A Radical Addition Approach to a Heptafluoroisopropyl Substituted Arene, Combined with a Highly Diastereoselective Annulation Reaction To Synthesize the Tricyclic Core of BMS-986251

2021 ◽  
Author(s):  
William P. Gallagher ◽  
John R. Coombs ◽  
Carlos A. Guerrero ◽  
Eric M. Simmons ◽  
Francisco González-Bobes
Keyword(s):  
Radical Addition ◽  
Tricyclic Core

Radical addition to acrylonitrile via catalytic photochemical decarboxylation of aliphatic carboxylic acids

2013 ◽  
Vol 54 (32) ◽  
pp. 4324-4326 ◽  
Author(s):  
Yasuharu Yoshimi ◽  
Sonoka Washida ◽  
Yoshiki Okita ◽  
Keisuke Nishikawa ◽  
Kousuke Maeda ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Radical Addition ◽  
Aliphatic Carboxylic Acids

Sunlight-induced C C bond formation reaction: Radical addition of alcohols/ethers/acetals to olefins

2021 ◽  
Vol 413 ◽  
pp. 113263
Author(s):  
Mamiko Hayakawa ◽  
Hisashi Shirota ◽  
Souta Hirayama ◽  
Ryuusei Yamada ◽  
Tadashi Aoyama ◽  
...  
Keyword(s):  
Bond Formation ◽  
Radical Addition ◽  
Formation Reaction

Rapid construction of the tricyclic core of annotinine hydrate

Tetrahedron ◽  
2021 ◽  
Vol 82 ◽  
pp. 131934
Author(s):  
Hongliang Shi ◽  
Jinwei Huang ◽  
Shiqiang Ma ◽  
Xiaolin Ju ◽  
Jinbo Duan ◽  
...  
Keyword(s):  
Rapid Construction ◽  
Tricyclic Core

Atom-transfer radical addition of fluoroalkyl bromides to alkenes via a photoredox/copper catalytic system

2021 ◽  
Author(s):  
Vladislav S. Kostromitin ◽  
Artem A. Zemtsov ◽  
Vladimir A. Kokorekin ◽  
Vitalij V. Levin ◽  
Alexander D. Dilman
Keyword(s):  
Catalytic System ◽  
Radical Addition ◽  
Atom Transfer ◽  
Alkyl Bromides ◽  
System P ◽  
Atom Transfer Radical Addition

A method for the addition of fluorinated alkyl bromides to alkenes is described.

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