Mesoporous Weaved Turbostratic Nanodomains Enable Stable Na+ Ion Storage and Micropore Filling is Revealed to be More Unsafe than Adsorption and Deintercalation

2021 ◽  
Author(s):  
Manikandan Palanisamy ◽  
Ramakrishnan Perumal ◽  
Vilas G. Pol
Keyword(s):  
Micropore Filling ◽  
Ion Storage

Ultrathin Carbon Nanosheets for Highly-efficient Capacitive K-ion and Zn-ion Storage

2020 ◽  
Author(s):  
Yamin Zhang ◽  
Zhongpu Wang ◽  
Deping Li ◽  
Qing Sun ◽  
Kangrong Lai ◽  
...  
Keyword(s):  
Energy Storage ◽  
Porous Carbon ◽  
Metal Ion ◽  
Rate Capability ◽  
Energy Storage Devices ◽  
Capacity Retention ◽  
Carbon Nanosheets ◽  
Storage Devices ◽  
High Efficient ◽  
Ion Storage

<p></p><p>Porous carbon has attracted extensive attentions as the electrode material for various energy storage devices considering its advantages like high theoretical capacitance/capacity, high conductivity, low cost and earth abundant inherence. However, there still exists some disadvantages limiting its further applications, such as the tedious fabrication process, limited metal-ion transport kinetics and undesired structure deformation at harsh electrochemical conditions. Herein, we report a facile strategy, with calcium gluconate firstly reported as the carbon source, to fabricate ultrathin porous carbon nanosheets. <a>The as-prepared Ca-900 electrode delivers excellent K-ion storage performance including high reversible capacity (430.7 mAh g<sup>-1</sup>), superior rate capability (154.8 mAh g<sup>-1</sup> at an ultrahigh current density of 5.0 A g<sup>-1</sup>) and ultra-stable long-term cycling stability (a high capacity retention ratio of ~81.2% after 4000 cycles at 1.0 A g<sup>-1</sup>). </a>Similarly, when being applied in Zn-ion capacitors, the Ca-900 electrode also exhibits an ultra-stable cycling performance with ~90.9% capacity retention after 4000 cycles at 1.0 A g<sup>-1</sup>, illuminating the applicable potentials. Moreover, the origin of the fast and smooth metal-ion storage is also revealed by carefully designed consecutive CV measurements. Overall, considering the facile preparation strategy, unique structure, application flexibility and in-depth mechanism investigations, this work will deepen the fundamental understandings and boost the commercialization of high-efficient energy storage devices like potassium-ion/sodium-ion batteries, zinc-ion batteries/capacitors and aluminum-ion batteries.</p><br><p></p>

scholarly journals Pseudocapacitive Vanadium‐based Materials toward High‐Rate Sodium‐Ion Storage

2020 ◽  
Vol 3 (3) ◽  
pp. 221-234 ◽  
Author(s):  
Qiulong Wei ◽  
Ryan H. DeBlock ◽  
Danielle M. Butts ◽  
Christopher Choi ◽  
Bruce Dunn
Keyword(s):  
Sodium Ion ◽  
High Rate ◽  
Ion Storage ◽  
Sodium Ion Storage

Preparation of TiNb6O17 nanospheres as high-performance anode candidates for lithium-ion storage

2019 ◽  
Vol 374 ◽  
pp. 937-946 ◽  
Author(s):  
Yu Yuan ◽  
Haoxiang Yu ◽  
Xing Cheng ◽  
Runtian Zheng ◽  
Tingting Liu ◽  
...  
Keyword(s):  
High Performance ◽  
Lithium Ion ◽  
Ion Storage

N-doped hierarchical porous hollow carbon spheres with multi-cavities for high performance Na-ion storage

2021 ◽  
Vol 506 ◽  
pp. 230170
Author(s):  
Lantao Liu ◽  
Xiangyu Sun ◽  
Yue Dong ◽  
Dengke Wang ◽  
Zheng Wang ◽  
...  
Keyword(s):  
High Performance ◽  
Carbon Spheres ◽  
Hierarchical Porous ◽  
Ion Storage ◽  
Hollow Carbon ◽  
Hollow Carbon Spheres

