Effect of Non-fullerene Acceptors’ Side Chains on the Morphology and Photovoltaic Performance of Organic Solar Cells

2017 ◽  
Vol 9 (39) ◽  
pp. 33906-33912 ◽  
Author(s):  
Cai’e Zhang ◽  
Shiyu Feng ◽  
Yahui Liu ◽  
Ran Hou ◽  
Zhe Zhang ◽  
...  
2020 ◽  
Vol 02 (01) ◽  
pp. 026-032
Author(s):  
Chen Yang ◽  
Liu Yuan ◽  
Ruimin Zhou ◽  
Zhen Wang ◽  
Jianqi Zhang ◽  
...  

The molecular stacking assembly in the active layer plays a significant role in the photovoltaic performance of organic solar cells (OSCs). Here, we report two new small molecular donors with different side chains, FBT-O and FBT-H, and their corresponding fullerene-based OSCs. A slight change in the side chains led to a big difference in the power conversion efficiencies (PCEs). Although the molecular structures of the two donors are similar to each other, PCEs of the devices based on FBT-O were almost three times higher than those of the devices based on FBT-H, with manifold short-circuit current density, fill factor, as well as three orders of magnitude enhancement in the hole mobility. The difference in their single crystal structures was thoroughly investigated, whereby the FBT-O exhibited better planarity leading to appropriate phase separation and domain size. Furthermore, two-dimensional grazing-incidence wide-angle X-ray scattering results of the blend films revealed that the two donors retained a similar stacking structure as compared to the single-crystal structures, thus, establishing a clear relationship between the molecular stacking structure and the device performance.


2017 ◽  
Vol 5 (4) ◽  
pp. 937-942 ◽  
Author(s):  
Xue Gong ◽  
Guangwu Li ◽  
Shiyu Feng ◽  
Liangliang Wu ◽  
Yahui Liu ◽  
...  

The side chains of polymers had a great influence on their molecular packing, energy level, blend morphology and photovoltaic performance. The PCEs of 7.28% and 1.55% were obtained for alkoxy and alkylthio-substituted polymer based non-fullerene solar cells, respectively.


RSC Advances ◽  
2018 ◽  
Vol 8 (69) ◽  
pp. 39231-39240
Author(s):  
N. A. Mica ◽  
S. A. J. Almahmoud ◽  
L. Krishnan Jagadamma ◽  
G. Cooke ◽  
I. D. W. Samuel

The chemical nature of the acceptor side chain plays an important role in the processability and photovoltaic performance of EDOT-based small molecule donors.


Author(s):  
Xudong Jiang ◽  
Wenyue Xue ◽  
Wenbin Lai ◽  
Dongdong Xia ◽  
Qiaomei Chen ◽  
...  

In this work, the effect of alky side units of double-cable conjugated polymers on the photovoltaic performance of single-component organic solar cells (SCOSCs) was systematically studied. Four double-cable conjugated polymers...


2015 ◽  
Vol 5 (20) ◽  
pp. n/a-n/a ◽  
Author(s):  
Jens Adams ◽  
Michael Salvador ◽  
Luca Lucera ◽  
Stefan Langner ◽  
George D. Spyropoulos ◽  
...  

2010 ◽  
Vol 211 (8) ◽  
pp. 948-955 ◽  
Author(s):  
Weiwei Li ◽  
Yang Han ◽  
Yulan Chen ◽  
Cuihong Li ◽  
Bingsong Li ◽  
...  

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