Homogeneous Electrocatalytic CO2 Reduction Using a Porphyrin Complex with Flexible Triazole Units in the Second Coordination Sphere

2021 ◽  
Vol 4 (4) ◽  
pp. 3604-3611
Author(s):  
Nilakshi Devi ◽  
Caroline K. Williams ◽  
Ashwin Chaturvedi ◽  
Jianbing “Jimmy” Jiang
Keyword(s):  
Coordination Sphere ◽  
Co2 Reduction ◽  
Porphyrin Complex ◽  
Second Coordination Sphere

scholarly journals An iron porphyrin complex with pendant pyridine substituents facilitates electrocatalytic CO2 reduction via second coordination sphere effects

ChemCatChem ◽  
2021 ◽  
Author(s):  
Anthony Ramuglia ◽  
Hoang Khoa Ly ◽  
Vishal Budhija ◽  
Michael Marquardt ◽  
Matthias Schwalbe ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Co2 Reduction ◽  
Iron Porphyrin ◽  
Porphyrin Complex ◽  
Second Coordination Sphere

scholarly journals An Iron Porphyrin Complex with Pendant Pyridine Substituents Facilitates Electrocatalytic CO 2 Reduction via Second Coordination Sphere Effects

ChemCatChem ◽  
2021 ◽  
Author(s):  
Anthony R. Ramuglia ◽  
Vishal Budhija ◽  
Khoa H. Ly ◽  
Michael Marquardt ◽  
Matthias Schwalbe ◽  
...  
Keyword(s):  
Coordination Sphere ◽  
Iron Porphyrin ◽  
Porphyrin Complex ◽  
Second Coordination Sphere

Effects of Appended Poly(ethylene glycol) on Electrochemical CO2 Reduction by an Iron Porphyrin Complex

2021 ◽  
Vol 60 (6) ◽  
pp. 3843-3850
Author(s):  
Ashwin Chaturvedi ◽  
Caroline K. Williams ◽  
Nilakshi Devi ◽  
Jianbing “Jimmy” Jiang
Keyword(s):  
Ethylene Glycol ◽  
Co2 Reduction ◽  
Iron Porphyrin ◽  
Poly Ethylene Glycol ◽  
Porphyrin Complex ◽  
Electrochemical Co2 Reduction ◽  
Poly Ethylene

scholarly journals Recent advances in metalloporphyrin-based catalyst design towards carbon dioxide reduction: from bio-inspired second coordination sphere modifications to hierarchical architectures

2020 ◽  
Vol 49 (8) ◽  
pp. 2381-2396 ◽  
Author(s):  
Philipp Gotico ◽  
Zakaria Halime ◽  
Ally Aukauloo
Keyword(s):  
Carbon Dioxide ◽  
Coordination Sphere ◽  
Three Dimensional ◽  
Carbon Dioxide Reduction ◽  
Catalyst Design ◽  
Recent Advances ◽  
Hierarchical Architectures ◽  
Second Coordination Sphere

The progress in CO2 reduction catalyst design was examined starting from simple metalloporphyrin structures and progressing to three-dimensional active architectures.

scholarly journals An amide-based second coordination sphere promotes the dimer pathway of Mn-catalyzed CO2-to-CO reduction at low overpotential

2021 ◽  
Vol 12 (13) ◽  
pp. 4779-4788
Author(s):  
Yong Yang ◽  
Mehmed Z. Ertem ◽  
Lele Duan
Keyword(s):  
Coordination Sphere ◽  
Bond Cleavage ◽  
Low Overpotential ◽  
Second Coordination Sphere ◽  
Co Reduction ◽  
Reduction Catalysts

The amide NH group decreases the overpotential of Mn-based CO2 reduction catalysts by promoting the dimer and protonation-first pathways in the presence of H2O and enhances the CO2 electroreduction activity by facilitating C–OH bond cleavage.

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