Engineering zinc ferrite nanoparticles in a hierarchical graphene and carbon nanotube framework for improved lithium-ion storage

2021 ◽  
Vol 588 ◽  
pp. 346-356
Author(s):  
Shouchun Bao ◽  
Qingke Tan ◽  
Xiangli Kong ◽  
Can Wang ◽  
Yiyu Chen ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Zinc Ferrite ◽  
Lithium Ion ◽  
Ferrite Nanoparticles ◽  
Ion Storage

scholarly journals A Hierarchically Ordered Mesoporous-Carbon-Supported Iron Sulfide Anode for High-Rate Na-Ion Storage

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4349
Author(s):  
Anupriya K. Haridas ◽  
Natarajan Angulakshmi ◽  
Arul Manuel Stephan ◽  
Younki Lee ◽  
Jou-Hyeon Ahn
Keyword(s):  
Mesoporous Carbon ◽  
Anode Materials ◽  
Iron Sulfide ◽  
Carbon Composite ◽  
Ordered Mesoporous Carbon ◽  
Cycle Life ◽  
High Rate ◽  
Volume Changes ◽  
Ordered Mesoporous ◽  
Ion Storage

Sodium-ion batteries (SIBs) are promising alternatives to lithium-based energy storage devices for large-scale applications, but conventional lithium-ion battery anode materials do not provide adequate reversible Na-ion storage. In contrast, conversion-based transition metal sulfides have high theoretical capacities and are suitable anode materials for SIBs. Iron sulfide (FeS) is environmentally benign and inexpensive but suffers from low conductivity and sluggish Na-ion diffusion kinetics. In addition, significant volume changes during the sodiation of FeS destroy the electrode structure and shorten the cycle life. Herein, we report the rational design of the FeS/carbon composite, specifically FeS encapsulated within a hierarchically ordered mesoporous carbon prepared via nanocasting using a SBA-15 template with stable cycle life. We evaluated the Na-ion storage properties and found that the parallel 2D mesoporous channels in the resultant FeS/carbon composite enhanced the conductivity, buffered the volume changes, and prevented unwanted side reactions. Further, high-rate Na-ion storage (363.4 mAh g−1 after 500 cycles at 2 A g−1, 132.5 mAh g−1 at 20 A g−1) was achieved, better than that of the bare FeS electrode, indicating the benefit of structural confinement for rapid ion transfer, and demonstrating the excellent electrochemical performance of this anode material at high rates.

Molecular Engineering on MoS2 Enables Large Interlayers and Unlocked Basal Planes for High‐Performance Aqueous Zn‐Ion Storage

2021 ◽  
Author(s):  
Shengwei Li ◽  
Yongchang Liu ◽  
Xudong Zhao ◽  
Kaixuan Cui ◽  
Qiuyu Shen ◽  
...  
Keyword(s):  
High Performance ◽  
Molecular Engineering ◽  
Ion Storage

Bimetallic nickel cobalt sulfides with hierarchical coralliform architecture for ultrafast and stable Na-ion storage

Nano Research ◽  
2021 ◽  
Author(s):  
Yanyan He ◽  
Caifu Dong ◽  
Sijia He ◽  
Huan Li ◽  
Xiuping Sun ◽  
...  
Keyword(s):  
Nickel Cobalt ◽  
Ion Storage

scholarly journals Germanene Nanosheets: Achieving Superior Sodium‐Ion Storage via Pseudo‐Intercalation Reactions

2021 ◽  
Author(s):  
Nana Liu ◽  
Kang Xu ◽  
Yaojie Lei ◽  
Yilian Xi ◽  
Yani Liu ◽  
...  
Keyword(s):  
Sodium Ion ◽  
Ion Storage ◽  
Sodium Ion Storage
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