Tunable Electrical Conductivity and Magnetic Property of the Two Dimensional Metal Organic Framework [Cu(TPyP)Cu2(O2CCH3)4]

2016 ◽  
Vol 8 (25) ◽  
pp. 16154-16159 ◽  
Author(s):  
Ananya Sengupta ◽  
Subhadeep Datta ◽  
Chenliang Su ◽  
Tun Seng Herng ◽  
Jun Ding ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Magnetic Property ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Ultrathin Metal-Organic Framework Nanosheets and Devices

2021 ◽  
Author(s):  
AshokKumar Meiyazhagan
Keyword(s):  
Electrical Conductivity ◽  
Metal Organic Framework ◽  
Electronic Devices ◽  
Metal Organic Frameworks ◽  
Two Dimensional ◽  
Conductivity Measurements ◽  
Metal Organic ◽  
Organic Framework

Abstract A few recent findings on ultrathin two-dimensional (2D) metal-organic frameworks (MOFs) were discussed in this spotlight review. MOFs are a class of materials with intriguing properties for possible applications in several fields ranging from catalysis to sensors and functional devices. To date, several synthesis strategies have been explored to derive crystalline 2D MOF structures. However, most synthetic strategies to obtain such materials remain underexplored. This highlighted review evaluated select synthesis strategies focused on deriving micron-sized 2D MOF crystals, emphasizing their rich chemistries. More importantly, the possibility of integrating the synthesized ultrathin 2D crystalline MOFs into the functional device and their electrical conductivity measurements are reviewed. Overall, this review provides the most recent outcomes in the ultrathin 2D MOF community and its influence on electronic devices.

Synthesis and Structure of a Clathrated Two-Dimensional Metal-Organic Framework: [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2·H2O (L = Bis(1-pyrazinylethylidene)hydrazine)

2008 ◽  
Vol 73 (1) ◽  
pp. 24-31
Author(s):  
Dayu Wu ◽  
Genhua Wu ◽  
Wei Huang ◽  
Zhuqing Wang
Keyword(s):  
Metal Organic Framework ◽  
Channel Structure ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
X Ray ◽  
Square Planar ◽  
Metal Organic ◽  
Aqueous Meoh ◽  
Organic Framework

The compound [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2 was obtained by the reaction of Cd(ClO4)2, bis(1-pyrazinylethylidene)hydrazine (L) and 4,4'-bipyridine in aqueous MeOH. Single-crystal X-ray diffraction has revealed its two-dimensional metal-organic framework. The 2-D layers superpose on each other, giving a channel structure. The square planar grids consist of two pairs of shared edges with Cd(II) ion and a 4,4'-bipyridine molecule each vertex and side, respectively. The square cavity has a dimension of 11.817 × 11.781 Å. Two guest molecules of bis(1-pyrazinylethylidene)hydrazine are clathrated in every hydrophobic host cavity, being further stabilized by π-π stacking and hydrogen bonding. The results suggest that the hydrazine molecules present in the network serve as structure-directing templates in the formation of crystal structures.

Two-Dimensional Metal–Organic Framework Nanosheets as an Enzyme Inhibitor: Modulation of the α-Chymotrypsin Activity

2017 ◽  
Vol 139 (24) ◽  
pp. 8312-8319 ◽  
Author(s):  
Ming Xu ◽  
Shuai Yuan ◽  
Xin-Yu Chen ◽  
Yu-Jie Chang ◽  
Gregory Day ◽  
...  
Keyword(s):  
Enzyme Inhibitor ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Chymotrypsin Activity ◽  
Metal Organic ◽  
Organic Framework
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