Color-Tunable Aqueous Room-Temperature Phosphorescence Supramolecular Assembly

2021 ◽  
Vol 13 (12) ◽  
pp. 14407-14416
Author(s):  
Yuchen Deng ◽  
Peng Li ◽  
Jiatong Li ◽  
Daolai Sun ◽  
Huanrong Li
Keyword(s):  
Room Temperature ◽  
Supramolecular Assembly ◽  
Room Temperature Phosphorescence ◽  
Color Tunable

DNA Inspirited Rational Construction of Nonconventional Luminophores with Efficient and Color-Tunable Afterglow

2020 ◽  
Author(s):  
Yunzhong Wang ◽  
Saixing Tang ◽  
Yating Wen ◽  
Shuyuan Zheng ◽  
Bing Yang ◽  
...  
Keyword(s):  
Rational Design ◽  
Room Temperature ◽  
Double Helix ◽  
Mechanical Grinding ◽  
Room Temperature Phosphorescence ◽  
Color Tunable ◽  
Potential Applications ◽  
Rational Construction ◽  
Double Helix Structure ◽  
Made In

<div>Persistent room-temperature phosphorescence (p-RTP) from pure organics is attractive </div><div>due to its fundamental importance and potential applications in molecular imaging, </div><div>sensing, encryption, anticounterfeiting, etc.1-4 Recently, efforts have been also made in </div><div>obtaining color-tunable p-RTP in aromatic phosphors5 and nonconjugated polymers6,7. </div><div>The origin of color-tunable p-RTP and the rational design of such luminogens, </div><div>particularly those with explicit structure and molecular packing, remain challenging. </div><div>Noteworthily, nonconventional luminophores without significant conjugations generally </div><div>possess excitation-dependent photoluminescence (PL) because of the coexistence of </div><div>diverse clustered chromophores6,8, which strongly implicates the possibility to achieve </div><div>color-tunable p-RTP from their molecular crystals assisted by effective intermolecular </div><div>interactions. Here, inspirited by the highly stable double-helix structure and multiple </div><div>hydrogen bonds in DNA, we reported a series of nonconventional luminophores based on </div><div>hydantoin (HA), which demonstrate excitation-dependent PL and color-tunable p-RTP </div><div>from sky-blue to yellowish-green, accompanying unprecedentedly high PL and p-RTP </div><div>efficiencies of up to 87.5% and 21.8%, respectively. Meanwhile, the p-RTP emissions are </div><div>resistant to vigorous mechanical grinding, with lifetimes of up to 1.74 s. Such robust, </div><div>color-tunable and highly efficient p-RTP render the luminophores promising for varying </div><div>applications. These findings provide mechanism insights into the origin of color-tunable </div><div>p-RTP, and surely advance the exploitation of efficient nonconventional luminophores.</div>

scholarly journals Stable and color tunable emission properties based on non-cyclometalated gold(iii) complexes

2015 ◽  
Vol 44 (21) ◽  
pp. 10003-10013 ◽  
Author(s):  
Michael Bachmann ◽  
Olivier Blacque ◽  
Koushik Venkatesan
Keyword(s):  
Room Temperature ◽  
Room Temperature Phosphorescence ◽  
Emission Properties ◽  
Color Tunable ◽  
Tunable Emission

Room temperature phosphorescence based on non-cyclometalated gold(iii) complexes with readily tunable emission properties is demonstrated.

scholarly journals Multivalent Supramolecular Assembly with Ultralong Organic Room Temperature Phosphorescence, High Transfer Efficiency and Ultrahigh Antenna Effect in Water

2021 ◽  
Author(s):  
Wei-Lei Zhou ◽  
Wenjing Lin ◽  
Yong Chen ◽  
Xian-Yin Dai ◽  
Zhixue Liu ◽  
...  
Keyword(s):  
Room Temperature ◽  
Cell Imaging ◽  
Supramolecular Assembly ◽  
Soft Materials ◽  
Transfer Efficiency ◽  
Room Temperature Phosphorescence ◽  
Antenna Effect

Multivalent supramolecular assembly has recently attracted extensive attention in the application of soft materials and cell imaging. Here we report a novel multivalent supramolecular assembly constructed by 4-(4-bromophenyl)pyridine-1-ium bromide modified...

