scholarly journals Potentiation Effect of Iodine Species on the Antimicrobial Capability of Surfaces Coated with Electroactive Phthalocyanines

2021 ◽  
Author(s):  
Estefanía Baigorria ◽  
Javier. E. Durantini ◽  
Sol R. Martínez ◽  
María E. Milanesio ◽  
Yohana B. Palacios ◽  
...  
Keyword(s):  
Iodine Species ◽  
Potentiation Effect

The X40x10 Halogen Bonding Benchmark Revisited: Surprising Importance of (n-1)d Subvalence Correlation

2017 ◽  
Author(s):  
Manoj Kumar Kesharwani ◽  
Nitai Sylvetsky ◽  
Debashree Manna ◽  
Jan M.L. Martin
Keyword(s):  
Dissociation Energy ◽  
Noncovalent Interactions ◽  
Halogen Bonding ◽  
Coupled Cluster ◽  
Dissociation Energies ◽  
Iodine Species ◽  
Explicitly Correlated ◽  
High Level ◽  
Cluster Methods ◽  
Small Separation

<p>We have re-evaluated the X40x10 benchmark for halogen bonding using conventional and explicitly correlated coupled cluster methods. For the aromatic dimers at small separation, improved CCSD(T)–MP2 “high-level corrections” (HLCs) cause substantial reductions in the dissociation energy. For the bromine and iodine species, (n-1)d subvalence correlation increases dissociation energies, and turns out to be more important for noncovalent interactions than is generally realized. As in previous studies, we find that the most efficient way to obtain HLCs is to combine (T) from conventional CCSD(T) calculations with explicitly correlated CCSD-F12–MP2-F12 differences.</p>

The volatilization of iodine species over dilute iodide solutions

1993 ◽  
Vol 71 (5) ◽  
pp. 761-765 ◽  
Author(s):  
G. J. Evans ◽  
S. M. Mirbod ◽  
R. E. Jervis
Keyword(s):  
Iodine Species

scholarly journals Ion chromatographic analysis of aqueous iodine species by conductivity and radioactivity measurements

2005 ◽  
Vol 93 (9-10) ◽  
Author(s):  
Dorothea Schumann ◽  
R. Grasser ◽  
R. Dressler ◽  
H. Bruchertseifer
Keyword(s):  
Chromatographic Analysis ◽  
Nuclear Power ◽  
Power Plants ◽  
Radioactive Iodine ◽  
Cooling Water ◽  
Molecular Iodine ◽  
New Device ◽  
Iodine Species ◽  
Radioactivity Measurements

SummaryA new device was developed for the identification of several iodine species in aqueous solution using ion chromatography. Iodide, iodate and molecular iodine can be determined. (The equipment allows both conductivity and radioactivity detections.) The method is applicable for the determination of radioactive iodine contaminations in the cooling water of nuclear power plants.

scholarly journals Potentiation effect of choline esters on choline-catalysed decarbamoylation of dimethylcarbamoyl-acetylcholinesterase

1992 ◽  
Vol 284 (1) ◽  
pp. 153-160 ◽  
Author(s):  
Y B Kim ◽  
C H Jung ◽  
S J Choi ◽  
W J Seo ◽  
S H Cha ◽  
...  
Keyword(s):  
Ionic Strength ◽  
Quaternary Ammonium ◽  
Acyl Chain ◽  
Requirement Analysis ◽  
Ester Bond ◽  
Choline Ester ◽  
Anionic Sites ◽  
Structural Requirement ◽  
Potentiation Effect ◽  
Choline Esters

The choline esters potentiated the choline-catalysed decarbamoylation of dimethylcarbamoyl-acetylcholinesterase in proportion to the length of acyl group, although esters containing an acyl chain longer than the hexanoyl group exhibited a corresponding decrease in the potentiation. In structural requirement analysis it was found that both the quaternary ammonium moiety and the ester bond were important for the effective acceleration of choline-catalysed decarbamoylation. In general, the respective thiocholine ester was found to be more effective than the corresponding choline ester. Whereas the binding affinity (Ka) of choline in the decarbamoylation was not significantly altered, the maximum decarbamoylation rate (kr(max.)) of choline was greatly enhanced in the presence of choline esters or thiocholine esters. Along with the above observation, the isotope solvent effect, the effect of ionic strength and the antagonism studies demonstrate that the choline esters or thiocholine esters may interact with one of peripheral anionic sites, and thereby make the choline-catalysed decarbamoylation more favourable.

