Effects of an Integrated Separator/Electrode Assembly on Enhanced Thermal Stability and Rate Capability of Lithium-Ion Batteries

2017 ◽  
Vol 9 (21) ◽  
pp. 17814-17821 ◽  
Author(s):  
Seokhyeon Gong ◽  
Hyunkyu Jeon ◽  
Hoogil Lee ◽  
Myung-Hyun Ryou ◽  
Yong Min Lee
Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 764 ◽  
Author(s):  
Yanling Li ◽  
Xiang Wang ◽  
Jianyu Liang ◽  
Kuan Wu ◽  
Long Xu ◽  
...  

A zeolite/polyimide composite separator with a spongy-like structure was prepared by phase inversion methods based on heat-resistant polyimide (PI) polymer matrix and ZSM-5 zeolite filler, with the aim to improve the thermal stability and electrochemical properties of corresponding batteries. The separator exhibits enhanced thermal stability and no shrinkage up to 180 °C. The introduction of a certain number of ZSM-5 zeolites endows the composite separator with enhanced wettability and electrolyte uptake, better facilitating the free transport of lithium-ion. Furthermore, the composite separator shows a high ionic conductivity of 1.04 mS cm−1 at 25 °C, and a high decomposition potential of 4.7 V. Compared with the PP separator and pristine PI separator, the ZSM-5/PI composite separator based LiFePO4/Li cells have better rate capability (133 mAh g−1 at 2 C) and cycle performance (145 mAh g-1 at 0.5 C after 50 cycles). These results demonstrate that the ZSM-5/PI composite separator is promising for high-performance and high-safety lithium-ion batteries.


Nanoscale ◽  
2013 ◽  
Vol 5 (8) ◽  
pp. 3298 ◽  
Author(s):  
Min He ◽  
Lixia Yuan ◽  
Xianluo Hu ◽  
Wuxing Zhang ◽  
Jie Shu ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 63012-63016 ◽  
Author(s):  
Yourong Wang ◽  
Wei Zhou ◽  
Liping Zhang ◽  
Guangsen Song ◽  
Siqing Cheng

A SiO2@NiO core–shell electrode exhibits almost 100% coulombic efficiency, excellent cycling stability and rate capability after the first few cycles.


RSC Advances ◽  
2015 ◽  
Vol 5 (53) ◽  
pp. 42922-42930 ◽  
Author(s):  
Diganta Saikia ◽  
Tzu-Hua Wang ◽  
Chieh-Ju Chou ◽  
Jason Fang ◽  
Li-Duan Tsai ◽  
...  

Ordered mesoporous carbons CMK-3 and CMK-8 with different mesostructures are evaluated as anode materials for lithium-ion batteries. CMK-8 possesses higher reversible capacity, better cycling stability and rate capability than CMK-3.


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