Accelerating Anode Reaction with Electro-oxidation of Alcohols over Ru Nanoparticles to Reduce the Potential for Water Splitting

2021 ◽  
Author(s):  
Pei Zhu ◽  
Yongli Shen ◽  
Linxiu Dai ◽  
Qiuyuan Yu ◽  
Zhi-Ming Zhang ◽  
...  
Keyword(s):  
Water Splitting ◽  
Ru Nanoparticles ◽  
Oxidation Of Alcohols ◽  
Anode Reaction ◽  
Electro Oxidation

Sulfide-oxidation-assisted electrochemical water splitting for H2 production on a bifunctional Cu2S/nickel foam catalyst

2021 ◽  
Author(s):  
Yuhou Pei ◽  
Jiong Cheng ◽  
Heng Zhong ◽  
Zhenfeng Pi ◽  
Zhao Yu ◽  
...  
Keyword(s):  
Energy Consumption ◽  
Water Splitting ◽  
Hydrogen Evolution Reaction ◽  
Oxygen Evolution Reaction ◽  
Oxidation Reaction ◽  
Nickel Foam ◽  
Sulfide Oxidation ◽  
H2 Production ◽  
Electro Oxidation ◽  
Electrochemical Water Splitting

Replacing the sluggish oxygen evolution reaction (OER) by sulfide electro-oxidation reaction (SOR) could be a promising way to decrease the energy consumption for hydrogen evolution reaction (HER) and to treat...

Selective Electro-oxidation of Alcohols to the Corresponding Aldehydes in Aqueous Solution via Cu(III) Intermediates from CuO Nanorods

2021 ◽  
Vol 9 (35) ◽  
pp. 11855-11861
Author(s):  
Zhiyong Fang ◽  
Peili Zhang ◽  
Mei Wang ◽  
Fusheng Li ◽  
Xiujuan Wu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Oxidation Of Alcohols ◽  
Electro Oxidation ◽  
Cuo Nanorods

Photo-Electro-Oxidation of Alcohols on Titanium Dioxide Thin Film Electrodes

1999 ◽  
Vol 103 (26) ◽  
pp. 5505-5511 ◽  
Author(s):  
Pablo A. Mandelbaum ◽  
Alberto E. Regazzoni ◽  
Miguel A. Blesa ◽  
Sara A. Bilmes
Keyword(s):  
Thin Film ◽  
Titanium Dioxide ◽  
Oxidation Of Alcohols ◽  
Electro Oxidation ◽  
Thin Film Electrodes

scholarly journals Radiolytic Synthesis of Pt-Ru Catalysts Based on Functional Polymer-Grafted MWNT and Their Catalytic Efficiency for CO and MeOH

2011 ◽  
Vol 2011 ◽  
pp. 1-8 ◽  
Author(s):  
Dae-Soo Yang ◽  
Kwang-Sik Sim ◽  
Hai-Doo Kwen ◽  
Seong-Ho Choi
Keyword(s):  
Catalytic Efficiency ◽  
Multiwalled Carbon ◽  
Ru Catalysts ◽  
Functional Polymer ◽  
Co Stripping ◽  
Ru Nanoparticles ◽  
Direct Methanol ◽  
Radiation Induced ◽  
Electro Oxidation ◽  
Methanol Fuel Cell

Pt-Ru catalysts based on functional polymer-grafted MWNT (Pt-Ru@FP-MWNT) were prepared by radiolytic deposition of Pt-Ru nanoparticles on functional polymer-grafted multiwalled carbon nanotube (FP-MWNT). Three different types of functional polymers, poly(acrylic acid) (PAAc), poly(methacrylic acid) (PMAc), and poly(vinylphenyl boronic acid) (PVPBAc), were grafted on the MWNT surface by radiation-induced graft polymerization (RIGP). Then, Pt-Ru nanoparticles were deposited onto the FP-MWNT supports by the reduction of metal ions usingγ-irradiation to obtain Pt-Ru@FP-MWNT catalysts. The Pt-Ru@FP-MWNT catalysts were then characterized by XRD, XPS, TEM ,and elemental analysis. The catalytic efficiency of Pt-Ru@FP-MWNT catalyst was examined for CO stripping and MeOH oxidation for use in a direct methanol fuel cell (DMFC). The Pt-Ru@PVPBAc-MWNT catalyst shows enhanced activity for electro-oxidation of CO and MeOH oxidation over that of the commercial E-TEK catalyst.

scholarly journals Intermetallic Pd3 X (X= Ti and Zr) nanocrystals for electro-oxidation of alcohols and formic acid in alkaline and acidic media

2020 ◽  
Vol 21 (1) ◽  
pp. 573-583
Author(s):  
Rajesh Kodiyath ◽  
Gubbala V. Ramesh ◽  
Maidhily Manikandan ◽  
Shigenori Ueda ◽  
Takeshi Fujita ◽  
...  
Keyword(s):  
Formic Acid ◽  
Acidic Media ◽  
Oxidation Of Alcohols ◽  
Electro Oxidation

The Impregnating Reduction Method for Synthesis of Pt–Ru Nanoparticles and Its Catalytic Performance for Methanol Electro-oxidation

2015 ◽  
Vol 12 (4) ◽  
Author(s):  
Long-long Wang ◽  
Hong-min Mao ◽  
Xiao-jin Zhou ◽  
Qun-jie Xu ◽  
Qiao-xia Li
Keyword(s):  
Reduction Method ◽  
Average Particle Size ◽  
Catalytic Performance ◽  
Average Particle ◽  
X Ray ◽  
Onset Potential ◽  
Ru Nanoparticles ◽  
Oxidation Of Methanol ◽  
Transmission Electron ◽  
Electro Oxidation

Well-dispersed and low Pt content Pt–Ru/C nanoparticles were prepared by a developed impregnating reduction method with sodium citrate as stabilizer. The as-prepared Pt–Ru/C catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and energy dispersive X-ray (EDX) analysis. TEM showed that the Pt–Ru particles were quite uniformly distributed on the surface of the carbon with an average particle size of 3.5–4.5 nm. The effect of pH values on methanol electro-oxidation reaction was examined by cyclic voltammetry (CV) and chronoamperometry (CA). Pre-adsorbed CO monolayer stripping was used to evaluate the antipoisoning ability. The results showed that Pt–Ru/C (pH = 8) catalyst had the highest catalytic activity and stability toward the oxidation of methanol. Finally, comparing Pt–Ru/C (Pt–Ru 20 wt.%, Pt/Ru = 1:1) catalysts with Pt/C (Pt 20 wt.%), the onset potential was 200 mV lower and electrochemical active area was much bigger.

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