Enhancing Carrier Diffusion Length and Quantum Efficiency through Photoinduced Charge Transfer in Layered Graphene–Semiconducting Quantum Dot Devices

Author(s):  
Riya Dutta ◽  
Avradip Pradhan ◽  
Praloy Mondal ◽  
Saloni Kakkar ◽  
T. Phanindra Sai ◽  
...  
ACS Nano ◽  
2010 ◽  
Vol 4 (11) ◽  
pp. 6883-6893 ◽  
Author(s):  
Joseph E. Weaver ◽  
Mallika R. Dasari ◽  
Aniket Datar ◽  
Saikat Talapatra ◽  
Punit Kohli

2017 ◽  
Vol 121 (42) ◽  
pp. 23676-23682 ◽  
Author(s):  
Xiaohong Jiang ◽  
Meng Yuan ◽  
He Liu ◽  
Zhiyao Song ◽  
Huimin Li ◽  
...  

1996 ◽  
Vol 93 ◽  
pp. 1697-1713 ◽  
Author(s):  
P Changenet ◽  
P Plaza ◽  
MM Martin ◽  
YH Meyer ◽  
W Rettig

2020 ◽  
Author(s):  
Zhengqing Tong ◽  
Margaret S. Cheung ◽  
Barry D. Dunietz ◽  
Eitan Geva ◽  
Xiang Sun

The nonequilibrium Fermi’s golden rule (NE-FGR) describes the time-dependent rate coefficient for electronic transitions, when the nuclear degrees of freedom start out in a <i>nonequilibrium</i> state. In this letter, the linearized semiclassical (LSC) approximation of the NE-FGR is used to calculate the photoinduced charge transfer rates in the carotenoid-porphyrin-C<sub>60</sub> molecular triad dissolved in explicit tetrahydrofuran. The initial nonequilibrium state corresponds to impulsive photoexcitation from the equilibrated ground-state to the ππ* state, and the porphyrin-to-C<sub>60</sub> and the carotenoid-to-C<sub>60</sub> charge transfer rates are calculated. Our results show that accounting for the nonequilibrium nature of the initial state significantly enhances the transition rate of the porphyrin-to-C<sub>60</sub> CT process. We also derive the instantaneous Marcus theory (IMT) from LSC NE-FGR, which casts the CT rate coefficients in terms of a Marcus-like expression, with explicitly time-dependent reorganization energy and reaction free energy. IMT is found to reproduce the CT rates in the system under consideration remarkably well.


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