An Unprecedented Case: A Low Specific Surface Area Anatase/N-Doped Carbon Nanocomposite Derived from a New Single Source Precursor Affords Fast and Stable Lithium Storage

Desulfurisation of atmospheric distillation gasoline and gas oil was performed by adsorption process on Fe/ bentonite. The adsorbent was characterized by determining the adsorption isotherms, specific surface area, pore volume and average pore diameter. Adsorption experiments of atmospheric distillation gasoline and gas oil were performed in continuous system at 280�320oC, 5 atm and volume hourly space velocities of 1�2 h-1. The efficiency of adsorption on Fe / bentonite was better at desulphurisation of gasoline versus gas oil.

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Nanoporous Quasi-High-Entropy Alloy Microspheres

Metals ◽

10.3390/met9030345 ◽

2019 ◽

Vol 9 (3) ◽

pp. 345 ◽

Cited By ~ 3

Author(s):

Lianzan Yang ◽

Yongyan Li ◽

Zhifeng Wang ◽

Weimin Zhao ◽

Chunling Qin

Keyword(s):

Mechanical Properties ◽

Solid Solution ◽

Specific Surface ◽

Surface Area ◽

Specific Surface Area ◽

High Specific Surface Area ◽

High Entropy Alloy ◽

Face Centered Cubic ◽

High Entropy ◽

Hierarchical Porous

High-entropy alloys (HEAs) present excellent mechanical properties. However, the exploitation of chemical properties of HEAs is far less than that of mechanical properties, which is mainly limited by the low specific surface area of HEAs synthesized by traditional methods. Thus, it is vital to develop new routes to fabricate HEAs with novel three-dimensional structures and a high specific surface area. Herein, we develop a facile approach to fabricate nanoporous noble metal quasi-HEA microspheres by melt-spinning and dealloying. The as-obtained nanoporous Cu30Au23Pt22Pd25 quasi-HEA microspheres present a hierarchical porous structure with a high specific surface area of 69.5 m2/g and a multiphase approximatively componential solid solution characteristic with a broad single-group face-centered cubic XRD pattern, which is different from the traditional single-phase or two-phase solid solution HEAs. To differentiate, these are named quasi-HEAs. The synthetic strategy proposed in this paper opens the door for the synthesis of porous quasi-HEAs related materials, and is expected to promote further applications of quasi-HEAs in various chemical fields.

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Experimental Study on Activated Carbon-MIL-101(Cr) Composites for Ethanol Vapor Adsorption

Materials ◽

10.3390/ma14143811 ◽

2021 ◽

Vol 14 (14) ◽

pp. 3811

Author(s):

Zhongbao Liu ◽

Jiayang Gao ◽

Xin Qi ◽

Zhi Zhao ◽

Han Sun

Keyword(s):

Activated Carbon ◽

Specific Surface ◽

Surface Area ◽

Specific Surface Area ◽

Ethanol Vapor ◽

Future Application ◽

Working Fluid ◽

Relative Pressure ◽

Adsorption Refrigeration ◽

Vapor Adsorption

In this study, the hydrothermal method was used to synthesize MIL-101(Cr), and activated carbon (AC) with different content was incorporated in to MIL-101(Cr), thereby obtaining AC-MIL-101(Cr) composite material with a huge specific surface area. The physical properties of MIL-101(Cr) and AC-MIL-101(Cr) were characterized by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), nitrogen adsorption and desorption and specific surface area testing, and ethanol vapor adsorption performance testing. The results show that with the increase of activated carbon content, the thermal stability of AC-MIL-101(Cr) is improved. Compared with the pure sample, the BET specific surface area and pore volume of AC-MIL-101(Cr) have increased; In the relative pressure range of 0–0.4, the saturated adsorption capacity of AC-MIL-101(Cr) to ethanol vapor decreases slightly. It is lower than MIL-101(Cr), but its adsorption rate is improved. Therefore, AC-MIL-101(Cr)/ethanol vapor has a good application prospect in adsorption refrigeration systems. The exploration of AC-MIL-101(Cr) composite materials in this paper provides a reference for the future application of carbon-based/MOFS composite adsorbent/ethanol vapor working fluid in adsorption refrigeration.

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