Indium Tin-Doped Oxide (ITO) as a High Activity Water Oxidation Photoanode

Author(s):  
Matthew V. Sheridan ◽  
Jeffrey R. McLachlan ◽  
Johan R. González-Moya ◽  
Nicole D. Cortés-Medina ◽  
Christopher J. Dares
2022 ◽  
Vol 13 (1) ◽  
Author(s):  
Zhanwu Lei ◽  
Wenbin Cai ◽  
Yifei Rao ◽  
Kuan Wang ◽  
Yuyuan Jiang ◽  
...  

AbstractSingle-atom catalysts (SACs) have attracted tremendous research interests in various energy-related fields because of their high activity, selectivity and 100% atom utilization. However, it is still a challenge to enhance the intrinsic and specific activity of SACs. Herein, we present an approach to fabricate a high surface distribution density of iridium (Ir) SAC on nickel-iron sulfide nanosheet arrays substrate (Ir1/NFS), which delivers a high water oxidation activity. The Ir1/NFS catalyst offers a low overpotential of ~170 mV at a current density of 10 mA cm−2 and a high turnover frequency of 9.85 s−1 at an overpotential of 300 mV in 1.0 M KOH solution. At the same time, the Ir1/NFS catalyst exhibits a high stability performance, reaching a lifespan up to 350 hours at a current density of 100 mA cm−2. First-principles calculations reveal that the electronic structures of Ir atoms are significantly regulated by the sulfide substrate, endowing an energetically favorable reaction pathway. This work represents a promising strategy to fabricate high surface distribution density single-atom catalysts with high activity and durability for electrochemical water splitting.


2017 ◽  
Vol 5 (16) ◽  
pp. 7305-7308 ◽  
Author(s):  
Libin Yang ◽  
Danni Liu ◽  
Shuai Hao ◽  
Rongmei Kong ◽  
Abdullah M. Asiri ◽  
...  

As a durable catalyst electrode, a cobalt-borate nanosheet array on a Ti mesh shows high activity for water oxidation in 0.1 M K-Bi (pH: 9.2), achieving a geometrical catalytic current density of 10 mA cm−2 at an overpotential of 469 mV.


2018 ◽  
Vol 2 (7) ◽  
pp. 1561-1573 ◽  
Author(s):  
Manjunath Chatti ◽  
Alexey M. Glushenkov ◽  
Thomas Gengenbach ◽  
Gregory P. Knowles ◽  
Tiago C. Mendes ◽  
...  

A rapid low-temperature microwave-assisted synthesis of nickel(iron) layered hydroxides and sulphides that exhibit robust catalytic activity for electrooxidation of alkaline water is introduced.


2017 ◽  
Vol 1 (4) ◽  
pp. 780-788 ◽  
Author(s):  
Suoyuan Lian ◽  
Michelle P. Browne ◽  
Carlota Domínguez ◽  
Serban N. Stamatin ◽  
Hugo Nolan ◽  
...  

Solvothermally synthesised MnCO3 leads to template-free formation of highly porous, defect-rich MnO2 with high activity in water oxidation.


2014 ◽  
Vol 2 (24) ◽  
pp. 9405-9411 ◽  
Author(s):  
Jiarui Wang ◽  
Frank E. Osterloh

The high activity of BiVO4/Co3O4 was attributed to the electrocatalytic properties of the Co3O4 cocatalyst and to the formation of a heterojunction at the BiVO4–Co3O4 interface.


2017 ◽  
Vol 53 (99) ◽  
pp. 13237-13240 ◽  
Author(s):  
Yiqiang Sun ◽  
Tao Zhang ◽  
Xinyang Li ◽  
Dilong Liu ◽  
Guangqiang Liu ◽  
...  

We report the successful synthesis of Mn doped CoN nanowires on a carbon fiber cloth substrate (CFC) by a two-step strategy, which can be used as an efficient and stable OER electrocatalyst under both alkaline and neutral conditions.


2019 ◽  
Vol 6 (11) ◽  
pp. 3093-3096 ◽  
Author(s):  
Gang Yuan ◽  
Yujie Hu ◽  
Qiwei Wang ◽  
Zihan Wang ◽  
Li Wang ◽  
...  

Self-supported water oxidation catalysts with high activity under neutral conditions were fabricated with tunable morphology and electronic structure by anion regulation.


2018 ◽  
Vol 54 (72) ◽  
pp. 10187-10190 ◽  
Author(s):  
Bin Zhu ◽  
Qi Hu ◽  
Xiufang Liu ◽  
Guomin Li ◽  
Liangdong Fan ◽  
...  

The heterointerfaces between metallic Ag and NiFe-oxides on hierarchical arrays are found to possess high activity for the alkaline oxygen evolution reaction.


2020 ◽  
Author(s):  
Yuting Li ◽  
Xiaoyang Chen ◽  
Juan Wang ◽  
Zhigang Wang ◽  
Sibudjing Kawi ◽  
...  

2019 ◽  
Vol 55 (98) ◽  
pp. 14773-14776 ◽  
Author(s):  
Jian Du ◽  
Suxian Xu ◽  
Licheng Sun ◽  
Fei Li

Iron carbonate hydroxide templated NiFe-MOF nanoplates exhibit high activity and stability for electrocatalytic water oxidation in alkaline solution.


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