Facile Synthesis of 3D NiCoP@NiCoPOx Core–Shell Nanostructures with Boosted Catalytic Activity toward Oxygen Evolution Reaction

2019 ◽  
Vol 2 (6) ◽  
pp. 4188-4194 ◽  
Author(s):  
Mi-Xue Jin ◽  
Yu-Lu Pu ◽  
Zi-Juan Wang ◽  
Zheng Zhang ◽  
Lu Zhang ◽  
...  
Author(s):  
Min Jiang ◽  
Wei Fan ◽  
Anquan Zhu ◽  
Pengfei Tan ◽  
Jianping Xie ◽  
...  

This work employs bacteria as precursors and induces a cost-effective biosorption strategy to obtain Fe2P@carbon nanoparticles decorated on N and P co-doped carbon (Fe2P@CNPs/NPC) materials.


2021 ◽  
Vol 5 (6) ◽  
pp. 1801-1808
Author(s):  
Jie Yu ◽  
Tao Zhang ◽  
Changchang Xing ◽  
Xuejiao Li ◽  
Xinyang Li ◽  
...  

NiS2/Fe-P nanospheres were developed as an efficient oxygen evolution reaction electrocatalyst with a low overpotential (218 mV @ 10 mA cm−2 and 306 mV @ 800 mA cm−2) and Tafel slope (47.5 mV dec−1).


2021 ◽  
Author(s):  
Xiaoping Ma ◽  
Lili Deng ◽  
Manting Lu ◽  
Yi He ◽  
Shuai Zou ◽  
...  

Abstract Although researches on non-noble metal electrocatalysts have been made some progress recently, their performance in proton exchange membrane water electrolyzer (PEMWE) is still incomparable to that of noble-metal-based catalysts. Therefore, it is a more practical way to improve the utilization of precious metals in electrocatalysts for oxygen evolution reaction (OER) in the acidic medium. Herein, nanostructured IrCo@IrCoOx core-shell electrocatalysts composed of IrCo alloy core and IrCoOx shell were synthesized through a simple colloidally synthesis and calcination method. As expected, the hybrid IrCo-200 NPs with petal-like morphology show the best OER activities in acidic electrolytes. They deliver lower overpotential and better electrocatalytic kinetics than pristine IrCo alloy and commercial Ir/C, reaching a low overpotential (j = 10 mA/cm2) of 259 mV (vs. RHE) and a Tafel slope of 59 mV dec−1. The IrCo-200 NPs displayed robust durability with life time of about 55 h in acidic solution under a large current density of 50 mA/cm2. The enhanced electrocatalytic activity may be associated with the unique metal/amorphous metal oxide core-shell heterostructure, allowing the improved charge transferability. Moreover, the *OH-rich amorphous shell functions as the active site for OER and prevents the further dissolution of the metallic core and thus ensures high stability.


2019 ◽  
Vol 7 (16) ◽  
pp. 9690-9697 ◽  
Author(s):  
Jie-Song Sun ◽  
Yi-Tong Zhou ◽  
Rui-Qi Yao ◽  
Hang Shi ◽  
Zi Wen ◽  
...  

Chromium-doped NiFe oxyhydroxide nanosheets that are quasi-vertically oriented on three-dimensional nanoporous gold exhibit superior catalytic activity towards the oxygen evolution reaction.


2019 ◽  
Vol 469 ◽  
pp. 731-738 ◽  
Author(s):  
Jiaxin Wang ◽  
Wenchao Zhang ◽  
Zilong Zheng ◽  
Jingping Liu ◽  
Chunpei Yu ◽  
...  

2018 ◽  
Vol 11 (7) ◽  
pp. 1736-1741 ◽  
Author(s):  
Juzhe Liu ◽  
Yongfei Ji ◽  
Jianwei Nai ◽  
Xiaogang Niu ◽  
Yi Luo ◽  
...  

A simple strategy to synthesize ultrathin, amorphous and alloyed structural cobalt–vanadium hydr(oxy)oxide catalysts with enhanced water oxidation catalytic activity.


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