Complex Hydride Solid Electrolytes of the Li(CB9H10)–Li(CB11H12) Quasi-Binary System: Relationship between the Solid Solution and Phase Transition, and the Electrochemical Properties

2020 ◽  
Vol 3 (5) ◽  
pp. 4831-4839
Author(s):  
Sangryun Kim ◽  
Kazuaki Kisu ◽  
Shigeyuki Takagi ◽  
Hiroyuki Oguchi ◽  
Shin-ichi Orimo
Keyword(s):  
Phase Transition ◽  
Solid Solution ◽  
Binary System ◽  
Electrochemical Properties ◽  
Solid Electrolytes ◽  
Complex Hydride ◽  
Quasi Binary System

Phase equilibria of the GeTe−Bi2Te3 quasi-binary system in the range 0–50 mol% Bi2Te3

2021 ◽  
pp. 1-10
Author(s):  
T. M. Alakbarova ◽  
Hans-Jürgen Meyer ◽  
E. N. Orujlu ◽  
I. R. Amiraslanov ◽  
M. B. Babanly
Keyword(s):  
Binary System ◽  
Phase Equilibria ◽  
Quasi Binary System

Phase transition-induced changes in the Raman properties of DMSO/benzene binary systems

2021 ◽  
Vol 23 (15) ◽  
pp. 9211-9217
Author(s):  
Guannan Qu ◽  
Rasheed Bilal ◽  
Minsi Xin ◽  
Zhong Lv ◽  
Guangyong Jin ◽  
...  
Keyword(s):  
Phase Transition ◽  
Hydrogen Bond ◽  
Binary System ◽  
Binary Systems ◽  
Induced Changes

Hydrogen bond generated between DMSO and benzene binary system induced changes in the Raman properties during phase transition.

Phase equilibria in the quasi-binary system Zn7Sb2O12–Li3Zn3Sb3O12 and thermal properties of Li3xZn7-4xSb2+xO12 solid solutions

2019 ◽  
Vol 45 (17) ◽  
pp. 23119-23125
Author(s):  
C. Tabasco-Novelo ◽  
J.F. May-Crespo ◽  
A. López-González ◽  
J.A. Marín-Romero ◽  
J.J. Alvarado-Gil ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Binary System ◽  
Phase Equilibria ◽  
Solid Solutions ◽  
Quasi Binary System

Co-sputtered films within the quasi-binary system TiN-TiB2

1997 ◽  
Vol 94-95 ◽  
pp. 297-302 ◽  
Author(s):  
P. Losbichler ◽  
C. Mitterer ◽  
P.N. Gibson ◽  
W. Gissler ◽  
F. Hofer ◽  
...  
Keyword(s):  
Binary System ◽  
Sputtered Films ◽  
Quasi Binary System

scholarly journals Ionic Conductivity and Phase Transition Behaviour in 4AgI-(1-)-2CuI System

2008 ◽  
Vol 2008 ◽  
pp. 1-4 ◽  
Author(s):  
Mohammed Hassan ◽  
Rfi Rafiuddin
Keyword(s):  
Phase Transition ◽  
Ionic Conductivity ◽  
Binary System ◽  
High Temperature Phase ◽  
Temperature Phase ◽  
Conductivity Measurements ◽  
Temperature Dependent ◽  
X Ray ◽  
Dsc Curves ◽  
Transition Behaviour

Samples of general formula 4AgI-(1-)-2CuI, , have been prepared and investigated by XRD, DSC, and temperature-dependent conductivity studies. X-ray diffractograms showed the presence of binary system consisting of AgI and in the sample . Cu-substituted samples showed very similar diffractograms to that of the pure compound which indicates that no effect for the substitution on the nature of the binary system. DSC curves showed the presence of phase transition whose temperature increased with ratio in the system. Ionic conductivity measurements confirmed the occurrence of the phase transition and showed that the high temperature phase is superionic conducting, whose conductivity increases with the increasing amount in the system.

Mechanochemical synthesis of a Mg-Li-Al-H complex hydride

2009 ◽  
Vol 24 (9) ◽  
pp. 2880-2885 ◽  
Author(s):  
Jing Zhang ◽  
Wei Yan ◽  
Chenguang Bai ◽  
Fusheng Pan
Keyword(s):  
Solid Solution ◽  
Hydrogen Storage ◽  
Storage Capacity ◽  
Raw Materials ◽  
Initial Step ◽  
Hydrogen Atmosphere ◽  
Al Alloy ◽  
Hydrogen Storage Capacity ◽  
Scanning Calorimetry ◽  
Complex Hydride

Mg-Li-Al alloy was prepared by ingot casting and then underwent subsequent reactive ball milling. A Mg-Li-Al-H complex hydride was obtained under a 0.4 MPa hydrogen atmosphere at room temperature, and as high as 10.7 wt% hydrogen storage capacity was achieved, with the peak desorption temperature of the initial step at approximately 65 °C. The evolution of the reaction during milling, as well as the effect of Li/Al ratio in the raw materials on the desorption properties of the hydrides formed, were studied by x-ray diffraction and simultaneous thermogravimetry and differential scanning calorimetry techniques. The results showed that mechanical milling increases the solubility of Li in Mg, leading to the transformation of bcc β(Li) solid solution to hcp α(Mg) solid solution, the latter continues to incorporate Li and Al, which stimulates the formation of Mg-Li-Al-H hydride. A lower Li/Al ratio resulted in faster hydrogen desorption rate and a greater amount of hydrogen released at a low temperature range, but sacrificing total hydrogen storage capacity.

New Phosphorus – Tellurium Heterocycles in the Quasi – Binary System RP/Te

2001 ◽  
Vol 169 (1) ◽  
pp. 51-54 ◽  
Author(s):  
Stephan Grimm ◽  
Konstantin Karaghiosoff ◽  
Peter Mayer ◽  
Debbie Ross
Keyword(s):  
Binary System ◽  
Quasi Binary System
Sign in / Sign up

Export Citation Format

Share Document