Efficiently Selective Oxidation of H2S to Elemental Sulfur over Covalent Triazine Framework Catalysts

Author(s):  
Wen-Li Peng ◽  
Xun Kan ◽  
Wei Chen ◽  
Jinxing Mi ◽  
Guanqing Zhang ◽  
...  
2015 ◽  
Vol 5 (11) ◽  
pp. 4991-4999 ◽  
Author(s):  
Xin Zhang ◽  
Zhuo Wang ◽  
Yuyin Tang ◽  
Nanli Qiao ◽  
Yang Li ◽  
...  

H2S was firstly adsorbed on the moderated basic site and then oxidized into elemental sulfur by Fe3+.


1993 ◽  
Vol 17 (1-2) ◽  
pp. 217-224 ◽  
Author(s):  
R.J.A.M. Terörde ◽  
P.J. van den Brink ◽  
L.M. Visser ◽  
A.J. van Dillen ◽  
J.W. Geus

2004 ◽  
Vol 21 (1) ◽  
pp. 104-109 ◽  
Author(s):  
Bong-Kuk Kim ◽  
Byung-Ha Hwang ◽  
Hwa-Soo Lee ◽  
Hee-Chul Woo ◽  
Dae-Won Park

2001 ◽  
Vol 211 (2) ◽  
pp. 213-225 ◽  
Author(s):  
Moon Young Shin ◽  
Chang Mo Nam ◽  
Dae Won Park ◽  
Jong Shik Chung

Author(s):  
H. Mehmet Tasdemir ◽  
Yavuz Yagizatli ◽  
Sena Yasyerli ◽  
Nail Yasyerli

Abstract In this study, alumina supported Ti-Ce catalysts (10 % by weight and Ti/Ce molar ratio is 4:1) were prepared by using wet impregnation method and their catalytic activities were tested in H2S selective oxidation to elemental sulfur. The support alumina was synthesized by classical (SGC) and modified (SGM) sol-gel methods. The N2 adsorption-desorption, XRD, XPS, EDS and FTIR techniques were used to characterize the synthesized catalysts. The N2 adsorption-desorption isotherms showed that both catalysts have mesoporous structure. Only γ-Al2O3 crystalline phase together with amorphous structure were observed in the XRD patterns. The pyridine adsorbed FTIR analyzes showed that 10 %Ti-Ce@SGC and 10 %Ti-Ce@SGM catalysts have the same Lewis acidity. The activity tests were carried out at 250 °C and with a stoichiometric feed ratio of O2 to H2S being 0.5 for two different reaction times as 150 and 510 min. Complete conversion of H2S was obtained during 180 min. and 330 min. of reaction time over 10 %Ti-Ce@SGC and 10 %Ti-Ce@SGM, respectively. However, all catalysts showed very high sulfur selectivity. Sulfur deposition was detected over 10 %Ti-Ce@SGC catalyst both 150 and 510 min. of reaction time while it was observed after 510 min. of durability test over 10 %Ti-Ce@SGM catalyst. This can be the reason for the earlier loss of catalytic activity 10 %Ti-Ce@SGC than 10 %Ti-Ce@SGM.


2016 ◽  
Vol 55 (9) ◽  
pp. 3106-3111 ◽  
Author(s):  
Siddulu Naidu Talapaneni ◽  
Tae Hoon Hwang ◽  
Sang Hyun Je ◽  
Onur Buyukcakir ◽  
Jang Wook Choi ◽  
...  

ChemInform ◽  
2010 ◽  
Vol 24 (39) ◽  
pp. no-no
Author(s):  
R. J. A. M. TEROERDE ◽  
P. J. VAN DEN BRINK ◽  
L. M. VISSER ◽  
A. J. VAN DILLEN ◽  
J. W. GEUS

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