Controlling Interfacial Ion-Transport Kinetics Using Polyelectrolyte Membranes for Additive- and Effluent-free, High-Performance Electrodeposition

Author(s):  
Kensuke Akamatsu ◽  
Shu-ichi Nakano ◽  
Koshi Kimura ◽  
Yohei Takashima ◽  
Takaaki Tsuruoka ◽  
...  
ChemInform ◽  
2010 ◽  
Vol 33 (52) ◽  
pp. no-no
Author(s):  
Merlin L. Bruening ◽  
Daniel M. Sullivan

Langmuir ◽  
2013 ◽  
Vol 29 (6) ◽  
pp. 1885-1892 ◽  
Author(s):  
Chao Cheng ◽  
Andriy Yaroshchuk ◽  
Merlin L. Bruening

Author(s):  
Chen-Wei Chang ◽  
Chien-Wei Chu ◽  
Yen-Shao Su ◽  
Li-Hsien Yeh

Capturing osmotic energy from a salinity gradient through an ion-selective membrane is regarded as one of the renewable clean energy resources to solve the increasing global energy demands. However, suffering...


2018 ◽  
Vol 10 (44) ◽  
pp. 38006-38014 ◽  
Author(s):  
Xun Zhao ◽  
Ming Luo ◽  
Wenxia Zhao ◽  
Ruimei Xu ◽  
Yong Liu ◽  
...  

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Shuaifeng Lou ◽  
Qianwen Liu ◽  
Fang Zhang ◽  
Qingsong Liu ◽  
Zhenjiang Yu ◽  
...  

Abstract Interfacial issues commonly exist in solid-state batteries, and the microstructural complexity combines with the chemical heterogeneity to govern the local interfacial chemistry. The conventional wisdom suggests that “point-to-point” ion diffusion at the interface determines the ion transport kinetics. Here, we show that solid-solid ion transport kinetics are not only impacted by the physical interfacial contact but are also closely associated with the interior local environments within polycrystalline particles. In spite of the initial discrete interfacial contact, solid-state batteries may still display homogeneous lithium-ion transportation owing to the chemical potential force to achieve an ionic-electronic equilibrium. Nevertheless, once the interior local environment within secondary particle is disrupted upon cycling, it triggers charge distribution from homogeneity to heterogeneity and leads to fast capacity fading. Our work highlights the importance of interior local environment within polycrystalline particles for electrochemical reactions in solid-state batteries and provides crucial insights into underlying mechanism in interfacial transport.


Author(s):  
Shi Wang ◽  
Xiang-Chun Li ◽  
Tao Cheng ◽  
Yuan-Yuan Liu ◽  
Qiange Li ◽  
...  

Covalent organic frameworks (COFs) with well-tailored channels have the potential to efficiently transport ions yet remain to be explored. The ion transport capability is generally limited due to the lack...


2019 ◽  
Vol 7 (16) ◽  
pp. 10030-10040 ◽  
Author(s):  
Muhammad A. Shehzad ◽  
Xian Liang ◽  
Aqsa Yasmin ◽  
Xiaolin Ge ◽  
Xinle Xiao ◽  
...  

Stenting stabilizes the ion transport channels which hold excess water and boosts ion permeation, thus overcoming the current stability–efficiency tradeoffs.


Nano Letters ◽  
2017 ◽  
Vol 17 (3) ◽  
pp. 1670-1677 ◽  
Author(s):  
Ming Xu ◽  
Linfeng Fei ◽  
Weibing Zhang ◽  
Tao Li ◽  
Wei Lu ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document