Divergent Synthesis of Trifluoromethyl Sulfoxides and β-SCF3 Carbonyl Compounds by Tandem Trifluoromethylthiolation/Rearrangement of Allylic and Propargylic Alcohols

Deng Zhu; Tong-Mei Ding; Hui-Yun Luo; Hua Ke; Zhi-Min Chen

doi:10.1021/acs.orglett.0c02875

Divergent Synthesis of Trifluoromethyl Sulfoxides and β-SCF3 Carbonyl Compounds by Tandem Trifluoromethylthiolation/Rearrangement of Allylic and Propargylic Alcohols

Organic Letters ◽

10.1021/acs.orglett.0c02875 ◽

2020 ◽

Vol 22 (19) ◽

pp. 7699-7703

Author(s):

Deng Zhu ◽

Tong-Mei Ding ◽

Hui-Yun Luo ◽

Hua Ke ◽

Zhi-Min Chen

Keyword(s):

Carbonyl Compounds ◽

Propargylic Alcohols

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Novel rhenium(i) catalysts for the isomerization of propargylic alcohols into α,β-unsaturated carbonyl compounds: an unprecedented recyclable catalytic system in ionic liquids

Chemical Communications ◽

10.1039/c1cc10768b ◽

2011 ◽

Vol 47 (22) ◽

pp. 6470 ◽

Cited By ~ 25

Author(s):

Joaquín García-Álvarez ◽

Josefina Díez ◽

José Gimeno ◽

Christine M. Seifried

Keyword(s):

Ionic Liquids ◽

Catalytic System ◽

Carbonyl Compounds ◽

Propargylic Alcohols

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A gold(i)-catalyzed route to α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols

Chemical Communications ◽

10.1039/c2cc32042h ◽

2012 ◽

Vol 48 (52) ◽

pp. 6586 ◽

Cited By ~ 29

Author(s):

Srijit Biswas ◽

Joseph S. M. Samec

Keyword(s):

Carbonyl Compounds ◽

Propargylic Alcohols

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ChemInform Abstract: Atom-Efficient Gold(I)-Chloride-Catalyzed Synthesis of α-Sulfenylated Carbonyl Compounds from Propargylic Alcohols and Aryl Thiols: Substrate Scope and Experimental and Theoretical Mechanistic Investigation.

ChemInform ◽

10.1002/chin.201422063 ◽

2014 ◽

Vol 45 (22) ◽

pp. no-no

Author(s):

Srijit Biswas ◽

Christian Dahlstrand ◽

Rahul A. Watile ◽

Marcin Kalek ◽

Fahmi Himo ◽

...

Keyword(s):

Carbonyl Compounds ◽

Propargylic Alcohols ◽

Mechanistic Investigation

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ChemInform Abstract: Novel Rhenium(I) Catalysts for the Isomerization of Propargylic Alcohols into α,β-Unsaturated Carbonyl Compounds: An Unprecedented Recyclable Catalytic System in Ionic Liquids.

ChemInform ◽

10.1002/chin.201135042 ◽

2011 ◽

Vol 42 (35) ◽

pp. no-no

Author(s):

Joaquin Garcia-Alvarez ◽

Josefina Diez ◽

Jose Gimeno ◽

Christine M. Seifried

Keyword(s):

Ionic Liquids ◽

Catalytic System ◽

Carbonyl Compounds ◽

Propargylic Alcohols

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Isomerization of Propargylic Alcohols into α,β-Unsaturated Carbonyl Compounds Catalyzed by the Sixteen-Electron Allyl-Ruthenium(II) Complex [Ru(η3-2-C3H4Me)(CO)(dppf)] [SbF6].

ChemInform ◽

10.1002/chin.200622039 ◽

2006 ◽

Vol 37 (22) ◽

Author(s):

Victorio Cadierno ◽

Sergio E. Garcia-Garrido ◽

Jose Gimeno

Keyword(s):

Carbonyl Compounds ◽

Propargylic Alcohols

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A Simple and Versatile Re-Catalyzed Meyer-Schuster Rearrangement of Propargylic Alcohols to α,β-Unsaturated Carbonyl Compounds

Chemistry - A European Journal ◽

10.1002/chem.200802622 ◽

2009 ◽

Vol 15 (16) ◽

pp. 3940-3944 ◽

Cited By ~ 43

Author(s):

Massimo Stefanoni ◽

Marco Luparia ◽

Alessio Porta ◽

Giuseppe Zanoni ◽

Giovanni Vidari

Keyword(s):

Carbonyl Compounds ◽

Propargylic Alcohols

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ChemInform Abstract: A Gold(I)-Catalyzed Route to α-Sulfenylated Carbonyl Compounds from Propargylic Alcohols and Aryl Thiols.

ChemInform ◽

10.1002/chin.201241083 ◽

2012 ◽

Vol 43 (41) ◽

pp. no-no

Author(s):

Srijit Biswas ◽

Joseph S. M. Samec

Keyword(s):

Carbonyl Compounds ◽

Propargylic Alcohols

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ChemInform Abstract: A Simple and Versatile Re-Catalyzed Meyer-Schuster Rearrangement of Propargylic Alcohols to α,β-Unsaturated Carbonyl Compounds.

ChemInform ◽

10.1002/chin.200934071 ◽

2009 ◽

Vol 40 (34) ◽

Author(s):

Massimo Stefanoni ◽

Marco Luparia ◽

Alessio Porta ◽

Giuseppe Zanoni ◽

Giovanni Vidari

Keyword(s):

Carbonyl Compounds ◽

Propargylic Alcohols

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Metal-catalyzed transformations of propargylic alcohols into α,β-unsaturated carbonyl compounds: from the Meyer–Schuster and Rupe rearrangements to redox isomerizations

Dalton Transactions ◽

10.1039/b923602c ◽

2010 ◽

Vol 39 (17) ◽

pp. 4015 ◽

Cited By ~ 114

Author(s):

Victorio Cadierno ◽

Pascale Crochet ◽

Sergio E. García-Garrido ◽

José Gimeno

Keyword(s):

Carbonyl Compounds ◽

Propargylic Alcohols ◽

Metal Catalyzed

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Alkynylation of Carbonyl Compounds with Terminal Acetylenes Promoted by ZnCl2 and Et3N: Simple, Mild and Efficient Preparation of Propargylic Alcohols.

ChemInform ◽

10.1002/chin.200305088 ◽

2003 ◽

Vol 34 (5) ◽

Author(s):

Biao Jiang ◽

Yu-Gui Si

Keyword(s):

Carbonyl Compounds ◽

Propargylic Alcohols ◽

Terminal Acetylenes

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