Highly Transparent Dual-Sensitized Titanium Dioxide Nanotube Arrays for Spontaneous Solar Water Splitting Tandem Configuration

2015 ◽  
Vol 7 (33) ◽  
pp. 18429-18434 ◽  
Author(s):  
Kahee Shin ◽  
Jong Hyeok Park
2014 ◽  
Vol 313 ◽  
pp. 633-639 ◽  
Author(s):  
Zhangrong He ◽  
Jianzhong Xiao ◽  
Feng Xia ◽  
Koji Kajiyoshi ◽  
Chanatip Samart ◽  
...  

Nano Research ◽  
2018 ◽  
Vol 12 (3) ◽  
pp. 643-650 ◽  
Author(s):  
Hui Yang ◽  
Joeseph Bright ◽  
Sujan Kasani ◽  
Peng Zheng ◽  
Terence Musho ◽  
...  

Nano Letters ◽  
2015 ◽  
Vol 15 (9) ◽  
pp. 5709-5715 ◽  
Author(s):  
In Sun Cho ◽  
Jongmin Choi ◽  
Kan Zhang ◽  
Sung June Kim ◽  
Myung Jin Jeong ◽  
...  

2019 ◽  
Vol 11 (1) ◽  
Author(s):  
Lixia Sang ◽  
Lei Lei ◽  
Clemens Burda

Abstract Effective utilization of hot electrons generated from the decay of surface plasmon resonance in metal nanoparticles is conductive to improve solar water splitting efficiency. Herein, Ag nanoparticles and reduced graphene oxide (rGO) co-decorated hierarchical TiO2 nanoring/nanotube arrays (TiO2 R/T) were facilely fabricated by using two-step electrochemical anodization, electrodeposition, and photoreduction methods. Comparative studies were conducted to elucidate the effects of rGO and Ag on the morphology, photoresponse, charge transfer, and photoelectric properties of TiO2. Firstly, scanning electron microscope images confirm that the Ag nanoparticles adhered on TiO2 R/T and TiO2 R/T-rGO have similar diameter of 20 nm except for TiO2 R-rGO/T. Then, the UV–Vis DRS and scatter spectra reveal that the optical property of the Ag-TiO2 R/T-rGO ternary composite is enhanced, ascribing to the visible light absorption of plasmonic Ag nanoparticles and the weakening effect of rGO on light scattering. Meanwhile, intensity-modulated photocurrent spectroscopy and photoluminescence spectra demonstrate that rGO can promote the hot electrons transfer from Ag nanoparticles to Ti substrate, reducing the photogenerated electron–hole recombination. Finally, Ag-TiO2 R/T-rGO photoanode exhibits high photocurrent density (0.98 mA cm−2) and photovoltage (0.90 V), and the stable H2 evolution rate of 413 μL h−1 cm−2 within 1.5 h under AM 1.5 which exceeds by 1.30 times than that of pristine TiO2 R/T. In line with the above results, this work provides a reliable route synergizing rGO with plasmonic metal nanoparticles for photocatalysis, in which, rGO presents a broad absorption spectrum and effective photogenerated electrons transfer.


2016 ◽  
Vol 16 (6) ◽  
pp. 6148-6154 ◽  
Author(s):  
Bo Sun ◽  
Tielin Shi ◽  
Xianhua Tan ◽  
Zhiyong Liu ◽  
Youni Wu ◽  
...  

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