Enhancement of Near-Infrared Singlet–Triplet Absorption of Ru(II) Sensitizers for Improving Conversion Efficiency of Solar Cells

Author(s):  
Takumi Kinoshita ◽  
Miki Otsubo ◽  
Takaoki Ono ◽  
Hiroshi Segawa
RSC Advances ◽  
2014 ◽  
Vol 4 (92) ◽  
pp. 50897-50905 ◽  
Author(s):  
Wenhui Li ◽  
Zonghao Liu ◽  
Xiaobao Xu ◽  
Yi-Bing Cheng ◽  
Zhixin Zhao ◽  
...  

Two new near-infrared porphyrins exhibited energy conversion efficiency of 7.21% in dye-sensitized solar cells.


MRS Advances ◽  
2017 ◽  
Vol 2 (15) ◽  
pp. 857-862 ◽  
Author(s):  
Kichang Jung ◽  
Taehoon Lim ◽  
Yaqiong Li ◽  
Alfredo A. Martinez-Morales

ABSTRACTIn this work, the integration of ZnO-CuO core-shell nanostructures shows improvement in the conversion efficiency of ZnO-based dye-sensitized solar cells (DSSCs). This is due to CuO acting as a secondary absorption layer that allows the absorption of near-infrared (NIR) light increasing the generated photocurrent in the device, and as a blocking layer that reduces electron-hole recombination. The ZnO core and encapsulating CuO shell are synthesized through chemical vapor deposition (CVD), and thermal oxidation of a Cu seed layer, respectively. The crystallinity of the synthesized ZnO and CuO is analyzed by X-ray diffraction (XRD). Scanning electron microscope (SEM) images show the change in morphology through the steps of Cu seed layer deposition and thermal oxidation of this layer. To determine optical properties of CuO on ZnO nanorods, UV-Vis-NIR photospectrocopy is used. The comparison of conversion efficiency of DSSCs using two different photoelectrodes (i.e. ZnO nanorods versus ZnO-CuO core-shell nanostructure) is performed by I-V measurements.


2020 ◽  
Vol 1 (7) ◽  
pp. 2520-2525
Author(s):  
Venkatesh Piradi ◽  
Xiaopeng Xu ◽  
Qiang Peng ◽  
Xunjin Zhu

The binding of a porphyrin dimer donor (ETDPP-2P) and a non-fullerene acceptor IT-M leads to a visible-near-infrared photoresponse in all small molecule organic solar cells with a power conversion efficiency of 5.69%.


Nanoscale ◽  
2016 ◽  
Vol 8 (30) ◽  
pp. 14432-14437 ◽  
Author(s):  
Meidan Que ◽  
Wenxiu Que ◽  
Xingtian Yin ◽  
Peng Chen ◽  
Yawei Yang ◽  
...  

2016 ◽  
Vol 20 (07) ◽  
pp. 804-812
Author(s):  
Jun Choi ◽  
Woosung Lee ◽  
Jae P. Kim

Novel tetrabenzocorrolazine green photosensitizer was designed and synthesized to enhance the solar energy-to-electricity conversion efficiency of dye-sensitized solar cells. This near-infrared absorbing dye exhibited superior short-circuit photocurrent density induced from the additional absorption compared to the phthalocyanine dye commonly applied as a photosensitizer covering the near-infrared region in dye-sensitized solar cells. The introduction of bulky peripheral groups and axial substituents to the novel dye led to the increase of open-circuit photovoltage. As a result, the novel tetrabenzocorrolazine dye achieved a solar energy-to-electricity conversion efficiency of 3.78% under AM 1.5G conditions which was much higher than that of the phthalocyanine reference dye.


2014 ◽  
Vol 707 ◽  
pp. 98-101
Author(s):  
Su Wen Li ◽  
Yi Jiang ◽  
Shu Guang Ju

The BaF2: Ce3+, Yb3+ nanoparticles doped with different concentration were prepared by a hydrothermal method. The structure,morphology and photoluminescence properties were studied. In BaF2: Ce3+, Yb3+ nanoparticles, a strong near infrared emissionat 900 – 1050 nm matching to energy of Si band gap of Si-based solar cells was observed under the excitation of 5d level of Ce3+. As a downconversion luminescent convertor, the kinds of materials have potential to be applied in front of Si-based solar cells to reduce thermalization loss and enhance conversion efficiency of solar cells.


2014 ◽  
Vol 28 (17) ◽  
pp. 1450106 ◽  
Author(s):  
Won-Ho Son ◽  
Si-Hun Lee ◽  
Sie-Young Choi

This article shows the characteristics on a - SiGe:H based solar cells with various structures. Based on these results, we proposed the a - SiC:H / a - SiGe:H hetero-junction thin film solar cells with a - Si:H buffer layer at the p/i interface to improve the performance of pin-type a - SiGe:H based solar cell. All films of amorphous materials were deposited by 13.56 MHz PECVD method. The effects of deposited parameters on the characteristics of a - SiC:H and a - SiGe:H films have been investigated by ultraviolet–visible–near infrared (UV–VIS–NIR) spectrophotometer. The various values of V oc , J sc , FF and η were measured under 100 mW/cm2 (AM 1.5) solar simulator irradiation. In the proposed structure, we achieved a higher conversion efficiency than general a - SiGe:H solar cell and a - SiC:H / a - SiGe:H hetero-junction thin film solar cells without a - Si:H buffer layer at the p/i interface. Based on results obtained from this study, we discuss the roles of a - Si:H buffer layer in a - SiC:H / a - SiGe:H hetero-junction thin film solar cells.


Nanoscale ◽  
2019 ◽  
Vol 11 (45) ◽  
pp. 21824-21833 ◽  
Author(s):  
Jyoti V. Patil ◽  
Sawanta S. Mali ◽  
Chang Kook Hong

Controlling the grain size of the organic–inorganic perovskite thin films using thiourea additives now crossing 2 μm size with >20% power conversion efficiency.


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