Membrane-Free, Selective Ion Sensing by Combining Organic Electrochemical Transistors and Impedance Analysis of Ionic Diffusion

2021 ◽  
Author(s):  
Hsin Tseng ◽  
Matteo Cucchi ◽  
Anton Weissbach ◽  
Karl Leo ◽  
Hans Kleemann
Keyword(s):  
Impedance Analysis ◽  
Ionic Diffusion ◽  
Ion Sensing ◽  
Organic Electrochemical Transistors

Characterizations of Synthetic 8mol% YSZ with Comparison to 3mol %YSZ for HT-SOFC

2020 ◽  
Vol 38 (4A) ◽  
pp. 491-500
Author(s):  
Abeer F. Al-Attar ◽  
Saad B. H. Farid ◽  
Fadhil A. Hashim
Keyword(s):  
Ionic Conductivity ◽  
Electrochemical Impedance ◽  
Structural Information ◽  
Impedance Analysis ◽  
High Energy ◽  
Yttria Stabilized Zirconia ◽  
X Ray Diffraction ◽  
Stabilized Zirconia ◽  
Powder Morphology ◽  
X Ray

In this work, Yttria (Y2O3) was successfully doped into tetragonal 3mol% yttria stabilized Zirconia (3YSZ) by high energy-mechanical milling to synthesize 8mol% yttria stabilized Zirconia (8YSZ) used as an electrolyte for high temperature solid oxide fuel cells (HT-SOFC). This work aims to evaluate the densification and ionic conductivity of the sintered electrolytes at 1650°C. The bulk density was measured according to ASTM C373-17. The powder morphology and the microstructure of the sintered electrolytes were analyzed via Field Emission Scanning Electron Microscopy (FESEM). The chemical analysis was obtained with Energy-dispersive X-ray spectroscopy (EDS). Also, X-ray diffraction (XRD) was used to obtain structural information of the starting materials and the sintered electrolytes. The ionic conductivity was obtained through electrochemical impedance spectroscopy (EIS) in the air as a function of temperatures at a frequency range of 100(mHz)-100(kHz). It is found that the 3YSZ has a higher density than the 8YSZ. The impedance analysis showed that the ionic conductivity of the prepared 8YSZ at 800°C is0.906 (S.cm) and it was 0.214(S.cm) of the 3YSZ. Besides, 8YSZ has a lower activation energy 0.774(eV) than that of the 3YSZ 0.901(eV). Thus, the prepared 8YSZ can be nominated as an electrolyte for the HT-SOFC.

Structure refinement and impedance analysis of Ba0.85Ca0.15Zr0.10Ti0.90O3 ceramics sintered in air and nitrogen

2019 ◽  
Vol 30 (23) ◽  
pp. 20673-20686
Author(s):  
Ku Noor Dhaniah Ku Muhsen ◽  
Rozana Aina Maulat Osman ◽  
Mohd Sobri Idris
Keyword(s):  
Structure Refinement ◽  
Impedance Analysis

One-step synthesis of PCL/Mg Janus micromotor for precious metal ion sensing, removal and recycling

2019 ◽  
Vol 54 (9) ◽  
pp. 7322-7332 ◽  
Author(s):  
Dongmei Zhang ◽  
Dan Wang ◽  
Jieai Li ◽  
Xiaoyi Xu ◽  
Hui Zhang ◽  
...  
Keyword(s):  
Precious Metal ◽  
Metal Ion ◽  
Ion Sensing ◽  
One Step ◽  
Metal Ion Sensing
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