Catalytic Asymmetric Electrochemical Oxidative Coupling of Tertiary Amines with Simple Ketones

2017 ◽  
Vol 19 (8) ◽  
pp. 2122-2125 ◽  
Author(s):  
Niankai Fu ◽  
Longji Li ◽  
Qi Yang ◽  
Sanzhong Luo
Keyword(s):  
Oxidative Coupling ◽  
Tertiary Amines ◽  
Catalytic Asymmetric

Organocatalyzed Asymmetric Oxidative Coupling of α-Csp3-H of Tertiary Amines to α,β-Unsaturated γ-Butyrolactam: Synthesis of MBH-Type Products

2014 ◽  
Vol 16 (20) ◽  
pp. 5358-5361 ◽  
Author(s):  
Yunxia Ma ◽  
Gen Zhang ◽  
Jinlong Zhang ◽  
Dongxu Yang ◽  
Rui Wang
Keyword(s):  
Oxidative Coupling ◽  
Tertiary Amines

Oxidative Coupling of Tertiary Amines: Scope, Mechanism and Challenges

Synlett ◽  
2011 ◽  
Vol 2012 (02) ◽  
pp. 159-162 ◽  
Author(s):  
Martin Klussmann ◽  
Kevin Jones
Keyword(s):  
Oxidative Coupling ◽  
Tertiary Amines

ChemInform Abstract: Highly Efficient Cu-Catalyzed Oxidative Coupling of Tertiary Amines and Siloxyfurans.

ChemInform ◽  
2009 ◽  
Vol 40 (20) ◽  
Author(s):  
Youming Shen ◽  
Ze Tan ◽  
De Chen ◽  
Xunbo Feng ◽  
Mo Li ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Tertiary Amines ◽  
Highly Efficient

Preparation of Tertiary Amines via the Oxidative Coupling of Polyfunctional Aryl and Heteroaryl Amidocuprates

Synthesis ◽  
2007 ◽  
Vol 2007 (8) ◽  
pp. 1272-1278 ◽  
Author(s):  
Paul Knochel ◽  
Marcel Kienle ◽  
Srinivas Reddy Dubbaka ◽  
Vicente del Amo
Keyword(s):  
Oxidative Coupling ◽  
Tertiary Amines

Highly efficient Cu-catalyzed oxidative coupling of tertiary amines and siloxyfurans

Tetrahedron ◽  
2009 ◽  
Vol 65 (1) ◽  
pp. 158-163 ◽  
Author(s):  
Youming Shen ◽  
Ze Tan ◽  
De Chen ◽  
Xunbo Feng ◽  
Mo Li ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Tertiary Amines ◽  
Highly Efficient

Photoredox Mediated Asymmetric Cross-Dehydrogenative Coupling of Enones and Tertiary Amines by Chiral Primary Amine Catalysis

Synthesis ◽  
2021 ◽  
Author(s):  
Zongbin Jia ◽  
Qi Yang ◽  
Sanzhong Luo
Keyword(s):  
Primary Amine ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Tertiary Amines ◽  
Dehydrogenative Coupling ◽  
Cross Coupling Reaction ◽  
Iminium Ion ◽  
Amine Catalysis ◽  
Catalytic Asymmetric

We report herein a catalytic asymmetric dehydrogenative cross-coupling reaction between enones and tertiary amines enabled by synergistic photoredox and chiral primary amine catalysis. The reaction was proposed to proceed via the interception of iminium ion intermediate, in situ generated from photoredox oxidation, by dienamine at α-position, following by isomerization, leading to aza-Morita-Baylis-Hillman-type products with good diastereo- and enantio- selectivity.

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