Supercritical Fluid Facilitated Disintegration of Hexagonal Boron Nitride Nanosheets to Quantum Dots and Its Application in Cells Imaging

2016 ◽  
Vol 8 (29) ◽  
pp. 18647-18651 ◽  
Author(s):  
Pitchai Thangasamy ◽  
Manikandan Santhanam ◽  
Marappan Sathish
CrystEngComm ◽  
2015 ◽  
Vol 17 (31) ◽  
pp. 5895-5899 ◽  
Author(s):  
Pitchai Thangasamy ◽  
Marappan Sathish

A simple, rapid, one-pot method for generating exfoliated surfactant-free few-layered h-boron nitride by supercritical fluid processing is demonstrated. The product was characterized by AFM, TEM and Raman analyses.


2021 ◽  
Vol 44 ◽  
pp. 100475
Author(s):  
Xiaobin Zhu ◽  
Liang Zhang ◽  
Bin Zuo ◽  
Zhengcun Zhou ◽  
Yifei Yang ◽  
...  

2014 ◽  
Vol 140 (20) ◽  
pp. 204701 ◽  
Author(s):  
M. S. Si ◽  
Daqiang Gao ◽  
Dezheng Yang ◽  
Yong Peng ◽  
Z. Y. Zhang ◽  
...  

Nano Energy ◽  
2021 ◽  
pp. 106628
Author(s):  
Ainikulangara Sundaran Bhavya ◽  
Harris Varghese ◽  
Achu Chandran ◽  
Kuzhichalil Peethambharan Surendran

2009 ◽  
Vol 20 (38) ◽  
pp. 385707 ◽  
Author(s):  
Chun Li ◽  
Yoshio Bando ◽  
Chunyi Zhi ◽  
Yang Huang ◽  
Dmitri Golberg

2010 ◽  
Vol 114 (41) ◽  
pp. 17434-17439 ◽  
Author(s):  
Yi Lin ◽  
Tiffany V. Williams ◽  
Wei Cao ◽  
Hani E. Elsayed-Ali ◽  
John W. Connell

2018 ◽  
Vol 32 (06) ◽  
pp. 1850084 ◽  
Author(s):  
Yi-Min Ding ◽  
Jun-Jie Shi ◽  
Min Zhang ◽  
Meng Wu ◽  
Hui Wang ◽  
...  

It is difficult to integrate two-dimensional (2D) graphene and hexagonal boron-nitride (h-BN) in optoelectronic nanodevices, due to the semi-metal and insulator characteristic of graphene and h-BN, respectively. Using the state-of-the-art first-principles calculations based on many-body perturbation theory, we investigate the electronic and optical properties of h-BN nanosheet embedded with graphene dots. We find that C atom impurities doped in h-BN nanosheet tend to phase-separate into graphene quantum dots (QD), and BNC hybrid structure, i.e. a graphene dot within a h-BN background, can be formed. The band gaps of BNC hybrid structures have an inverse relationship with the size of graphene dot. The calculated optical band gaps for BNC structures vary from 4.71 eV to 3.77 eV, which are much smaller than that of h-BN nanosheet. Furthermore, the valence band maximum is located in C atoms bonded to B atoms and conduction band minimum is located in C atoms bonded to N atoms, which means the electron and hole wave functions are closely distributed around the graphene dot. The bound excitons, localized around the graphene dot, determine the optical spectra of the BNC hybrid structures, in which the exciton binding energies decrease with increase in the size of graphene dots. Our results provide an important theoretical basis for the design and development of BNC-based optoelectronic nanodevices.


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