Insights into Free Volume Variations across Ion-Exchange Membranes upon Mixed Solvents Uptake by Small and Ultrasmall Angle Neutron Scattering

2017 ◽  
Vol 9 (10) ◽  
pp. 8704-8713 ◽  
Author(s):  
Francois-Marie Allioux ◽  
Christopher J. Garvey ◽  
Christine Rehm ◽  
Blaise L. Tardy ◽  
Raymond Riley Dagastine ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Neutron Scattering ◽  
Free Volume ◽  
Mixed Solvents ◽  
Ion Exchange Membranes

Electrokinetic studies on ion-exchange membranes. I. Transport of nonaqueous and mixed solvents

1975 ◽  
Vol 79 (23) ◽  
pp. 2574-2578 ◽  
Author(s):  
R. P. Rastogi ◽  
Kehar Singh ◽  
Jhulan Singh
Keyword(s):  
Ion Exchange ◽  
Mixed Solvents ◽  
Ion Exchange Membranes

Equilibrium Sorptions in Heterogeneous Ion Exchange Membranes

1992 ◽  
Vol 57 (9) ◽  
pp. 1905-1914
Author(s):  
Miroslav Bleha ◽  
Věra Šumberová
Keyword(s):  
Experimental Data ◽  
Ion Exchange ◽  
Total Content ◽  
Distribution Coefficients ◽  
Exchange Capacity ◽  
Ion Exchange Membranes ◽  
Ion Exchange Capacity ◽  
Equilibrium Sorption ◽  
Inhomogeneity Factor

The equilibrium sorption of uni-univalent electrolytes (NaCl, KCl) in heterogeneous cation exchange membranes with various contents of the ion exchange component and in ion exchange membranes Ralex was investigated. Using experimental data which express the concentration dependence of equilibrium sorption, validity of the Donnan relation for the systems under investigation was tested and values of the Glueckauf inhomogeneity factor for Ralex membranes were determined. Determination of the equilibrium sorption allows the effect of the total content of internal water and of the ion-exchange capacity on the distribution coefficients of the electrolyte to be determined.

Interpolymer ion exchange membranes for CapMix process

Desalination ◽  
2020 ◽  
Vol 482 ◽  
pp. 114384
Author(s):  
Katarzyna Smolinska-Kempisty ◽  
Anna Siekierka ◽  
Marek Bryjak
Keyword(s):  
Ion Exchange ◽  
Ion Exchange Membranes

A comprehensive review on the synthesis and applications of ion exchange membranes

Chemosphere ◽  
2021 ◽  
pp. 130817
Author(s):  
Shanxue Jiang ◽  
Haishu Sun ◽  
Huijiao Wang ◽  
Bradley P. Ladewig ◽  
Zhiliang Yao
Keyword(s):  
Ion Exchange ◽  
Ion Exchange Membranes ◽  
Comprehensive Review

scholarly journals The Influence of Concentration and Temperature on the Membrane Resistance of Ion Exchange Membranes and the Levelised Cost of Hydrogen from Reverse Electrodialysis with Ammonium Bicarbonate

Membranes ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 135
Author(s):  
Yash Dharmendra Raka ◽  
Robert Bock ◽  
Håvard Karoliussen ◽  
Øivind Wilhelmsen ◽  
Odne Stokke Burheim
Keyword(s):  
Ion Exchange ◽  
Waste Heat ◽  
Ammonium Bicarbonate ◽  
Operating Efficiency ◽  
Membrane Thickness ◽  
Ion Exchange Membranes ◽  
Reverse Electrodialysis ◽  
Ohmic Resistance ◽  
Production Of Hydrogen ◽  
The Impact

The ohmic resistances of the anion and cation ion-exchange membranes (IEMs) that constitute a reverse electrodialysis system (RED) are of crucial importance for its performance. In this work, we study the influence of concentration (0.1 M, 0.5 M, 1 M and 2 M) of ammonium bicarbonate solutions on the ohmic resistances of ten commercial IEMs. We also studied the ohmic resistance at elevated temperature 313 K. Measurements have been performed with a direct two-electrode electrochemical impedance spectroscopy (EIS) method. As the ohmic resistance of the IEMs depends linearly on the membrane thickness, we measured the impedance for three different layered thicknesses, and the results were normalised. To gauge the role of the membrane resistances in the use of RED for production of hydrogen by use of waste heat, we used a thermodynamic and an economic model to study the impact of the ohmic resistance of the IEMs on hydrogen production rate, waste heat required, thermochemical conversion efficiency and the levelised cost of hydrogen. The highest performance was achieved with a stack made of FAS30 and CSO Type IEMs, producing hydrogen at 8.48× 10−7 kg mmem−2s−1 with a waste heat requirement of 344 kWh kg−1 hydrogen. This yielded an operating efficiency of 9.7% and a levelised cost of 7.80 € kgH2−1.

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