TiO2 Nanofiber-Modified Lithium Metal Composite Anode for Solid-State Lithium Batteries

2021 ◽  
Author(s):  
Yuwei Chen ◽  
Ying Huang ◽  
Haoyu Fu ◽  
Yongmin Wu ◽  
Dongdong Zhang ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Metal Composite ◽  
Lithium Metal ◽  
Composite Anode ◽  
Tio2 Nanofiber

Recent progress in carbon/lithium metal composite anode for safe lithium metal batteries

Rare Metals ◽  
2018 ◽  
Vol 37 (6) ◽  
pp. 449-458 ◽  
Author(s):  
Tao Li ◽  
He Liu ◽  
Peng Shi ◽  
Qiang Zhang
Keyword(s):  
Recent Progress ◽  
Metal Composite ◽  
Lithium Metal ◽  
Composite Anode ◽  
Lithium Metal Batteries

Formation of Stable Interphase of Polymer-in-Salt Electrolyte in All-Solid-State Lithium Batteries

2020 ◽  
Vol 2020 ◽  
pp. 1-10
Author(s):  
Hongcai Gao ◽  
Nicholas S. Grundish ◽  
Yongjie Zhao ◽  
Aijun Zhou ◽  
John B. Goodenough
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Lithium Metal ◽  
Practical Utilization ◽  
Metal Anode ◽  
Lithium Metal Anode

The integration of solid-polymer electrolytes into all-solid-state lithium batteries is highly desirable to overcome the limitations of current battery configurations that have a low energy density and severe safety concerns. Polyacrylonitrile is an appealing matrix for solid-polymer electrolytes; however, the practical utilization of such polymer electrolytes in all-solid-state cells is impeded by inferior ionic conductivity and instability against a lithium-metal anode. In this work, we show that a polymer-in-salt electrolyte based on polyacrylonitrile with a lithium salt as the major component exhibits a wide electrochemically stable window, a high ionic conductivity, and an increased lithium-ion transference number. The growth of dendrites from the lithium-metal anode was suppressed effectively by the polymer-in-salt electrolyte to increase the safety features of the batteries. In addition, we found that a stable interphase was formed between the lithium-metal anode and the polymer-in-salt electrolyte to restrain the uncontrolled parasitic reactions, and we demonstrated an all-solid-state battery configuration with a LiFePO4 cathode and the polymer-in-salt electrolyte, which exhibited a superior cycling stability and rate capability.

Constructing a Stable Lithium Metal–Gel Electrolyte Interface for Quasi-Solid-State Lithium Batteries

2018 ◽  
Vol 10 (36) ◽  
pp. 30065-30070 ◽  
Author(s):  
Tong-Tong Zuo ◽  
Yang Shi ◽  
Xiong-Wei Wu ◽  
Peng-Fei Wang ◽  
Shu-Hua Wang ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Gel Electrolyte ◽  
Lithium Metal ◽  
Electrolyte Interface

Boosting the performance of lithium metal capacitors with a Li composite anode

2021 ◽  
Author(s):  
Bao Liu ◽  
Jiangtao Chen ◽  
Bingjun Yang ◽  
Lingyang Liu ◽  
Yinglun Sun ◽  
...  
Keyword(s):  
Metal Composite ◽  
Lithium Metal ◽  
Composite Anode

A Li metal capacitor with enhanced performance is achieved by constructing a dendrite-free Li metal composite anode.

scholarly journals Toward safer solid-state lithium metal batteries: a review

2020 ◽  
Vol 2 (5) ◽  
pp. 1828-1836 ◽  
Author(s):  
Zhenkang Wang ◽  
Jie Liu ◽  
Mengfan Wang ◽  
Xiaowei Shen ◽  
Tao Qian ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Lithium Metal ◽  
Safety Issues ◽  
Lithium Metal Batteries ◽  
Potential Safety

This minireview summarizes several potential safety issues for solid-state lithium batteries, and the general conclusion and perspective on the research of solid-state lithium batteries with ultra-high safety are presented.

Formation of Stable Interphase of Polymer-in-Salt Electrolyte in All-Solid-State Lithium Batteries

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Hongcai Gao ◽  
Nicholas S. Grundish ◽  
Yongjie Zhao ◽  
Aijun Zhou ◽  
John B. Goodenough
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Lithium Metal ◽  
Practical Utilization ◽  
Metal Anode ◽  
Lithium Metal Anode

The integration of solid-polymer electrolytes into all-solid-state lithium batteries is highly desirable to overcome the limitations of current battery configurations that have a low energy density and severe safety concerns. Polyacrylonitrile is an appealing matrix for solid-polymer electrolytes; however, the practical utilization of such polymer electrolytes in all-solid-state cells is impeded by inferior ionic conductivity and instability against a lithium-metal anode. In this work, we show that a polymer-in-salt electrolyte based on polyacrylonitrile with a lithium salt as the major component exhibits a wide electrochemically stable window, a high ionic conductivity, and an increased lithium-ion transference number. The growth of dendrites from the lithium-metal anode was suppressed effectively by the polymer-in-salt electrolyte to increase the safety features of the batteries. In addition, we found that a stable interphase was formed between the lithium-metal anode and the polymer-in-salt electrolyte to restrain the uncontrolled parasitic reactions, and we demonstrated an all-solid-state battery configuration with a LiFePO4 cathode and the polymer-in-salt electrolyte, which exhibited a superior cycling stability and rate capability.

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