Novel Composite Polymer Electrolytes of PVdF-HFP Derived by Electrospinning with Enhanced Li-Ion Conductivities for Rechargeable Lithium–Sulfur Batteries

2018 ◽  
Vol 1 (2) ◽  
pp. 483-494 ◽  
Author(s):  
Pavithra M. Shanthi ◽  
Prashanth J. Hanumantha ◽  
Taciana Albuquerque ◽  
Bharat Gattu ◽  
Prashant N. Kumta
Keyword(s):  
Polymer Electrolytes ◽  
Composite Polymer ◽  
Composite Polymer Electrolytes ◽  
Ion Conductivities ◽  
Lithium Sulfur Batteries ◽  
Li Ion ◽  
Lithium Sulfur

Dispersibility of nano-TiO2 on performance of composite polymer electrolytes for Li-ion batteries

2013 ◽  
Vol 111 ◽  
pp. 674-679 ◽  
Author(s):  
Jiang Cao ◽  
Li Wang ◽  
Yuming Shang ◽  
Mou Fang ◽  
Lingfeng Deng ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Li Ion Batteries ◽  
Composite Polymer ◽  
Nano Tio2 ◽  
Composite Polymer Electrolytes ◽  
Li Ion

Design of composite polymer electrolytes for Li ion batteries based on mechanical stability criteria

2012 ◽  
Vol 201 ◽  
pp. 280-287 ◽  
Author(s):  
Sergiy Kalnaus ◽  
Adrian S. Sabau ◽  
Wyatt E. Tenhaeff ◽  
Nancy J. Dudney ◽  
Claus Daniel
Keyword(s):  
Polymer Electrolytes ◽  
Mechanical Stability ◽  
Li Ion Batteries ◽  
Stability Criteria ◽  
Composite Polymer ◽  
Composite Polymer Electrolytes ◽  
Li Ion

High Li-ion conductive composite polymer electrolytes for all-solid-state Li-metal batteries

2021 ◽  
Vol 482 ◽  
pp. 228929
Author(s):  
Qiongyu Zhou ◽  
Qinghui Li ◽  
Songli Liu ◽  
Xin Yin ◽  
Bing Huang ◽  
...  
Keyword(s):  
Solid State ◽  
Polymer Electrolytes ◽  
Composite Polymer ◽  
Composite Polymer Electrolytes ◽  
Conductive Composite ◽  
Li Ion

Dual Li-ion migration channels in ester-rich copolymer/ionic liquid quasi-solid-state electrolyte for high-performance Li-S batteries

2021 ◽  
Author(s):  
Xiaomin Cai ◽  
Bei Ye ◽  
Jianlong Ding ◽  
Ziyun Chi ◽  
Liping Sun ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Solid State ◽  
Polymer Electrolytes ◽  
High Performance ◽  
Ion Migration ◽  
Solid State Electrolyte ◽  
Lithium Sulfur Batteries ◽  
Li Ion ◽  
Lithium Sulfur

Solid-state polymer electrolytes are expected to fundamentally solve the instability and safety problems of liquid electrolytes for lithium sulfur batteries. Herein, ionic liquids were introduced on the basis of constructing...

scholarly journals Excellent Performances of Composite Polymer Electrolytes with Porous Vinyl-Functionalized SiO2 Nanoparticles for Lithium Metal Batteries

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2468
Author(s):  
Hui Zhan ◽  
Mengjun Wu ◽  
Rui Wang ◽  
Shuohao Wu ◽  
Hao Li ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Specific Capacity ◽  
Sio2 Nanoparticles ◽  
Inorganic Materials ◽  
Solid Polymer Electrolytes ◽  
Lithium Metal ◽  
Composite Polymer ◽  
Composite Electrolyte ◽  
Composite Polymer Electrolytes ◽  
Lithium Metal Batteries

Composite polymer electrolytes (CPEs) incorporate the advantages of solid polymer electrolytes (SPEs) and inorganic solid electrolytes (ISEs), which have shown huge potential in the application of safe lithium-metal batteries (LMBs). Effectively avoiding the agglomeration of inorganic fillers in the polymer matrix during the organic–inorganic mixing process is very important for the properties of the composite electrolyte. Herein, a partial cross-linked PEO-based CPE was prepared by porous vinyl-functionalized silicon (p-V-SiO2) nanoparticles as fillers and poly (ethylene glycol diacrylate) (PEGDA) as cross-linkers. By combining the mechanical rigidity of ceramic fillers and the flexibility of PEO, the as-made electrolyte membranes had excellent mechanical properties. The big special surface area and pore volume of nanoparticles inhibited PEO recrystallization and promoted the dissolution of lithium salt. Chemical bonding improved the interfacial compatibility between organic and inorganic materials and facilitated the homogenization of lithium-ion flow. As a result, the symmetric Li|CPE|Li cells could operate stably over 450 h without a short circuit. All solid Li|LiFePO4 batteries were constructed with this composite electrolyte and showed excellent rate and cycling performances. The first discharge-specific capacity of the assembled battery was 155.1 mA h g−1, and the capacity retention was 91% after operating for 300 cycles at 0.5 C. These results demonstrated that the chemical grafting of porous inorganic materials and cross-linking polymerization can greatly improve the properties of CPEs.

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