Palladium-Catalyzed Tandem Reaction of Three Aryl Iodides Involving Triple C–H Activation

2018 ◽  
Vol 20 (10) ◽  
pp. 2997-3000 ◽  
Author(s):  
Xiai Luo ◽  
Yankun Xu ◽  
Genhua Xiao ◽  
Wenjuan Liu ◽  
Cheng Qian ◽  
...  
Keyword(s):  
Tandem Reaction ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Access to chiral tetrahydrofluorenes through a palladium-catalyzed enantioselective tandem intramolecular Heck/Tsuji–Trost reaction

2019 ◽  
Vol 55 (26) ◽  
pp. 3769-3772 ◽  
Author(s):  
Ying Zhang ◽  
Hong-Cheng Shen ◽  
Yang-Yang Li ◽  
Yong-Shuang Huang ◽  
Zhi-Yong Han ◽  
...  
Keyword(s):  
Tandem Reaction ◽  
Aryl Iodides ◽  
Palladium Catalyzed

A palladium-catalyzed enantioselective tandem reaction of 2,5-cyclohexadienyl-substituted aryl iodides and carbon or heteroatom nucleophiles has been successfully established by using a chiral H8-BINOL-based phosphoramidite ligand.

scholarly journals Palladium-catalyzed three-component tandem reaction of sulfonyl hydrazones, aryl iodides and allenes: highly stereoselective synthesis of (Z)-α-hydroxymethyl allylic sulfones

RSC Advances ◽  
2017 ◽  
Vol 7 (79) ◽  
pp. 50372-50377 ◽  
Author(s):  
Yunlei Hou ◽  
Qi Shen ◽  
Liangyu Zhu ◽  
Yufei Han ◽  
Yanfang Zhao ◽  
...  
Keyword(s):  
Stereoselective Synthesis ◽  
Tandem Reaction ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Sulfonyl hydrazones have been identified as an excellent sulfonyl anion surrogate in the tandem reaction with aryl iodides and allenes for the synthesis of functionalized (Z)-allylic sulfones.

Synthesis of S-aryl thioesters via palladium-catalyzed thiocarbonylation of aryl iodides and aryl sulfonyl hydrazides

2020 ◽  
Vol 7 (19) ◽  
pp. 2938-2943
Author(s):  
Yeojin Kim ◽  
Kwang Ho Song ◽  
Sunwoo Lee
Keyword(s):  
Aryl Iodide ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Aryl sulfonyl hydrazide reacted with aryl iodide in the presence of CO to give the corresponding S-aryl thioesters.

Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters

2020 ◽  
Vol 7 (6) ◽  
pp. 885-889 ◽  
Author(s):  
Xinxin Qi ◽  
Zhi-Peng Bao ◽  
Xiao-Feng Wu
Keyword(s):  
Sulfonyl Chlorides ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Convenient Access

A palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides to thioesters has been studied.

Palladium-Catalyzed Asymmetric Annulation Between Aryl Iodides and Racemic Epoxides Using a Chiral Norbornene Cocatalyst

2018 ◽  
Author(s):  
Guangbin Dong ◽  
Renhe Li
Keyword(s):  
Isopropyl Ester ◽  
Synthetic Route ◽  
Initial Development ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Herein, we describe our initial development of an asymmetric Pd-catalyzed annulation between aryl iodides and racemic epoxides for synthesis of 2,3-dihydrobenzofurans using a chiral norbornene cocatalyst. A series of enantiopure ester-, amide- and imide-substituted norbornenes have been prepared with a reliable synthetic route. Promising enantioselectivity (42-45% ee) has been observed using the isopropyl ester-substituted norbornene (N1*) and the amide-substituted norbornene (N7*).

scholarly journals Selective Synthesis of N-Acylnortropane Derivatives in Palladium-Catalysed Aminocarbonylation

Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1813
Author(s):  
László Kollár ◽  
Ádám Erdélyi ◽  
Haroon Rasheed ◽  
Attila Takács
Keyword(s):  
Synthetic Method ◽  
Selective Synthesis ◽  
Varied Structure ◽  
Biological Importance ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Derivatives Of

The aminocarbonylation of various alkenyl and (hetero)aryl iodides was carried out using tropane-based amines of biological importance, such as 8-azabicyclo[3.2.1]octan-3-one (nortropinone) and 3α-hydroxy-8-azabicyclo[3.2.1]octane (nortropine) as N-nucleophile. Using iodoalkenes, the two nucleophiles were selectively converted to the corresponding amide in the presence of Pd(OAc)2/2 PPh3 catalysts. In the presence of several iodo(hetero)arenes, the application of the bidentate Xantphos was necessary to produce the target compounds selectively. The new carboxamides of varied structure, formed in palladium-catalyzed aminocarbonylation reactions, were isolated and fully characterized. In this way, a novel synthetic method has been developed for the producing of N-acylnortropane derivatives of biological importance.

Palladium-catalyzed carbonylative cyclization of 2-alkynylanilines and aryl iodides to access N-acyl indoles

2021 ◽  
Author(s):  
Lingyun Yao ◽  
Yan Shang ◽  
Jian-Shu Wang ◽  
Ailin Pan ◽  
Jun Ying ◽  
...  
Keyword(s):  
Aryl Iodides ◽  
Palladium Catalyzed

A palladium-catalyzed carbonylative synthesis of N-acyl indoles from 2-alkynylanilines and aryl iodides has been developed.

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