Simultaneous Nitrogen Doping and Pore Generation in Thermo-Insulating Graphene Films via Colloidal Templating

2016 ◽  
Vol 8 (46) ◽  
pp. 31617-31624 ◽  
Author(s):  
Hyunwoo Bark ◽  
Jeongmin Lee ◽  
Hosun Lim ◽  
Hye Young Koo ◽  
Wonmok Lee ◽  
...  
2019 ◽  
Vol 54 (9) ◽  
pp. 7165-7179 ◽  
Author(s):  
Shaofeng Lin ◽  
Su Ju ◽  
Gang Shi ◽  
Jianwei Zhang ◽  
Yonglyu He ◽  
...  

NANO ◽  
2020 ◽  
Vol 15 (12) ◽  
pp. 2050157
Author(s):  
Shaofeng lin ◽  
Qing Zheng ◽  
Bowen Lei ◽  
Jianwei Zhang ◽  
Dazhi Jiang

Three kinds of diamine monomers [ethylenediamine, butylenediamine and [Formula: see text]-phenylenediamine (PPD)] are adopted to cross-link carboxylated graphene (GP-COOH) sheets through filtration with a vacuum-assisted self-assembly technique, to fabricate highly conductive and excellent electromagnetic interference (EMI) shielding films. XRD spectroscopy of cross-linked graphene films exhibits higher interlayer [Formula: see text]-spacing than the GP-COOH film. Results of FTIR and XPS spectroscopies indicate that diamine monomers are chemically grafted to the GP-COOH sheets through nucleophilic substitution reactions. Compared with that of the GP-COOH film, electrical conductivity of the PPD-cross-linked graphene film (GP-PPD) is remarkably improved from 69.7[Formula: see text]S/cm to 248.6[Formula: see text]S/cm, attributed to the decrease of junction contact resistance between adjacent graphene sheets, nitrogen doping effect and repair of defects. Higher nitrogen content and C/O ratio are observed in the XPS spectra of the GP-PPD film, leading to higher electrical conductivity than the remaining two amine-modified graphene films. The GP-PPD film also demonstrates excellent EMI shielding performance, with EMI shielding effectiveness (SE) of 26.5 dB at a thickness of 12.5[Formula: see text][Formula: see text]m, which is also better than the others. The outstanding EMI performance of the PPD-cross-linked graphene film is mainly ascribed to the enhanced electrical conductivity and modified electronic structure with nitrogen doping.


2012 ◽  
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Author(s):  
C. D. Wang ◽  
M. F. Yuen ◽  
T. W. Ng ◽  
S. K. Jha ◽  
Z. Z. Lu ◽  
...  

ACS Omega ◽  
2021 ◽  
Vol 6 (37) ◽  
pp. 23710-23722
Author(s):  
Nur Hamizah Zainal Ariffin ◽  
Muhammad Aniq Shazni Mohammad Haniff ◽  
Mohd Ismahadi Syono ◽  
Mohd Ambri Mohamed ◽  
Azrul Azlan Hamzah ◽  
...  

2015 ◽  
Vol 30 (6) ◽  
pp. 662 ◽  
Author(s):  
YU Jian-Hua ◽  
XU Li-Li ◽  
ZHANG Wu-Shou ◽  
ZHU Qian-Qian ◽  
WANG Xiao-Xia ◽  
...  

2020 ◽  
Vol 54 (12) ◽  
pp. 1674-1677
Author(s):  
I. A. Eliseyev ◽  
V. Yu. Davydov ◽  
A. N. Smirnov ◽  
S. V. Belov ◽  
A. V. Zubov ◽  
...  
Keyword(s):  

Nano Express ◽  
2020 ◽  
Vol 1 (1) ◽  
pp. 010027
Author(s):  
Cantekin Kaykılarlı ◽  
Deniz Uzunsoy ◽  
Ebru Devrim Şam Parmak ◽  
Mehmet Ferdi Fellah ◽  
Özgen Çolak Çakır

2018 ◽  
Vol 1 (4) ◽  
pp. 1734-1741 ◽  
Author(s):  
Kazuhiko Maeda ◽  
Yuki Tokunaga ◽  
Keisuke Hibino ◽  
Kotaro Fujii ◽  
Hiroyuki Nakaki ◽  
...  

2018 ◽  
Vol 951 ◽  
pp. 012007 ◽  
Author(s):  
A A Lebedev ◽  
V Y Davydov ◽  
D Y Usachov ◽  
S P Lebedev ◽  
A N Smirnov ◽  
...  

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