Fabrication of 2D Metal–Organic Framework Nanosheets with Highly Colloidal Stability and High Yield through Coordination Modulation

2021 ◽  
Author(s):  
Huazhang Zhou ◽  
Liying Zhang ◽  
Guizhou Wang ◽  
Yichi Zhang ◽  
Xuanhe Wang ◽  
...  
Keyword(s):  
Colloidal Stability ◽  
Metal Organic Framework ◽  
High Yield ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Sulfonic acid functionalized metal–organic framework (S-IRMOF-3): a novel catalyst for sustainable approach towards the synthesis of acrylonitriles

RSC Advances ◽  
2019 ◽  
Vol 9 (28) ◽  
pp. 15749-15762 ◽  
Author(s):  
Ryhan Abdullah Rather ◽  
Zeba N. Siddiqui
Keyword(s):  
Reaction Time ◽  
Heterogeneous Catalyst ◽  
Sulfonic Acid ◽  
Metal Organic Framework ◽  
High Yield ◽  
Time Period ◽  
Metal Organic ◽  
Novel Catalyst ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

Sulfonic acid functionalized metal–organic framework (S-IRMOF-3) as an efficient heterogeneous catalyst has been synthesized and employed for sustainable approach towards the synthesis of acrylonitriles in high yield and shorter reaction time period.

Direct one-pot conversion of monosaccharides into high-yield 2,5-dimethylfuran over a multifunctional Pd/Zr-based metal–organic framework@sulfonated graphene oxide catalyst

2017 ◽  
Vol 19 (11) ◽  
pp. 2482-2490 ◽  
Author(s):  
Rizki Insyani ◽  
Deepak Verma ◽  
Seung Min Kim ◽  
Jaehoon Kim
Keyword(s):  
Graphene Oxide ◽  
Oxide Catalyst ◽  
Metal Organic Framework ◽  
High Yield ◽  
One Pot ◽  
Sulfonated Graphene ◽  
Metal Organic ◽  
Multifunctional Catalyst ◽  
Organic Framework

A one-pot conversion of monosaccharides (fructose and glucose) into high-yield 2,5-dimethylfuran (2,5-DMF) is demonstrated over a multifunctional catalyst obtained by loading Pd on UiO-66@ sulfonated GO (Pd/UiO-66@SGO).

scholarly journals High Electrical Conductivity in Three-Dimensional Porphyrin-Phosphonate Metal Organic-Frameworks

2021 ◽  
Author(s):  
Yunus Zorlu ◽  
Patrik Tholen ◽  
Mehmet Menaf Ayhan ◽  
Ceyda Bayraktar ◽  
Gabriel Hanna ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
High Yield ◽  
Electrically Conductive ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Indirect Band Gap ◽  
Organic Framework

<p>Herein, we report the design and synthesis of a highly electrically conductive and microporous three-dimensional zinc-phosphonate metal-organic framework [Zn(Cu-<i>p</i>-H<sub>4</sub>TPPA)] ⋅2 (CH<sub>3</sub>)<sub>2</sub>NH<sub>2</sub><sup>+</sup> (designated as GTUB3), constructed using the 5,10,15,20‐tetrakis [<i>p</i>‐phenylphosphonic acid] porphyrin (<i>p</i>-H<sub>8</sub>TPPA) organic linker. GTUB3 has an indirect band gap of 1.64 eV and a high average electrical conductivity of<b> </b>4 S/m, making it a rare example of an electrically conductive zinc metal-organic framework. The N<sub>2</sub>-accessible geometric surface area of GTUB3, as predicted by molecular simulations, is 671 m<sup>2</sup>/g. Owing to its simple, high-yield synthesis at low temperatures, porosity, and electrical conductivity, GTUB3 may be used as a low-cost electrode material in next generation phosphonate-supercapacitors. </p>

Inversion of Dispersion: Colloidal Stability of Calixarene-Modified Metal–Organic Framework Nanoparticles in Nonpolar Media

2019 ◽  
Vol 141 (31) ◽  
pp. 12182-12186 ◽  
Author(s):  
Uiseok Jeong ◽  
Nesibe A. Dogan ◽  
Mousumi Garai ◽  
Thien S. Nguyen ◽  
J. Fraser Stoddart ◽  
...  
Keyword(s):  
Colloidal Stability ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Facile and high-yield synthesis of improved MIL-101(Cr) metal-organic framework with exceptional CO2 and H2S uptake; the impact of excess ligand-cluster

2019 ◽  
Vol 279 ◽  
pp. 153-164 ◽  
Author(s):  
Masood Sheikh Alivand ◽  
Marzieh Shafiei-Alavijeh ◽  
Neda Haj Mohammad Hossein Tehrani ◽  
Ebrahim Ghasemy ◽  
Alimorad Rashidi ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Yield ◽  
Metal Organic ◽  
The Impact ◽  
Organic Framework

scholarly journals Role of Modulators in Controlling the Colloidal Stability and Polydispersity of the UiO-66 Metal–Organic Framework

2017 ◽  
Vol 9 (39) ◽  
pp. 33413-33418 ◽  
Author(s):  
William Morris ◽  
Shunzhi Wang ◽  
David Cho ◽  
Evelyn Auyeung ◽  
Peng Li ◽  
...  
Keyword(s):  
Colloidal Stability ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Bimetallic metal–organic framework-derived MoFe-PC microspheres for electrocatalytic ammonia synthesis under ambient conditions

2020 ◽  
Vol 8 (4) ◽  
pp. 2099-2104 ◽  
Author(s):  
Silong Chen ◽  
Haeseong Jang ◽  
Jia Wang ◽  
Qing Qin ◽  
Xien Liu ◽  
...  
Keyword(s):  
Porous Structure ◽  
Active Sites ◽  
Ammonia Synthesis ◽  
Metal Organic Framework ◽  
High Yield ◽  
Ambient Conditions ◽  
Faradaic Efficiency ◽  
Yield Rate ◽  
Metal Organic ◽  
Organic Framework

MoFe-PC exhibits a high yield rate and faradaic efficiency for NH3 electrosynthesis in acidic electrolytes due to the multicomponent active sites and inherent porous structure.

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