Pd-Immobilized Schiff Base Double-Layer Macrocycle: Synthesis, Structures, Peroxidase Mimic Activity, and Antibacterial Performance

2021 ◽  
Author(s):  
Kuiyuan Wang ◽  
Kai Chen ◽  
Timothy J. Prior ◽  
Xing Feng ◽  
Carl Redshaw
Keyword(s):  
Schiff Base ◽  
Double Layer ◽  
Peroxidase Mimic ◽  
Antibacterial Performance

SYNTHESIS AND ELECTROLUMINESCENT PROPERTIES OF POLYAZOMETHINE-TYPE CONJUGATED POLYMERS CONTAINING HETEROCYCLIC PHENOTHIAZINE AND CARBAZOLE MOIETY

2005 ◽  
Vol 14 (04) ◽  
pp. 545-553 ◽  
Author(s):  
JEON WOO JEONG ◽  
YOUNGHWAN KWON ◽  
JEONG JU BAEK ◽  
LEE SOON PARK ◽  
EUI-WAN LEE ◽  
...  
Keyword(s):  
Schiff Base ◽  
Conjugated Polymers ◽  
Organic Solvents ◽  
Double Layer ◽  
Polymer Structure ◽  
The Other ◽  
Side Chains ◽  
Emission Color ◽  
Alkyl Side Chains

Polyazomethine-type conjugated polymers were synthesized by Schiff-base reaction. One was poly(PZ-PBI) with alternating phenothiazine (PZ) and azomethine units (-C = N-) , and the other was poly(CZ-PBI) comprising alternating carbazole (CZ) and azomethine groups. Conjugated polymers exhibited improved solubility in common organic solvents due to alkyl side chains on phenothiazine and carbazole rings as well as polar azomethine groups in main chains. Single- and double-layer PLEDs were fabricated. Their electroluminescent properties were studied from the viewpoint of polymer structure vs. emission color and efficiency.

Spin-crossover in an iron(iii) complex showing a broad thermal hysteresis

2021 ◽  
Author(s):  
Cyril Rajnák ◽  
Romana Mičová ◽  
Ján Moncoľ ◽  
Ľubor Dlháň ◽  
Christoph Krüger ◽  
...  
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Spin Crossover ◽  
Thermal Hysteresis ◽  
Mononuclear Complex ◽  
Hysteresis Width ◽  
Thermally Induced

A pentadentate Schiff-base ligand 3,5Cl-L2− and NCSe− form a iron(iii) mononuclear complex [Fe(3,5Cl-L)(NCSe)], which shows a thermally induced spin crossover with a broad hysteresis width of 24 K between 123 K (warming) and 99 K (cooling).

Cracking at the fold in double layer coated paper: the influence of latex and starch composition

TAPPI Journal ◽  
2019 ◽  
Vol 18 (2) ◽  
pp. 93-99
Author(s):  
SEYYED MOHAMMAD HASHEMI NAJAFI ◽  
DOUGLAS BOUSFIELD, ◽  
MEHDI TAJVIDI
Keyword(s):  
Mechanical Properties ◽  
Double Layer ◽  
Starch Content ◽  
Single Layer ◽  
Double Layers ◽  
Coated Paper ◽  
Coated Papers ◽  
Coating Layers ◽  
Scanned Images ◽  
Packaging Paper

Cracking at the fold of publication and packaging paper grades is a serious problem that can lead to rejection of product. Recent work has revealed some basic mechanisms and the influence of various parameters on the extent of crack area, but no studies are reported using coating layers with known mechanical properties, especially for double-coated systems. In this study, coating layers with different and known mechanical properties were used to characterize crack formation during folding. The coating formulations were applied on two different basis weight papers, and the coated papers were folded. The binder systems in these formulations were different combinations of a styrene-butadiene latex and mixtures of latex and starch for two different pigment volume concentrations (PVC). Both types of papers were coated with single and double layers. The folded area was scanned with a high-resolution scanner while the samples were kept at their folded angle. The scanned images were analyzed within a constant area. The crack areas were reported for different types of papers, binder system and PVC values. As PVC, starch content, and paper basis weight increased, the crack area increased. Double layer coated papers with high PVC and high starch content at the top layer had more cracks in comparison with a single layer coated paper, but when the PVC of the top layer was low, cracking area decreased. No measurable cracking was observed when the top layer was formulated with a 100% latex layer.

A Survey on Crypto-Steganographic Schemes and A Use Case in Healthcare System

2019 ◽  
Vol 1 (2) ◽  
pp. 25-33
Author(s):  
Mei Ling Phang ◽  
Swee Huay Heng
Keyword(s):  
Social Networking ◽  
Information Sharing ◽  
Healthcare System ◽  
Double Layer ◽  
21St Century ◽  
Electronic Devices ◽  
Third Party ◽  
Use Case ◽  
Comparison Analysis ◽  
Information Assets

Information sharing has become prevalent due to the expansion of social networking in this 21st century. However, electronic devices are vulnerable to various kinds of attacks. Information might be disclosed, modified and accessed by an unauthorised third party which consequently leads to the breach of confidentiality, integrity and availability of the information. Therefore, it is of utmost importance to employ the technology of cryptography and steganography to protect information assets. Cryptography and steganography have weaknesses when they are working alone. Therefore, crypto-steganography, the combination of cryptography and steganography are introduced to overcome the weaknesses in order to provide a double layer of security and protection. This paper provides a general overview of steganography and cryptography as well as a comparison analysis of different crypto-steganographic schemes. A secure crypto-steganographic system for healthcare is then developed with the implementation and integration of the secure crypto-steganographic scheme proposed by Juneja and Sandhu. This healthcare system enables users to store and deliver message in a more secure way while achieving the main goals of both cryptography and steganography.

Polymer Anchored Copper (II) Complex Supported by -ONNO- Schiff Base: Efficient Catalysts for Oxidation of Phenol

2011 ◽  
Vol 3 (11) ◽  
pp. 44-48
Author(s):  
Alekha Kumar Sutar ◽  
◽  
Yasobanta Das ◽  
Prasanta Rath ◽  
Tungabidya Maharana
Keyword(s):  
Schiff Base ◽  
Polymer Anchored ◽  
Oxidation Of Phenol
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