scholarly journals Understanding the Role of Oxidative Debris on the Structure of Graphene Oxide Films at the Air–Water Interface: A Neutron Reflectivity Study

2020 ◽  
Vol 12 (22) ◽  
pp. 25453-25463 ◽  
Author(s):  
David López-Dı́az ◽  
M. Dolores Merchán ◽  
M. Mercedes Velázquez ◽  
Armando Maestro
Nanoscale ◽  
2017 ◽  
Vol 9 (34) ◽  
pp. 12543-12548 ◽  
Author(s):  
Nathalie Bonatout ◽  
François Muller ◽  
Philippe Fontaine ◽  
Ignacio Gascon ◽  
Oleg Konovalov ◽  
...  

In this study, we have characterized graphene oxide films formed at the air–water interface by X-ray reflectivity and grazing incidence X-ray diffraction using synchrotron sources.


2021 ◽  
Vol 416 ◽  
pp. 129121
Author(s):  
Kai Yu ◽  
Bin Li ◽  
Huagui Zhang ◽  
Zhentao Wang ◽  
Wei Zhang ◽  
...  

2009 ◽  
Vol 479 (4-6) ◽  
pp. 173-183 ◽  
Author(s):  
Dominik Horinek ◽  
Alexander Herz ◽  
Lubos Vrbka ◽  
Felix Sedlmeier ◽  
Shavkat I. Mamatkulov ◽  
...  

2018 ◽  
Vol 115 (13) ◽  
pp. 3255-3260 ◽  
Author(s):  
Xinxing Zhang ◽  
Kevin M. Barraza ◽  
J. L. Beauchamp

The role of cholesterol in bilayer and monolayer lipid membranes has been of great interest. On the biophysical front, cholesterol significantly increases the order of the lipid packing, lowers the membrane permeability, and maintains membrane fluidity by forming liquid-ordered–phase lipid rafts. However, direct observation of any influence on membrane chemistry related to these cholesterol-induced physical properties has been absent. Here we report that the addition of 30 mol % cholesterol to 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) or 1-palmitoyl-2-oleoyl-sn-glycero-3-phospho-(1′-rac-glycerol) (POPG) monolayers at the air–water interface greatly reduces the oxidation and ester linkage cleavage chemistries initiated by potent chemicals such as OH radicals and HCl vapor, respectively. These results shed light on the indispensable chemoprotective function of cholesterol in lipid membranes. Another significant finding is that OH oxidation of unsaturated lipids generates Criegee intermediate, which is an important radical involved in many atmospheric processes.


Soft Matter ◽  
2012 ◽  
Vol 8 (27) ◽  
pp. 7161 ◽  
Author(s):  
Po-Wei Yang ◽  
Tsang-Lang Lin ◽  
I-Ting Liu ◽  
Yuan Hu ◽  
Michael James

2018 ◽  
Vol 29 (32) ◽  
pp. 325706 ◽  
Author(s):  
Maheshwari Kavirajan Kavitha ◽  
Tushar Sakorikar ◽  
Pramitha Vayalamkuzhi ◽  
Manu Jaiswal

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