Arylazopyrazole-Based Dendrimer Solar Thermal Fuels: Stable Visible Light Storage and Controllable Heat Release

Author(s):  
Xingtang Xu ◽  
Bo Wu ◽  
Peng Zhang ◽  
Youmei Xing ◽  
Ke Shi ◽  
...  
2020 ◽  
Vol 8 (36) ◽  
pp. 18668-18676 ◽  
Author(s):  
Liqi Dong ◽  
Yuanhao Chen ◽  
Fei Zhai ◽  
Lin Tang ◽  
Wenchao Gao ◽  
...  

The energy storage and heat release of this STF sample can be controlled completely using light alone at room temperature.


2016 ◽  
Vol 4 (21) ◽  
pp. 8020-8028 ◽  
Author(s):  
Wei Feng ◽  
Shipei Li ◽  
Man Li ◽  
Chengqun Qin ◽  
Yiyu Feng

A bis-azobenzene/hybrid assembly combining high energy density, high power density and tunable heat release was presented.


2021 ◽  
Author(s):  
Zhichun Shangguan ◽  
Wenjin Sun ◽  
Zhao-yang Zhang ◽  
Dong Fang ◽  
Si Wu ◽  
...  

Photochemical crystal-to-liquid transition generally needs UV light as a stimulus and it is even more challenging to carry out below 0 oC. Here, we design a series of 4-alkylthioarylazopyrazoles as molecular solar thermal batteries, which show bidirectional visible-light-triggered photochemical trans-crystal ↔ cis-liquid transitions below ice point (-1 oC). Through co-harvesting visible-light energy and low-temperature ambient heat, high energy density (0.25 MJ kg-1) is achieved. Further, the rechargeable solar thermal batteries devices are fabricated, which can be charged by blue light (400 nm) at -1 oC. Then, the charged devices can release energy on demand in the form of high-temperature heat. Under green light (532 nm) irradiation, the temperature difference between the charged devices and the ice-cold surrounding is up to 13.5 oC. This study paves the way for the design of advanced molecular solar thermal batteries that store both natural sunlight and ambient heat over a wide temperature range.


RSC Advances ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 6356-6364 ◽  
Author(s):  
Martin Drøhse Kilde ◽  
Paloma Garcia Arroyo ◽  
Anders S. Gertsen ◽  
Kurt V. Mikkelsen ◽  
Mogens Brøndsted Nielsen

The optical properties of pyridyl-substituted dihydroazulene (DHA) photoswitches can be tuned by protonation/deprotonation as well as the thermal back-reaction rate and amount of heat release from the vinylheptafulvene (VHF) photoisomers.


2013 ◽  
Vol 6 (10) ◽  
pp. 3007 ◽  
Author(s):  
Zhou Wang ◽  
Chongyin Yang ◽  
Tianquan Lin ◽  
Hao Yin ◽  
Ping Chen ◽  
...  

2012 ◽  
Vol 608-609 ◽  
pp. 74-81
Author(s):  
Qing Shan Zhou ◽  
Zhi Gang Zhang

Based on the thermal equilibrium between the PV panels and the glazing cover of PV/T system, the influence of the spacing between PV panels and glazing cover on the solar-thermal efficiency is discussed. The heat release and solar-heat conversion efficiency of the photovoltaic panels, under different plate spacing, in the PV/T systems in summer are calculated, according to the typical annual meteorological parameters of Tianjin area. The results show that the photo-thermal efficiency of the PV/T system can be improved by appropriate setup of the plate spacing, and the optimal plate spacing is affected by the temperature of photovoltaic panels.


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