scholarly journals Restorable Neutralization of Poly(acrylic acid) Binders toward Balanced Processing Properties and Cycling Performance for Silicon Anodes in Lithium-Ion Batteries

2020 ◽  
Vol 12 (52) ◽  
pp. 57932-57940
Author(s):  
Zhangxing Shi ◽  
Sisi Jiang ◽  
Lily A. Robertson ◽  
Yuyue Zhao ◽  
Erik Sarnello ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Silicon Anodes ◽  
Processing Properties ◽  
Poly Acrylic Acid

scholarly journals Vinyltriethoxysilane crosslinked poly(acrylic acid sodium) as a polymeric binder for high performance silicon anodes in lithium ion batteries

RSC Advances ◽  
2018 ◽  
Vol 8 (51) ◽  
pp. 29230-29236 ◽  
Author(s):  
Xiangyu Zeng ◽  
Yongji Shi ◽  
Yu Zhang ◽  
Ruixian Tang ◽  
Liangming Wei
Keyword(s):  
Acrylic Acid ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Polymeric Binder ◽  
Silicon Anodes ◽  
Poly Acrylic Acid

The PVTES-NaPAA binder possesses a three-dimensional crosslinked network and exhibits an excellent cycling performance.

scholarly journals A conductive self healing polymeric binder using hydrogen bonding for Si anodes in lithium ion batteries

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jaebin Nam ◽  
Eunsoo Kim ◽  
Rajeev K.K. ◽  
Yeonho Kim ◽  
Tae-Hyun Kim
Keyword(s):  
Hydrogen Bonding ◽  
Acrylic Acid ◽  
Lithium Ion Batteries ◽  
Coulombic Efficiency ◽  
Lithium Ion ◽  
Polymer Binder ◽  
Self Healing ◽  
Si Anodes ◽  
Ion Conducting ◽  
Poly Acrylic Acid

Abstract A ureido-pyrimidinone (UPy)-functionalized poly(acrylic acid) grafted with poly(ethylene glycol)(PEG), designated PAU-g-PEG, was developed as a high performance polymer binder for Si anodes in lithium-ion batteries. By introducing both a ureido-pyrimidinone (UPy) unit, which is capable of self-healing through dynamic hydrogen bonding within molecules as well as with Si, and an ion-conducting PEG onto the side chain of the poly(acrylic acid), this water-based self-healable and conductive polymer binder can effectively accommodate the volume changes of Si, while maintaining electronic integrity, in an electrode during repeated charge/discharge cycles. The Si@PAU-g-PEG electrode retained a high capacity of 1,450.2 mAh g−1 and a Coulombic efficiency of 99.4% even after 350 cycles under a C-rate of 0.5 C. Under a high C-rate of 3 C, an outstanding capacity of 2,500 mAh g−1 was also achieved, thus demonstrating its potential for improving the electrochemical performance of Si anodes.

Aqueous binder effects of poly(acrylic acid) and carboxy methylated cellulose on anode performance in lithium-ion batteries

2019 ◽  
Vol 43 (32) ◽  
pp. 12555-12562 ◽  
Author(s):  
Xiaofei Yang ◽  
Huimin Zhang ◽  
Hai Ming ◽  
Jingyi Qiu ◽  
Gaoping Cao ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Metal Oxide ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Metal Oxide Anode ◽  
Aqueous Binder ◽  
Oxide Anode ◽  
Poly Acrylic Acid

The aqueous binder effects of poly(acrylic acid) and carboxy methylated cellulose on metal (oxide) anode performance in lithium-ion batteries were studied.

High performance polymer binders inspired by chemical finishing of textiles for silicon anodes in lithium ion batteries

2017 ◽  
Vol 5 (42) ◽  
pp. 22156-22162 ◽  
Author(s):  
Liangming Wei ◽  
Zhongyu Hou
Keyword(s):  
Lithium Ion Batteries ◽  
Carboxymethyl Cellulose ◽  
High Performance ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Silicon Anodes ◽  
Polymer Binders ◽  
High Performance Polymer ◽  
Si Anodes

Inspired by the chemical finishing method for textile, theN-methylol acrylamide functionalized carboxymethyl cellulose binder has been developed for Si anodes. This binder can help maintain integration of the Si electrodes, leading to significant improvement in cycling performance of the Si based lithium ion batteries.

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