Effect of Dy3+ and Eu3+ 4f Band Gap States on Luminescence and Energy Transfer in Monoclinic Lutetium Tungstate

2019 ◽  
Vol 1 (5) ◽  
pp. 772-782 ◽  
Author(s):  
Bangfu Ding ◽  
Ce Yu ◽  
Jiandi Xin ◽  
Luqiao Yin ◽  
Zhaohua Li ◽  
...  
Keyword(s):  
Band Gap ◽  
2017 ◽  
Vol 50 (3) ◽  
pp. 787-794 ◽  
Author(s):  
Swati Bishnoi ◽  
G. Swati ◽  
Paramjeet Singh ◽  
V. V. Jaiswal ◽  
Mukesh K. Sahu ◽  
...  

This paper reports the detailed synthesis mechanism and the structural, morphological and optical characterization of ultraviolet (∼311 nm) excitable samarium doped gadolinium yttrium orthovanadate, (Gd,Y)VO4:Sm3+, nanocrystals. X-ray diffraction and Rietveld refinement studies confirmed that the synthesized samples crystallize in a tetragonal structure withI41/amdspace group. The enhanced photoluminescence intensity of (Gd,Y)VO4:Sm3+compared with the existing YVO4:Sm3+phosphor clearly indicates the significant role of Gd3+ions. This has been attributed to the sensitization of the6PJenergy level of Gd3+ions by energy transfer from orthovanadate (VO43−) ions and subsequent energy trapping by Sm3+ions. The energy transfer from VO43−to Sm3+viaGd3+ions as intermediates and concentration quenching of Gd3+luminescence are discussed in detail. The optical band gap of the as-prepared nanocrystals has been estimated using UV–vis–NIR absorption spectroscopy, which reveals a slightly higher band gap (3.75 eV) for YVO4as compared to GdYVO4(3.50 eV). Furthermore, confocal microcopy, decay parameters and Commission Internationale de l'Eclairage chromatic coordinates have supplemented these studies, which established the suitability of these nanophosphors for achieving spectral conversion in silicon solar cells.


2020 ◽  
Vol 38 (5) ◽  
pp. 514-522 ◽  
Author(s):  
Yiyi Ou ◽  
Weijie Zhou ◽  
Fengkai Ma ◽  
Chunmeng Liu ◽  
Rongfu Zhou ◽  
...  

1981 ◽  
Vol 38 (11) ◽  
pp. 884-886 ◽  
Author(s):  
J. Singh ◽  
A. Madhukar
Keyword(s):  
Band Gap ◽  

Author(s):  
Florian Siegrist ◽  
Annkatrin Sommer ◽  
Malte Schröder ◽  
Tobias Boolakee ◽  
Keyhan Golyari ◽  
...  
Keyword(s):  

1986 ◽  
Vol 56 (26) ◽  
pp. 2846-2849 ◽  
Author(s):  
R. Haight ◽  
J. Bokor

1997 ◽  
Vol 65 (3) ◽  
pp. 329-331 ◽  
Author(s):  
N. Achtziger ◽  
J. Grillenberger ◽  
W. Witthuhn
Keyword(s):  
Band Gap ◽  

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