Fluorinated Graphite (FG)-Modified Li–S Batteries with Superhigh Primary Specific Capacity and Improved Cycle Stability

Author(s):  
Ziyang Jia ◽  
Hongzhang Zhang ◽  
Tianyu Li ◽  
Yang Luo ◽  
Jingwang Yan ◽  
...  
2019 ◽  
Vol 43 (9) ◽  
pp. 3907-3912
Author(s):  
Xuan Gao ◽  
Xiaochen Sun ◽  
Zhigang Jiang ◽  
Qiliang Wang ◽  
Nan Gao ◽  
...  

In this work, we report a new type of anode consisting of mixed detonation nanodiamonds (DNDs) and titanium dioxide (TiO2) hollow nanospheres (HNSs) for improving the specific capacity and cycle stability of lithium ion batteries (LIBs).


2014 ◽  
Vol 7 (5) ◽  
pp. 1643-1647 ◽  
Author(s):  
Ya You ◽  
Xing-Long Wu ◽  
Ya-Xia Yin ◽  
Yu-Guo Guo

High-quality Prussian blue crystals with a small number of vacancies and a low water content show high specific capacity and remarkable cycle stability as cathode materials for Na-ion batteries.


2020 ◽  
Author(s):  
Liming Liu ◽  
X.X. Huang ◽  
Zengyan Wei ◽  
Xiaoming Duan ◽  
Bo Zhong ◽  
...  

Abstract CoCO3 with high theoretical capacity has been considered as a candidate anode for the next generation of lithium-ion batteries. However, the electrochemical characteristics of CoCO3 itself, especially the cycle stability under high current density, hindering its application. Herein, pure phase CoCO3 particles with different particle and pore sizes were prepared by adjusting the solvents. CoCO3 synthesized with diethylene glycol (DG-CC) as the reaction solvent shows the best electrochemical performance for the particle size of about 0.85 µm, which because the small primary particle size within and the mesopores maintain the structural stability. A high specific capacity of after 1000 cycles was achieved, and an excellent capacity retention was presented. The capacity provided by different electrochemical reactions and the impedance of DG-CC under different cycles were further compared. Those results provide an important reference for the structural design and stable cycle performance of pure CoCO3.


2018 ◽  
Vol 28 (20) ◽  
pp. 1707272 ◽  
Author(s):  
Jian Gou ◽  
Hongzhang Zhang ◽  
Xiaofei Yang ◽  
Yuqing Chen ◽  
Ying Yu ◽  
...  

2019 ◽  
Vol 944 ◽  
pp. 699-704 ◽  
Author(s):  
Jing Wang ◽  
Xiao Hang Yang ◽  
Yue Feng Su ◽  
Shi Chen ◽  
Feng Wu

Silicon anode is a promising candidate as an alternative to the conventional graphitic anode in lithium-ion batteries. In this work, silicon anode is modified by NH4F using a facile method in air. The concentration of NH4F on the electrochemical performance is systematically checked. The 5wt%NH4F-modified silicon anode exhibits enhanced cycle and rate performances, the first discharge specific capacity is 3958 mAh·g-1 with 86.45% as the coulombic efficiency at 0.4A·g-1. The capacity can maintain at 703.3 mAh·g-1 after 50 cycles, exhibiting a much better cycle stability than pristine silicon anode (329.9 mAh·g-1 after 50 cycles). SEM images confirm that NH4F can alleviate the volume expansion of silicon since LiF can be generated at the surface which is beneficial to the stability of solid-electrolyte interphase (SEI).


2017 ◽  
Vol 5 (4) ◽  
pp. 1588-1594 ◽  
Author(s):  
Yanshan Huang ◽  
Dongqing Wu ◽  
Arezoo Dianat ◽  
Manferd Bobeth ◽  
Tao Huang ◽  
...  

As cathode materials in lithium ion batteries, nitrogen-doped graphene frameworks (N-GFs) manifest excellent specific capacity and cycle stability, owing to the fast surface faradaic reactions of pyridinic N and pyridinic N-oxide with both p- and n-doped states.


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