scholarly journals Silver Nanomaterial-Immobilized Desalination Systems for Efficient Removal of Radioactive Iodine Species in Water

Nanomaterials ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 660 ◽  
Author(s):  
Ha Shim ◽  
Jung Yang ◽  
Sun-Wook Jeong ◽  
Chang Lee ◽  
Lee Song ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Radioactive Iodine ◽  
Deinococcus Radiodurans ◽  
Single Photon ◽  
Photon Emission ◽  
Emission Computed Tomography ◽  
Cellulose Acetate Membrane ◽  
High Concentration ◽  
Iodine Species ◽  
Radiation Resistant

Increasing concerns regarding the adverse effects of radioactive iodine waste have inspired the development of a highly efficient and sustainable desalination process for the treatment of radioactive iodine-contaminated water. Because of the high affinity of silver towards iodine species, silver nanoparticles immobilized on a cellulose acetate membrane (Ag-CAM) and biogenic silver nanoparticles containing the radiation-resistant bacterium Deinococcus radiodurans (Ag-DR) were developed and investigated for desalination performance in removing radioactive iodines from water. A simple filtration of radioactive iodine using Ag-CAM under continuous in-flow conditions (approximately 1.5 mL/s) provided an excellent removal efficiency (>99%) as well as iodide anion-selectivity. In the bioremediation study, the radioactive iodine was rapidly captured by Ag-DR in the presence of high concentration of competing anions in a short time. The results from both procedures can be visualized by using single-photon emission computed tomography (SPECT) scanning. This work presents a promising desalination method for the removal of radioactive iodine and a practical application model for remediating radioelement-contaminated waters.

scholarly journals An Antipersister Strategy for Treatment of Chronic Pseudomonas aeruginosa Infections

2017 ◽  
Vol 61 (12) ◽  
Author(s):  
Martina Koeva ◽  
Alina D. Gutu ◽  
Wesley Hebert ◽  
Jeffrey D. Wager ◽  
Lael M. Yonker ◽  
...  
Keyword(s):  
Cystic Fibrosis ◽  
Pseudomonas Aeruginosa ◽  
Lactate Dehydrogenase ◽  
Stationary Phase ◽  
Persister Cells ◽  
Content Type ◽  
Ph Values ◽  
Potentiation Effect ◽  
Metabolite Concentrations ◽  
Ldh Assay

ABSTRACTBacterial persisters are a quasidormant subpopulation of cells that are tolerant to antibiotic treatment. The combination of the aminoglycoside tobramycin with fumarate as an antibacterial potentiator utilizes an antipersister strategy that is aimed at reducing recurrentPseudomonas aeruginosainfections by enhancing the killing ofP. aeruginosapersisters. Stationary-phase cultures ofP. aeruginosawere used to generate persister cells. A range of tobramycin concentrations was tested with a range of metabolite concentrations to determine the potentiation effect of the metabolite under a variety of conditions, including a range of pH values and in the presence of azithromycin or cystic fibrosis (CF) patient sputum. In addition, 96-well dish biofilm and colony biofilm assays were performed, and the cytotoxicity of the tobramycin-fumarate combination was determined utilizing a lactate dehydrogenase (LDH) assay. Enhanced killing of up to 6 orders of magnitude ofP. aeruginosapersisters over a range of CF isolates, including mucoid and nonmucoid strains, was observed for the tobramycin-fumarate combination compared to killing with tobramycin alone. Furthermore, significant fumarate-mediated potentiation was seen in the presence of azithromycin or CF patient sputum. Fumarate also reduced the cytotoxicity of tobramycin-treatedP. aeruginosato human epithelial airway cells. Finally, in mucoid and nonmucoid CF isolates, complete eradication ofP. aeruginosabiofilm was observed in the colony biofilm assay due to fumarate potentiation. These data suggest that a combination of tobramycin with fumarate as an antibacterial potentiator may be an attractive therapeutic for eliminating recurrentP. aeruginosainfections in CF patients through the eradication of bacterial persisters.

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