Preparation of Main-Chain Polymers Based on Novel Monomers with D−π–A Structure for Application in Organic Second-Order Nonlinear Optical Materials with Good Long-Term Stability

2017 ◽  
Vol 9 (12) ◽  
pp. 10366-10370 ◽  
Author(s):  
Canbin Ouyang ◽  
Jialei Liu ◽  
Qi Liu ◽  
Yuan Li ◽  
Dongdong Yan ◽  
...  
Keyword(s):  
Optical Materials ◽  
Nonlinear Optical ◽  
Main Chain ◽  
Second Order ◽  
Nonlinear Optical Materials ◽  
Term Stability ◽  
Long Term Stability ◽  
Main Chain Polymers

Realization Of Large, Stable Second Order Optical Nonlinearities Through Double-EndCrosslinkable Chromophores

1993 ◽  
Vol 328 ◽  
Author(s):  
C. Xu ◽  
B. Wu ◽  
L. R. Dalton ◽  
Y. Shi ◽  
P. M. Ranon ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Second Order ◽  
Side Chain ◽  
Optical Nonlinearities ◽  
Term Stability ◽  
Long Term Stability

ABSTRACTWe have developed a novel class of double-end crosslinkable (DEC) chromophores. Processible side-chain nonlinear optical (NLO) polymers with crosslinkable groups at the ends of chromophore pendants were synthesized from DEC Monomers. The polymers were processed into good quality films, which were subsequently poled with a corona setup and thermally cured to attain stable noncentrosymmetric order. Using this DEC approach, we have realized large optical nonlinearities (χ(2) = 90–220 pm/V) with long term stability at 125 °C.

Noncentrosymmetric Triazolephthalocyanines as Second-Order Nonlinear Optical Materials

2000 ◽  
Vol 104 (18) ◽  
pp. 4295-4299 ◽  
Author(s):  
Gema Rojo ◽  
Fernando Agulló-López ◽  
Beatriz Cabezón ◽  
Tomás Torres ◽  
Sophie Brasselet ◽  
...  
Keyword(s):  
Optical Materials ◽  
Nonlinear Optical ◽  
Second Order ◽  
Nonlinear Optical Materials

Thermoset Second-Order Nonlinear Optical Materials from a Trifunctionalized Chromophore

1998 ◽  
pp. 288-294
Author(s):  
Youn Soo RA ◽  
Shane S. H. Mao ◽  
Bo Wu ◽  
Lan Guo ◽  
Larry R. Dalton ◽  
...  
Keyword(s):  
Optical Materials ◽  
Nonlinear Optical ◽  
Second Order ◽  
Nonlinear Optical Materials
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