materials to metal–organic solids. Among these, metal–organic frameworks in particular bear structures that offer intrinsic porosity, vast chemical and structural programmability, and tunability of electronic properties. Nevertheless, magnetic order within metal–organic frameworks has generally been limited to low temperatures, owing largely to challenges in creating strong magnetic exchange in extended metal–organic solids. Here, we employ the phenomenon of itinerant ferromagnetism to realize magnetic ordering at <i>T</i><sub>C</sub> = 225 K in a mixed-valence chromium(II/III) triazolate compound, representing the highest ferromagnetic ordering temperature yet observed in a metal–organic framework. The itinerant ferromagnetism is shown to proceed via a double-exchange mechanism, the first such observation in any metal–organic material. Critically, this mechanism results in variable-temperature conductivity with barrierless charge transport below <i>T</i><sub>C</sub> and a large negative magnetoresistance of 23% at 5 K. These observations suggest applications for double-exchange-based coordination solids in the emergent fields of magnetoelectrics and spintronics. Taken together, the insights gleaned from these results are expected to provide a blueprint for the design and synthesis of porous materials with synergistic high-temperature magnetic and charge transport properties. </b>

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