Highly Efficient Catalytic Hydrogen Evolution from Ammonia Borane Using the Synergistic Effect of Crystallinity and Size of Noble-Metal-Free Nanoparticles Supported by Porous Metal–Organic Frameworks

2017 ◽  
Vol 9 (12) ◽  
pp. 10759-10767 ◽  
Author(s):  
Penglong Liu ◽  
Xiaojun Gu ◽  
Kai Kang ◽  
Hao Zhang ◽  
Jia Cheng ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Hydrogen Evolution ◽  
Noble Metal ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Ammonia Borane ◽  
Metal Free ◽  
Metal Organic ◽  
Catalytic Hydrogen ◽  
Catalytic Hydrogen Evolution

Synergistic effect of a noble metal free Ni(OH)2 co-catalyst and a ternary ZnIn2S4/g-C3N4 heterojunction for enhanced visible light photocatalytic hydrogen evolution

2020 ◽  
Vol 4 (2) ◽  
pp. 750-759 ◽  
Author(s):  
Lakshmana Reddy Nagappagari ◽  
Soumadri Samanta ◽  
Nidhi Sharma ◽  
Venugopala Rao Battula ◽  
Kamalakannan Kailasam
Keyword(s):  
Reaction Mechanism ◽  
Hydrogen Production ◽  
Synergistic Effect ◽  
Visible Light ◽  
Hydrogen Evolution ◽  
Noble Metal ◽  
Visible Light Irradiation ◽  
Co Catalyst ◽  
Metal Free ◽  
Visible Light Photocatalytic

A plausible reaction mechanism for photocatalytic hydrogen production by employing a ZnIn2S4/g-C3N4@Ni(OH)2 heterojunction photocatalyst under visible light irradiation.

Noble metal-free integrated UiO-66-PANI-Co3O4 catalyst for visible-light-induced H2 production

2019 ◽  
Vol 55 (96) ◽  
pp. 14494-14497 ◽  
Author(s):  
Ajay K. Singh ◽  
Spandana Gonuguntla ◽  
Bhushan Mahajan ◽  
Ujjwal Pal
Keyword(s):  
Charge Carrier ◽  
Visible Light ◽  
Noble Metal ◽  
Crystal Engineering ◽  
Metal Organic Frameworks ◽  
H2 Production ◽  
Electron Hole ◽  
Metal Free ◽  
Metal Organic

The discriminate etching chemistry (crystal engineering) of metal–organic frameworks (MOFs) offers promising opportunities for tailoring electron–hole separation, and charge-carrier utilization plays a central role in photocatalysis.

scholarly journals Synergistic effect of Co–Ni co-bridging with MoS2 nanosheets for enhanced electrocatalytic hydrogen evolution reactions

RSC Advances ◽  
2018 ◽  
Vol 8 (7) ◽  
pp. 3374-3380 ◽  
Author(s):  
Ammar Bin Yousaf ◽  
Muhammad Imran ◽  
Muhammad Farooq ◽  
Peter Kasak
Keyword(s):  
Synergistic Effect ◽  
Hydrogen Evolution ◽  
Noble Metal ◽  
Mos2 Nanosheets ◽  
Metal Free ◽  
Hydrogen Evolution Reactions

A noble-metal-free Co–Ni/MoS2 nanocomposite was synthesized, which showed enhanced electrocatalytic hydrogen evolution performance.

Electroreduction of a CoIIcoordination complex producing a metal–organic film with high performance toward electrocatalytic hydrogen evolution

2018 ◽  
Vol 6 (40) ◽  
pp. 19590-19603 ◽  
Author(s):  
Leticia S. Bezerra ◽  
Persiely P. Rosa ◽  
Guilherme V. Fortunato ◽  
Lucas Pizzuti ◽  
Gleison A. Casagrande ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Noble Metal ◽  
High Performance ◽  
High Stability ◽  
Organic Film ◽  
Metal Free ◽  
Metal Organic

Remarkable, high stability, simple, and inexpensive noble metal-free materials as electrocatalysts with the best TOF (312 900 s−1, corrected by Faraday efficiency) for H2production.

scholarly journals Co@NH2-MIL-125(Ti): cobaloxime-derived metal–organic framework-based composite for light-driven H2 production

2015 ◽  
Vol 8 (1) ◽  
pp. 364-375 ◽  
Author(s):  
M. A. Nasalevich ◽  
R. Becker ◽  
E. V. Ramos-Fernandez ◽  
S. Castellanos ◽  
S. L. Veber ◽  
...  
Keyword(s):  
Visible Light ◽  
Hydrogen Evolution ◽  
Noble Metal ◽  
Cobalt Catalyst ◽  
Metal Organic Framework ◽  
H2 Production ◽  
Light Illumination ◽  
Metal Free ◽  
Visible Light Illumination ◽  
Metal Organic

Encapsulation of cobalt catalyst within the pores of a photoresponsive MOF results in very efficient and fully recyclable noble metal-free photocatalyst for hydrogen evolution from water under visible light illumination.

Tailoring three-dimensional porous cobalt phosphides templated from bimetallic metal–organic frameworks as precious metal-free catalysts towards the dehydrogenation of ammonia-borane

2019 ◽  
Vol 7 (14) ◽  
pp. 8277-8283 ◽  
Author(s):  
Chun-Chao Hou ◽  
Qian-Qian Chen ◽  
Kai Li ◽  
Chuan-Jun Wang ◽  
Cheng-Yun Peng ◽  
...  
Keyword(s):  
Precious Metal ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Catalytic Efficiency ◽  
Ammonia Borane ◽  
Metal Free ◽  
Metal Organic

Three-dimensional porous CoP@CNF materials derived from bimetallic MOFs exhibit superior catalytic efficiency towards the ammonia-borane hydrolysis.

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