Hierarchical Design in LiMn2O4 Particles for Advanced Hybrid Aqueous Batteries

Author(s):  
Alireza Zehtab Yazdi ◽  
Jian Zhi ◽  
Min Zhou ◽  
Tuan K. A. Hoang ◽  
Mei Han ◽  
...  
2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yiping Zou ◽  
Tingting Liu ◽  
Qijun Du ◽  
Yingying Li ◽  
Haibo Yi ◽  
...  

AbstractElectrochemically reversible redox couples that embrace more electron transfer at a higher potential are the eternal target for energy storage batteries. Here, we report a four-electron aqueous zinc-iodine battery by activating the highly reversible I2/I+ couple (1.83 V vs. Zn/Zn2+) in addition to the typical I−/I2 couple (1.29 V). This is achieved by intensive solvation of the aqueous electrolyte to yield ICl inter-halogens and to suspend its hydrolysis. Experimental characterization and modelling reveal that limited water activity and sufficient free chloride ions in the electrolyte are crucial for the four-electron process. The merits of the electrolyte also afford to stabilize Zn anode, leading to a reliable Zn-I2 aqueous battery of 6000 cycles. Owing to high operational voltage and capacity, energy density up to 750 Wh kg−1 based on iodine mass was achieved (15–20 wt% iodine in electrode). It pushes the Zn-I2 battery to a superior level among these available aqueous batteries.


2021 ◽  
Vol 373 ◽  
pp. 137847
Author(s):  
R. Trócoli ◽  
A. Morata ◽  
C Erinmwingbovo ◽  
F. La Mantia ◽  
A. Tarancón
Keyword(s):  
Li Ion ◽  

Nanoscale ◽  
2018 ◽  
Vol 10 (44) ◽  
pp. 20754-20760 ◽  
Author(s):  
Ke Lu ◽  
Hong Zhang ◽  
Siyuan Gao ◽  
Yingwen Cheng ◽  
Houyi Ma

Prussian blue particles were deposited on polypyrrole coated wiper clothes and used as bipolar electrodes for fabrication of high performance flexible solid state K-ion aqueous batteries.


2020 ◽  
Vol 12 (31) ◽  
pp. 34931-34940 ◽  
Author(s):  
Wanhai Zhou ◽  
Jian He ◽  
Ding Zhu ◽  
Jinchi Li ◽  
Yungui Chen

2017 ◽  
Vol 8 (8) ◽  
pp. 1701988 ◽  
Author(s):  
Sofia Perticarari ◽  
Yuman Sayed-Ahmad-Baraza ◽  
Chris Ewels ◽  
Philippe Moreau ◽  
Dominique Guyomard ◽  
...  

2009 ◽  
Vol 238 (3) ◽  
pp. 45-62 ◽  
Author(s):  
Roberto Bruni ◽  
Alberto Lluch Lafuente ◽  
Ugo Montanari
Keyword(s):  

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