Degradation Mechanism Study and Safety Hazard Analysis of Overdischarge on Commercialized Lithium-ion Batteries

2020 ◽  
Vol 12 (50) ◽  
pp. 56086-56094
Author(s):  
Tianyi Ma ◽  
Siyuan Wu ◽  
Fang Wang ◽  
Joseph Lacap ◽  
Chunjing Lin ◽  
...  
Author(s):  
Xiaogang Wu ◽  
Yinlong Xia ◽  
Jiuyu Du ◽  
Kun Zhang ◽  
Jinlei Sun

High-power-charging (HPC) behavior and extreme ambient temperature not only pose security risks on the operation of lithium-ion batteries but also lead to capacity degradation. Exploring the degradation mechanism under these two conditions is very important for safe and rational use of lithium-ion batteries. To investigate the influence of various charging-current rates on the battery-capacity degradation in a wide temperature range, a cycle-aging test is carried out. Then, the effects of HPC on the capacity degradation at various temperatures are analyzed and discussed using incremental capacity analysis and electrochemical impedance spectroscopy. The analysis results show that a large number of lithium ions accelerate the deintercalation when the HPC cycle rate exceeds 3 C, making the solid electrolyte interphase at the negative surface unstable and vulnerable to destruction, which results in irreversible consumption of active lithium. In addition, the decomposition of electrolyte is significantly promoted when the HPC temperature is more than 30°C, resulting in accelerated consumption of electrode materials and active lithium, which are the main reasons for the capacity degradation of lithium-ion batteries during HPC under various temperatures.


2018 ◽  
Vol 42 (23) ◽  
pp. 18678-18689 ◽  
Author(s):  
Min Seok Kang ◽  
Dae-Hyuk Lee ◽  
Kyung-Jae Lee ◽  
Hee Soo Kim ◽  
Jihoon Ahn ◽  
...  

Facile method for morphology-preserved transformation of MOFs to porosity and content-controlled M/MO/MC@C composites is presented.


2017 ◽  
Vol 75 (23) ◽  
pp. 77-90 ◽  
Author(s):  
Keisuke Ando ◽  
Tomoyuki Matsuda ◽  
Masao Myojin ◽  
Daichi Imamura

2006 ◽  
Vol 153 (3) ◽  
pp. A576 ◽  
Author(s):  
Toshihiro Yoshida ◽  
Michio Takahashi ◽  
Satoshi Morikawa ◽  
Chikashi Ihara ◽  
Hiroyuki Katsukawa ◽  
...  

Author(s):  
Guiying Tian ◽  
Chuanfeng Huang ◽  
Xianlin Luo ◽  
Zijian Zhao ◽  
Yong Peng ◽  
...  

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