Tertiary-Amine-Assisted Synthesis of Hierarchical Porous Nitrogen-Incorporated Cobalt–Iron (Oxy)hydroxide Nanosheets for Improved Oxygen Evolution Reaction

Author(s):  
Xiang Chen ◽  
Zhaojian Qiu ◽  
Hanlu Xing ◽  
Shunxin Fei ◽  
Lianbo Ma
2019 ◽  
Vol 29 (18) ◽  
pp. 1900315 ◽  
Author(s):  
Kai Wan ◽  
Jiangshui Luo ◽  
Chen Zhou ◽  
Ting Zhang ◽  
Jordi Arbiol ◽  
...  

2019 ◽  
Vol 55 (62) ◽  
pp. 9212-9215 ◽  
Author(s):  
Jiang Han ◽  
Gen Chen ◽  
Xiaohe Liu ◽  
Ning Zhang ◽  
Shuquan Liang ◽  
...  

Co3FePx/C nanocomposites were derived from one-step phosphorization of anthraquinone-2-sulfonate (AQS2) intercalated Co3Fe layered double hydroxides (Co3Fe LDHs).


2020 ◽  
Vol 873 ◽  
pp. 114443 ◽  
Author(s):  
Donggang Guo ◽  
Hongzhi Kang ◽  
Zewei Hao ◽  
Yang Yang ◽  
Pengkun Wei ◽  
...  

2020 ◽  
Vol 234 (5) ◽  
pp. 995-1019 ◽  
Author(s):  
Kirill Sliozberg ◽  
Yauhen Aniskevich ◽  
Ugur Kayran ◽  
Justus Masa ◽  
Wolfgang Schuhmann

AbstractCobalt-iron double hydroxide (CoFe–OH) films were electrochemically deposited on 3D Ni foam electrodes for the oxygen evolution reaction (OER). The dependence of the OER activity on film composition and thickness was evaluated, which revealed an optimal Fe:Co ratio of about 1:2.33. The composition of the catalyst film was observed to vary with film thickness. The electrodeposition parameters were carefully controlled to yield microstructured Ni-foam decorated with CoFe–OH films of controlled thickness and composition. The most active electrode exhibited an overpotential as low as 360 mV OER at an industrial scale current density of 400 mA cm−2 that remained stable for at least 320 h. This work contributes towards the fabrication of practical electrodes with the focus on the development of stable electrodes for electrocatalytic oxygen evolution at high current densities.


Ionics ◽  
2018 ◽  
Vol 24 (10) ◽  
pp. 3095-3100 ◽  
Author(s):  
Chan-Juan Zhang ◽  
Guo-Liang Pan ◽  
Yong-Qiang Zhou ◽  
Chang-Wei Xu

2019 ◽  
Author(s):  
Lichen Bai ◽  
Chia-Shuo Hsu ◽  
Duncan Alexander ◽  
Hao Ming Chen ◽  
Xile Hu

Single atom catalysts exhibit well-defined active sites and potentially maximum atomic efficiency. However, they are unsuitable for reactions that benefit from bimetallic promotion such as the oxygen evolution reaction (OER) in alkaline medium. Here we show that a single atom Co precatalyst can be in-situ transformed into a Co-Fe double atom catalyst for OER. This catalyst exhibits one of the highest turnover frequencies among metal oxides. Electrochemical, microscopic, and spectroscopic data including those from operando X-ray absorption spectroscopy, reveal a dimeric Co-Fe moiety as the active site of the catalyst. This work demonstrates double-atom catalysis as a promising approach for the developed of defined and highly active OER catalysts.


2019 ◽  
Vol 141 (36) ◽  
pp. 14190-14199 ◽  
Author(s):  
Lichen Bai ◽  
Chia-Shuo Hsu ◽  
Duncan T. L. Alexander ◽  
Hao Ming Chen ◽  
Xile Hu

Author(s):  
Seunghwa Lee ◽  
Aliki Moysiadou ◽  
You-Chiuan Chu ◽  
Hao Ming Chen ◽  
Xile Hu

The oxygen evolution reaction (OER) is the bottleneck reaction of water splitting, which can be used to generate green hydrogen from renewable electricity. Cobalt iron oxyhydroxides (CoFeOxHy) are among the...


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