Effect of Energy Alignment, Electron Mobility, and Film Morphology of Perylene Diimide Based Polymers as Electron Transport Layer on the Performance of Perovskite Solar Cells

2017 ◽  
Vol 9 (12) ◽  
pp. 10983-10991 ◽  
Author(s):  
Qiang Guo ◽  
Yingxue Xu ◽  
Bo Xiao ◽  
Bing Zhang ◽  
Erjun Zhou ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Electron Mobility ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Perylene Diimide ◽  
Electron Transport Layer ◽  
Film Morphology

scholarly journals Fabrication of SnO2 by RF magnetron sputtering for electron transport layer of planar perovskite solar cells

2021 ◽  
Vol 2145 (1) ◽  
pp. 012027
Author(s):  
R Thanimkan ◽  
B Namnuan ◽  
S Chatraphorn
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Magnetron Sputtering ◽  
Electron Mobility ◽  
Perovskite Solar Cells ◽  
Rf Magnetron Sputtering ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
High Electron ◽  
High Electron Mobility

Abstract The requirements of electron transport layer (ETL) for high efficiency Perovskite solar cells (PSCs) are, for example, appropriate band energy alignment, high electron mobility, high optical transmittance, high stability, and easy processing. SnO2 has attracted more attention as ETL for PSCs because it has diverse advantages, e.g., wide bandgap energy, excellent optical and chemical stability, high transparency, high electron mobility, and easy preparation. The SnO2 ETL was fabricated by RF magnetron sputtering technique to ensure the chemical composition and uniform layer thickness when compared to the use of chemical solution via spin-coating method. The RF power was varied from 60 - 150 W. The Ar sputtering gas pressure was varied from 1 × 10−3 - 6 × 10−3 mbar while keeping O2 partial pressure at 1 × 10−4 mbar. The thickness of SnO2 layer decreases as the Ar gas pressure increases resulting in the increase of sheet resistance. The surface morphology and optical transmission of the SnO2 ETL were investigated. It was found that the optimum thickness of SnO2 layer was approximately 35 - 40 nm. The best device shows Jsc = 27.4 mA/cm2, Voc = 1.03 V, fill factor = 0.63, and efficiency = 17.7%.

scholarly journals New generation perovskite solar cells with solution-processed amino-substituted perylene diimide derivative as electron-transport layer

2016 ◽  
Vol 4 (22) ◽  
pp. 8724-8733 ◽  
Author(s):  
Hua Zhang ◽  
Lingwei Xue ◽  
Junbo Han ◽  
Yong Qing Fu ◽  
Yan Shen ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Perylene Diimide ◽  
Electron Transport Layer ◽  
Solution Processed ◽  
Planar Heterojunction ◽  
New Generation ◽  
First Time

In this study, for the first time, we introduced amino-substituted perylene diimide derivative (N-PDI) as an alternative electron transport layer (ETL) to replace the commonly used TiO2 in planar heterojunction perovskite solar cells.

Achieving efficient inverted perovskite solar cells with excellent electron transport and stability by employing a ladder-conjugated perylene diimide dimer

2019 ◽  
Vol 7 (42) ◽  
pp. 24191-24198 ◽  
Author(s):  
Helin Wang ◽  
Fu Yang ◽  
Yuren Xiang ◽  
Shuai Ye ◽  
Xiao Peng ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Perylene Diimide ◽  
Electron Transport Layer

A ladder-conjugated perylene diimide dimer containing an indacenodithiophene unit was developed and used as a high efficiency electron transport layer in inverted perovskite solar cells.

