scholarly journals A Redox Isomerization Strategy for Accessing Modular Azobenzene Photoswitches with Near Quantitative Bidirectional Photoconversion

2019 ◽  
Vol 21 (21) ◽  
pp. 8765-8770 ◽  
Author(s):  
Jie S. Zhu ◽  
Julio M. Larach ◽  
Robert J. Tombari ◽  
Phillip W. Gingrich ◽  
Stanley R. Bode ◽  
...  
Keyword(s):  
Redox Isomerization

Efficient Redox Isomerization of Allylic Alcohols under Mild Conditions Catalyzed by Arene−Ruthenium(II) Complexes

2006 ◽  
Vol 25 (20) ◽  
pp. 4846-4849 ◽  
Author(s):  
Pascale Crochet ◽  
Mariano A. Fernández-Zúmel ◽  
José Gimeno ◽  
Marcus Scheele
Keyword(s):  
Allylic Alcohols ◽  
Mild Conditions ◽  
Redox Isomerization

Direct conversion of secondary propargyl alcohol into 1,3-di-arylpropanone via DBU promoted redox isomerization and palladium assisted chemoselective hydrogenation in a single pot operation

2021 ◽  
Author(s):  
Rimpa De ◽  
S. Antony Savarimuthu ◽  
Shubhadeep Chandra ◽  
Mrinal K Bera
Keyword(s):  
Direct Conversion ◽  
Single Step ◽  
Propargyl Alcohol ◽  
Efficient Catalyst ◽  
Chemoselective Hydrogenation ◽  
Redox Isomerization

Palladium(II)acetate is found to be an efficient catalyst for the single-step conversion of secondary propargyl alcohol to 1,3-diarylpropanone derivatives under mild basic conditions. The reaction is believed to proceed via...

Condensation-Based Methods for the C–H Bond Functionalization of Amines

Synthesis ◽  
2021 ◽  
Author(s):  
Weijie Chen ◽  
Daniel Seidel
Keyword(s):  
Azomethine Ylides ◽  
Comprehensive Overview ◽  
Bond Functionalization ◽  
Redox Isomerization

This review aims to provide a comprehensive overview of condensation-based methods for the C–H bond functionalization of amines that feature azomethine ylides as key intermediates. These transformations are typically redox-neutral and share common attributes with classic name reactions such as the Strecker, Mannich, Friedel−Crafts, Pictet−Spengler, and Kabachnik−Fields reaction, while incorporating a redox-isomerization step. This approach provides an ideal platform to rapidly transform simple starting materials into complex amines.

Total syntheses of melodienones by redox isomerization of propargylic alcohols

2021 ◽  
Author(s):  
Chunmao Dong ◽  
Weiwei Peng ◽  
Huan Wang ◽  
Xiao Zhang ◽  
Jun Zhang ◽  
...  
Keyword(s):  
Total Syntheses ◽  
Propargylic Alcohols ◽  
Rapid Construction ◽  
Redox Isomerization

A remarkable base-promoted methodology for rapid construction of the (E)- and (Z)-γ-oxo-α,β-alkenoic esters skeleton involved with readily accessed vinyl propargylic alcohols through modified redox isomerization was uncovered. This approach manifested...

scholarly journals Long-Sought Redox Isomerization of the Europium(III/II) Complex Achieved by Molecular Reorientation at the Interface

Langmuir ◽  
2020 ◽  
Vol 36 (6) ◽  
pp. 1423-1429 ◽  
Author(s):  
Alexander V. Shokurov ◽  
Daria S. Kutsybala ◽  
Alexander G. Martynov ◽  
Artem V. Bakirov ◽  
Maxim A. Shcherbina ◽  
...  
Keyword(s):  
Molecular Reorientation ◽  
Redox Isomerization

scholarly journals Vinyl Triflate–Aldehyde Reductive Coupling–Redox Isomerization Mediated by Formate: Rhodium‐Catalyzed Ketone Synthesis in the Absence of Stoichiometric Metals

2019 ◽  
Vol 25 (54) ◽  
pp. 12517-12520 ◽  
Author(s):  
William G. Shuler ◽  
Robert A. Swyka ◽  
Tabitha T. Schempp ◽  
Brian J. Spinello ◽  
Michael J. Krische
Keyword(s):  
Reductive Coupling ◽  
Redox Isomerization ◽  
Vinyl Triflate

Ruthenium Complexes with Dendritic Ferrocenyl Phosphanes: Synthesis, Characterization, and Application in the Catalytic Redox Isomerization of Allylic Alcohols

2015 ◽  
Vol 21 (17) ◽  
pp. 6590-6604 ◽  
Author(s):  
Paul Neumann ◽  
Hanna Dib ◽  
Alix Sournia-Saquet ◽  
Toni Grell ◽  
Marcel Handke ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Allylic Alcohols ◽  
Redox Isomerization
Sign in / Sign up

Export Citation Format

Share Document