Tunable room temperature phosphorescence and energy transfer in ratiometric co-crystals

2020 ◽  
Vol 56 (56) ◽  
pp. 7698-7701 ◽  
Author(s):  
Bo Zhou ◽  
Qihang Zhao ◽  
Longchang Tang ◽  
Dongpeng Yan
Keyword(s):  
Energy Transfer ◽  
Room Temperature ◽  
Room Temperature Phosphorescence ◽  
Color Tunable

Color-tunable green and yellow room temperature phosphorescence is realized through a ratiometric co-crystal strategy.

DNA Inspirited Rational Construction of Nonconventional Luminophores with Efficient and Color-Tunable Afterglow

2020 ◽  
Author(s):  
Yunzhong Wang ◽  
Saixing Tang ◽  
Yating Wen ◽  
Shuyuan Zheng ◽  
Bing Yang ◽  
...  
Keyword(s):  
Rational Design ◽  
Room Temperature ◽  
Double Helix ◽  
Mechanical Grinding ◽  
Room Temperature Phosphorescence ◽  
Color Tunable ◽  
Potential Applications ◽  
Rational Construction ◽  
Double Helix Structure ◽  
Made In

<div>Persistent room-temperature phosphorescence (p-RTP) from pure organics is attractive </div><div>due to its fundamental importance and potential applications in molecular imaging, </div><div>sensing, encryption, anticounterfeiting, etc.1-4 Recently, efforts have been also made in </div><div>obtaining color-tunable p-RTP in aromatic phosphors5 and nonconjugated polymers6,7. </div><div>The origin of color-tunable p-RTP and the rational design of such luminogens, </div><div>particularly those with explicit structure and molecular packing, remain challenging. </div><div>Noteworthily, nonconventional luminophores without significant conjugations generally </div><div>possess excitation-dependent photoluminescence (PL) because of the coexistence of </div><div>diverse clustered chromophores6,8, which strongly implicates the possibility to achieve </div><div>color-tunable p-RTP from their molecular crystals assisted by effective intermolecular </div><div>interactions. Here, inspirited by the highly stable double-helix structure and multiple </div><div>hydrogen bonds in DNA, we reported a series of nonconventional luminophores based on </div><div>hydantoin (HA), which demonstrate excitation-dependent PL and color-tunable p-RTP </div><div>from sky-blue to yellowish-green, accompanying unprecedentedly high PL and p-RTP </div><div>efficiencies of up to 87.5% and 21.8%, respectively. Meanwhile, the p-RTP emissions are </div><div>resistant to vigorous mechanical grinding, with lifetimes of up to 1.74 s. Such robust, </div><div>color-tunable and highly efficient p-RTP render the luminophores promising for varying </div><div>applications. These findings provide mechanism insights into the origin of color-tunable </div><div>p-RTP, and surely advance the exploitation of efficient nonconventional luminophores.</div>

Organic Clusters with Time-Dependent Color-Tunable Dual Persistent Room-Temperature Phosphorescence

2021 ◽  
Author(s):  
Zijian Chen ◽  
Mengke Li ◽  
Weidong Qiu ◽  
Wentao Xie ◽  
Qing Gu ◽  
...  
Keyword(s):  
Room Temperature ◽  
Time Dependent ◽  
Room Temperature Phosphorescence ◽  
Color Tunable ◽  
Tunable Emission

Luminescence from organic clusters has gained increasing interests recently because of their distinct emission characters in compared with the monomer, such as color tunable emission with different wavelength excitation. Herein,...

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