A perylene diimide-based electron transport layer enabling efficient inverted perovskite solar cells

2018 ◽  
Vol 6 (35) ◽  
pp. 16868-16873 ◽  
Author(s):  
Kui Jiang ◽  
Fei Wu ◽  
Hui Yu ◽  
Yanqing Yao ◽  
Guangye Zhang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Perylene Diimide ◽  
Electron Transport Layer ◽  
Interfacial Material

High efficiencies of 16.29% and 18.78% are obtained in inverted PSCs using TPE-PDI4 as an electron transporting material and interfacial material, respectively.

scholarly journals Ultrathin and compact electron transport layer made from novel water-dispersed Fe3O4 nanoparticles to accomplish UV-stable perovskite solar cells

2021 ◽  
Author(s):  
Song Fang ◽  
Bo Chen ◽  
Bangkai Gu ◽  
Linxing Meng ◽  
Hao Lu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Electron Transport ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Perovskite Material ◽  
Main Factors ◽  
Induced Decomposition

UV induced decomposition of perovskite material is one of main factors to severely destroy perovskite solar cells for instability. Here we report a UV stable perovskite solar cell with a...

scholarly journals The Influence of the Thickness of Compact TiO2 Electron Transport Layer on the Performance of Planar CH3NH3PbI3 Perovskite Solar Cells

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3295
Author(s):  
Andrzej Sławek ◽  
Zbigniew Starowicz ◽  
Marek Lipiński
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Short Circuit ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Precursor Solution ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Transport Layer ◽  
Electron Transport Layer

In recent years, lead halide perovskites have attracted considerable attention from the scientific community due to their exceptional properties and fast-growing enhancement for solar energy harvesting efficiency. One of the fundamental aspects of the architecture of perovskite-based solar cells (PSCs) is the electron transport layer (ETL), which also acts as a barrier for holes. In this work, the influence of compact TiO2 ETL on the performance of planar heterojunction solar cells based on CH3NH3PbI3 perovskite was investigated. ETLs were deposited on fluorine-doped tin oxide (FTO) substrates from a titanium diisopropoxide bis(acetylacetonate) precursor solution using the spin-coating method with changing precursor concentration and centrifugation speed. It was found that the thickness and continuity of ETLs, investigated between 0 and 124 nm, strongly affect the photovoltaic performance of PSCs, in particular short-circuit current density (JSC). Optical and topographic properties of the compact TiO2 layers were investigated as well.

Electron-transport-layer-free two-dimensional perovskite solar cells based on a flexible poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) cathode

2021 ◽  
Author(s):  
Zhihai Liu ◽  
Lei Wang ◽  
Chongyang Xu ◽  
Xiaoyin Xie
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Two Dimensional ◽  
High Power Conversion Efficiency ◽  
Long Term Stability

Recently, Ruddlesden–Popper two-dimensional (2D) perovskite solar cells (PSCs) have been intensively studied, owing to their high power conversion efficiency (PCE) and excellent long-term stability. In this work, we fabricated electron-transport-layer-free...

scholarly journals Magnesium doped TiO2 as an efficient electron transport layer in perovskite solar cells

2021 ◽  
pp. 101101
Author(s):  
Zafar Arshad ◽  
Asif Hussain Khoja ◽  
Sehar Shakir ◽  
Asif Afzal ◽  
M.A. Mujtaba ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Doped Tio2

scholarly journals Low-temperature-processed metal oxide electron transport layers for efficient planar perovskite solar cells

Rare Metals ◽  
2021 ◽  
Author(s):  
Jia-Xing Song ◽  
Xin-Xing Yin ◽  
Zai-Fang Li ◽  
Yao-Wen Li
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Low Temperature ◽  
Metal Oxide ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Future Research ◽  
Low Temperature Preparation

Abstract As a promising photovoltaic technology, perovskite solar cells (pero-SCs) have developed rapidly over the past few years and the highest power conversion efficiency is beyond 25%. Nowadays, the planar structure is universally popular in pero-SCs due to the simple processing technology and low-temperature preparation. Electron transport layer (ETL) is verified to play a vital role in the device performance of planar pero-SCs. Particularly, the metal oxide (MO) ETL with low-cost, superb versatility, and excellent optoelectronic properties has been widely studied. This review mainly focuses on recent developments in the use of low-temperature-processed MO ETLs for planar pero-SCs. The optical and electronic properties of widely used MO materials of TiO2, ZnO, and SnO2, as well as the optimizations of these MO ETLs are briefly introduced. The commonly used methods for depositing MO ETLs are also discussed. Then, the applications of different MO ETLs on pero-SCs are reviewed. Finally, the challenge and future research of MO-based ETLs toward practical application of efficient planar pero-SCs are proposed. Graphical abstract

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