Metal–Organic Framework HKUST-1 Promotes Methane Hydrate Formation for Improved Gas Storage Capacity

2020 ◽  
Vol 12 (47) ◽  
pp. 53510-53518
Author(s):  
Shurraya Denning ◽  
Ahmad AA Majid ◽  
Jolie M. Lucero ◽  
James M. Crawford ◽  
Moises A. Carreon ◽  
...  
Keyword(s):  
Methane Hydrate ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Hydrate Formation ◽  
Gas Storage ◽  
Metal Organic ◽  
Organic Framework

Adsorption of two gas molecules at a single metal site in a metal–organic framework

2016 ◽  
Vol 52 (53) ◽  
pp. 8251-8254 ◽  
Author(s):  
Tomče Runčevski ◽  
Matthew T. Kapelewski ◽  
Rodolfo M. Torres-Gavosto ◽  
Jacob D. Tarver ◽  
Craig M. Brown ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Metal Centers ◽  
Metal Site ◽  
Metal Organic ◽  
Gas Molecules ◽  
Organic Framework

One strategy to markedly increase the gas storage capacity of metal–organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules.

A stable zinc-4-carboxypyrazole framework with high uptake and selectivity of light hydrocarbons

2015 ◽  
Vol 44 (6) ◽  
pp. 2893-2896 ◽  
Author(s):  
Hong-Ru Fu ◽  
Fei Wang ◽  
Jian Zhang
Keyword(s):  
Chemical Stability ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
High Uptake ◽  
Light Hydrocarbons ◽  
High Storage Capacity ◽  
Metal Organic ◽  
High Storage ◽  
Organic Framework

A metal–organic framework based on 4-carboxypyrazole ligands has been synthesized, and it shows unusual chemical stability and high storage capacity for C2 light hydrocarbons.

An Interpenetrated Metal–Organic Framework and Its Gas Storage Behavior: Simulation and Experiment

2011 ◽  
Vol 50 (21) ◽  
pp. 11055-11063 ◽  
Author(s):  
Daniela Frahm ◽  
Michael Fischer ◽  
Frank Hoffmann ◽  
Michael Fröba
Keyword(s):  
Metal Organic Framework ◽  
Gas Storage ◽  
Behavior Simulation ◽  
Simulation And Experiment ◽  
Metal Organic ◽  
Storage Behavior ◽  
Organic Framework

A heterometallic metal–organic framework based on multi-nuclear clusters exhibiting high stability and selective gas adsorption

2019 ◽  
Vol 48 (1) ◽  
pp. 278-284 ◽  
Author(s):  
Dongmei Wang ◽  
Zihua Liu ◽  
Lili Xu ◽  
Chunxia Li ◽  
Dian Zhao ◽  
...  
Keyword(s):  
Chemical Stability ◽  
High Performance ◽  
High Stability ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Gas Storage ◽  
Nuclear Clusters ◽  
Metal Organic ◽  
Thermal And Chemical Stability ◽  
Organic Framework

Porous In/Tb-CBDA has been successfully synthesized in the light of the heterometallic cooperative crystallization (HCC) approach. In/Tb-CBDA with high thermal and chemical stability exhibited high performance for gas storage and separation.

A metal–organic framework functionalized with piperazine exhibiting enhanced CH4 storage

2017 ◽  
Vol 5 (1) ◽  
pp. 349-354 ◽  
Author(s):  
Mingxing Zhang ◽  
Cong Chen ◽  
Qian Wang ◽  
Wensheng Fu ◽  
Kunlin Huang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic ◽  
Organic Framework ◽  
Ch4 Storage

NJU-Bai 19, the first cycloaliphatic ring (piperazine) functionalized MOF-505 analogue, exhibits a notably high methane storage capacity of 246 cm3 (STP) cm−3 (at room temperature and 65 bar) and a working capacity of 185 cm3 (STP) cm−3.

scholarly journals Formulation of Metal–Organic Framework Inks for the 3D Printing of Robust Microporous Solids toward High-Pressure Gas Storage and Separation

2020 ◽  
Vol 12 (9) ◽  
pp. 10983-10992 ◽  
Author(s):  
Jérémy Dhainaut ◽  
Mickaële Bonneau ◽  
Ryota Ueoka ◽  
Kazuyoshi Kanamori ◽  
Shuhei Furukawa
Keyword(s):  
High Pressure ◽  
3D Printing ◽  
Metal Organic Framework ◽  
Gas Storage ◽  
Metal Organic ◽  
Microporous Solids ◽  
Organic Framework

Large H2 storage capacity of a new polyhedron-based metal–organic framework with high thermal and hygroscopic stability

2009 ◽  
pp. 5397 ◽  
Author(s):  
Seunghee Hong ◽  
Minhak Oh ◽  
Mira Park ◽  
Ji Woong Yoon ◽  
Jong-San Chang ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

New Prototype Isoreticular Metal−Organic Framework Zn4O(FMA)3for Gas Storage

2009 ◽  
Vol 48 (11) ◽  
pp. 4649-4651 ◽  
Author(s):  
Ming Xue ◽  
Yun Liu ◽  
Roxanna M. Schaffino ◽  
Shengchang Xiang ◽  
Xiaojun Zhao ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Gas Storage ◽  
Metal Organic ◽  
Organic Framework

A nitro-decorated NbO-type metal–organic framework with a highly selective CO2 uptake and CH4 storage capacity

CrystEngComm ◽  
2014 ◽  
Vol 16 (28) ◽  
pp. 6287-6290 ◽  
Author(s):  
Mingxing Zhang ◽  
Qian Wang ◽  
Zhiyong Lu ◽  
Huiyan Liu ◽  
Wenlong Liu ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Co2 Uptake ◽  
Adsorption Selectivity ◽  
Total Uptake ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework ◽  
Ch4 Storage

A nitro-decorated and highly porous metal–organic framework with NbO topology was reported, exhibiting good adsorption selectivity of CO2/CH4 (8) and CO2/N2 (24) at 273 K and 1 bar, high methane total uptake of 184 cm3 cm−3 at 290 K and 35 bar.

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